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Variation of Methods in Small‐Scale Safety and Thermal Testing of Improvised Explosives

Mary Sandstrom、Geoffrey W. Brown、Daniel Preston 等 12 位作者2014-09-29Propellants Explosives Pyrotechnics

Abstract One of the first steps in establishing safe handling procedures for explosives is small‐scale safety and thermal (SSST) testing. To better understand the response of homemade or improvised explosives (HMEs) to SSST testing, 16 HME materials were compared to three standard military explosives in a proficiency‐…

Energetic Materials and CombustionCombustion and Detonation ProcessesThermal and Kinetic Analysis

Quasiclassical Trajectory Calculations of the N(2D) + H2O Reaction Elucidating the Formation Mechanism of HNO and HON Seen in Molecular Beam Experiments

Zahra Homayoon、Joel M. Bowman、Nadia Balucani 等 4 位作者2014-09-29The Journal of Physical Chemistry Letters

The N((2)D) + H2O is a reaction with competitive product channels, passing through several intermediates. Dynamics of this reaction had been investigated by two of the present authors at two collision energies, Ec, using the crossed molecular beams mass spectrometric method ( Faraday Discuss. 2001 , 119 , 27 - 49 ). T…

Advanced Chemical Physics StudiesAtmospheric chemistry and aerosolsCatalytic Processes in Materials Science

Hollow Ni–Co–B amorphous alloy nanospheres: facile fabrication via vesicle-assisted chemical reduction and their enhanced catalytic performances

Wenjing Wei、Yu Zhao、Shichao Peng 等 9 位作者2014-09-29Journal of Materials Chemistry A

In this paper, we develop a simple vesicle-assisted chemical reduction approach for synthesizing hollow Ni–Co–B nanospheres. With various characterization techniques, the resulting Ni–Co–B nanospheres are identified as amorphous alloys with a hollow chamber. Coexistence of NiII and CoII species plays a significant rol…

Electrocatalysts for Energy ConversionNanomaterials for catalytic reactionsNanoporous metals and alloys

The mechanical properties of dissimilar resistance spot-welded DP600–DP1000 steel joints for automotive applications

Hakan Aydın2014-09-29Proceedings of the Institution of Mechanical Engineers Part D Journal of Automobile Engineering

A study was conducted to investigate the microstructure and the mechanical properties of dissimilar resistance spot welds between steel sheets of DP600 and DP1000 using different welding currents for automotive applications. Microstructural characterization, microhardness tests and tensile shear tests of the joints we…

Microstructure and mechanical propertiesAdvanced Welding Techniques AnalysisWelding Techniques and Residual Stresses

Chitosan Derivatives Cross-Linked with Iodinated 2,5-Dimethoxy-2,5-dihydrofuran for Non-Invasive Imaging

Paulomi Ghosh、Manisit Das、Arun Prabhu Rameshbabu 等 8 位作者2014-09-29ACS Applied Materials & Interfaces

Radiopaque polymer derivatives were successfully prepared through surface diffusion mediated cross-linking of chitosan with iodinated 2,5-dimethoxy-2,5-dihydrofuran. The incorporation of iodine in 2,5-dimethoxy-2,5-dihydrofuran was validated by (1)H NMR and mass spectroscopy. The cross-linking of the glucosamine moiet…

Molecular Sensors and Ion DetectionPolymer Surface Interaction StudiesAnalytical Chemistry and Sensors

Syntheses and coordination isomerism of heteroleptic divalent-metal (M = Co, Zn) carbazate complexes

Krishnan Srinivasan、Ayyasamy Kathiresan、William T. A. Harrison 等 4 位作者2014-09-29Journal of Coordination Chemistry

Three heteroleptic divalent-metal alkyl-carbazate-thiocyanate complexes, [M(NCS)2(NH2NHCOOR)2] [M = Co and R = CH2CH3 (1); M = Co and R = CH3 (2); M = Zn and R = CH3 (3)], have been prepared and characterized, and their crystal structures determined. In 1, Co(II) adopts a fairly regular centrosymmetric trans-CoO2N4 oc…

Metal-Organic Frameworks: Synthesis and ApplicationsCrystal structures of chemical compoundsMagnetism in coordination complexes

The effect of PF/PVAC weight ratio and ambient temperature on moisture absorption performance of bamboo‐bundle laminated veneer lumber

Jianchao Deng、Fuming Chen、Haidong Li 等 5 位作者2014-09-29Polymer Composites

The veneer preprocessing densification is a vital procedure in the manufacturing process of long‐span bamboo‐based engineering material, bamboo‐bundle laminated veneer lumber (BLVL). The adhesive used in the preprocessing densification process was the mixture of phenol formaldehyde (PF) resin and polyvinyl acetate (PV…

Wood Treatment and PropertiesNatural Fiber Reinforced CompositesBamboo properties and applications

Atomistic Simulations of P(NDI2OD-T2) Morphologies: From Single Chain to Condensed Phases

Claudia Caddeo、Daniele Fazzi、Mario Caironi 等 4 位作者2014-09-29The Journal of Physical Chemistry B

We investigate theoretically the structure, crystallinity, and solubility of a high-mobility n-type semiconducting copolymer, P(NDI2OD-T2), and we propose a set of new force field parameters. The force field is reparametrized against density functional theory (DFT) calculations, with the aim to reproduce the correct t…

Organic Electronics and PhotovoltaicsAdvanced Memory and Neural ComputingConducting polymers and applications

Effect of Fiber on Tensile Properties of Moso Bamboo

Huanrong Liu、Zehui Jiang、Xiubiao Zhang 等 5 位作者2014-09-29BioResources

Bamboo is a natural bio-composite that has outstanding mechanical properties. Fibers are the structural building block of bamboo. Understanding the effect of fiber area on tensile properties of moso bamboo (Phyllostachys pubescens Mazei ex. H. Lebaie) will shed light on natural efficient design of bamboo. In this pape…

Natural Fiber Reinforced CompositesBamboo properties and applicationsTree Root and Stability Studies

Quantum Hall effect in HgTe quantum wells at nitrogen temperatures

D. A. Kozlov、Z. D. Kvon、Н. Н. Михайлов 等 7 位作者2014-09-29Applied Physics Letters

We report on the observation of quantized Hall plateaus in a system of two-dimensional Dirac fermions, implemented in a 6.6 nm HgTe quantum well at magnetic fields up to 34 T at nitrogen temperatures. The activation energies determined from the temperature dependence of the longitudinal resistivity are found to be alm…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Comparison of foam core sandwich panel and through‐thickness polymer pin–reinforced foam core sandwich panel subject to indentation and flatwise compression loadings

Behzad Abdi、Syed Azwan、Arman Shah Abdullah 等 5 位作者2014-09-29Polymer Composites

Through‐thickness polymer pin–reinforced foam core sandwich (FCS) panels are new type of composite sandwich structure as the foam core of this structure was reinforced with cylindrical polymer pins, which also rigidly connect the face sheets. These sandwich panels are made of glass fiber–reinforced polyester face shee…

Mechanical Behavior of CompositesCellular and Composite StructuresPolymer composites and self-healing

Porous fluorine-doped tin oxide as a promising substrate for electrochemical biosensors—demonstration in hydrogen peroxide sensing

Kuan‐Ting Lee、Dai-Min Liu、Yung-Yung Liang 等 6 位作者2014-09-29Journal of Materials Chemistry B

Conducting porous substrates of high hydrophilicity are advantageous in applications of electrochemical biosensors as host electrodes, offering not only fast charge transport and large sensing surface areas but also necessary wettability in aqueous analytes. In this study, inexpensive, highly hydrophilic (contact angl…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Synthetic ferrimagnets with thermomagnetic switching

A. F. Kravets、Yu. I. Dzhezherya、A. I. Tovstolytkin 等 10 位作者2014-09-29Physical Review B

Interlayer exchange coupling in strong/weak/strong ferromagnetic multilayers is investigated as a function of external magnetic field and temperature, with the focus on the magnetization switching near the Curie transition in the spacer composed of a diluted ferromagnet of concentration paramagnetic in the bulk. The e…

Physics of Superconductivity and MagnetismMagnetic properties of thin filmsMagnetic and transport properties of perovskites and related materials

Surface and sub-surface thermal oxidation of thin ruthenium films

R. Coloma Ribera、Robbert Wilhelmus Elisabeth van de Kruijs、S. Kokke 等 6 位作者2014-09-29Applied Physics Letters

A mixed 2D (film) and 3D (nano-column) growth of ruthenium oxide has been experimentally observed for thermally oxidized polycrystalline ruthenium thin films. Furthermore, in situ x-ray reflectivity upon annealing allowed the detection of 2D film growth as two separate layers consisting of low density and high density…

ZnO doping and propertiesSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Control of waveguide properties by tuning femtosecond laser induced compositional changes

Jesús del Hoyo、Rebeca Martìnez Vàzquez、Belén Sotillo 等 8 位作者2014-09-29Applied Physics Letters

Local compositional changes induced by high repetition rate fs-laser irradiation can be used to produce high performance optical waveguides in phosphate-based glasses. The waveguide refractive index contrast is determined by the local concentration of La, which can be changed by the action of the writing laser pulses.…

Glass properties and applicationsLaser Material Processing TechniquesNonlinear Optical Materials Studies

Doping-tunable thermal emission from plasmon polaritons in semiconductor epsilon-near-zero thin films

Young Chul Jun、Ting S. Luk、A. Robert Ellis 等 5 位作者2014-09-29Applied Physics Letters

We utilize the unique dispersion properties of leaky plasmon polaritons in epsilon-near-zero (ENZ) thin films to demonstrate thermal radiation control. Owing to its highly flat dispersion above the light line, a thermally excited leaky wave at the ENZ frequency out-couples into free space without any scattering struct…

Metamaterials and Metasurfaces ApplicationsThermal Radiation and Cooling TechnologiesOptical properties and cooling technologies in crystalline materials

Pipeline Repair of Corrosion and Dents: A Comparison of Composite Repairs and Steel Sleeves

Chris Alexander、Brent Vyvial、F Wilson2014-09-29OpenAlex

When pipeline repairs are made on high pressure onshore transmission pipelines, in modern times repairs typically involve steel sleeves or composite repair systems. A comprehensive testing program was conducted to evaluate the repair of severe corrosion and dents using composite materials, as well as Type A and B stee…

Hydrogen embrittlement and corrosion behaviors in metalsStructural Integrity and Reliability AnalysisOffshore Engineering and Technologies

Ultrafine and well dispersed silver nanocrystals on 2D nanosheets: synthesis and application as a multifunctional material for electrochemical catalysis and biosensing

Tao Gao、Dawei Yang、Limin Ning 等 6 位作者2014-09-29Nanoscale

The strong coupling of inorganic nanocrystals with 2D nanosheets to produce function-enhanced nano-materials with uniform size, dispersion, and high coverage density has long been of interest to scientists from various research fields. Here, a simple and effective method has been described to fabricate ultrafine and w…

Advanced Photocatalysis TechniquesAdvanced biosensing and bioanalysis techniquesAdvanced Nanomaterials in Catalysis

Constitutional Hybrid Materials – Toward Selection of Functions

Mihail Bãrboiu2014-09-29European Journal of Inorganic Chemistry

Abstract This microreview reveals a new strategy to transcribe supramolecular architectures in self‐organized constitutional hybrids. In particular, the use of communicating reversible‐covalent and supramolecular hydrophobic interfaces between organic/supramolecular and inorganic/siloxane networks represents a useful…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryAnalytical Chemistry and Sensors

A three-photon probe with dual emission colors for imaging of Zn( ii ) ions in living cells

Amal Kumar Mandal、Tingchao He、Swarup Kumar Maji 等 5 位作者2014-09-29Chemical Communications

A novel three-photon probe for the imaging of exogenous Zn(II) ions in live cells with varying emission colors under three-photon excitation is developed. The tuning of the charge transfer state and the emission color of the probe was also demonstrated in the presence of acid.

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors