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Improving the mechanical properties of Zr-based bulk metallic glass by controlling the activation energy for β-relaxation through plastic deformation

Nozomu Adachi、Yoshikazu Todaka、Yoshihiko Yokoyama 等 4 位作者2014-09-29Applied Physics Letters

The mechanism of plastic deformation in bulk metallic glasses (BMGs) is widely believed to be based on a shear transformation zone (STZ). This model assumes that a shear-induced atomic rearrangement occurs at local clusters that are a few to hundreds of atoms in size. It was recently postulated that the potential ener…

Material Dynamics and PropertiesGlass properties and applicationsMetallic Glasses and Amorphous Alloys

Phosphorus-doped graphene-wrapped molybdenum disulfide hollow spheres as anode material for lithium-ion batteries

Wen-Da Qiu、Jiqing Jiao、Jian Xia 等 5 位作者2014-09-29RSC Advances

Molybdenum disulfide is a promising candidate for the anode material in lithium-ion batteries due to its high theoretical specific capacity. However, volume change during cycling causes poor cycling stability and rate performance, and improving cycle life is a major research challenge. Herein, we present a strategy by…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Charge transfer and mobility enhancement at CdO/SnTe heterointerfaces

Junichi Nishitani、K. M. Yu、Władek Walukiewicz2014-09-29Applied Physics Letters

We report a study of the effects of charge transfer on electrical properties of CdO/SnTe heterostructures. A series of structures with variable SnTe thicknesses were deposited by RF magnetron sputtering. Because of an extreme type III band offset with the valence band edge of SnTe located at 1.5 eV above the conductio…

ZnO doping and propertiesChalcogenide Semiconductor Thin FilmsAdvanced Semiconductor Detectors and Materials

Significant roles of low-temperature post-metallization annealing in solution-processed oxide thin-film transistors

Yong Xu、Chuan Liu、Paul S.K. Amegadze 等 9 位作者2014-09-29Applied Physics Letters

Inspired by the silicide technology in manufacturing silicon devices and the ongoing lack of knowledge on post-metallization annealing in realizing oxide devices, we investigated post-contact annealing for solution-processed InGaZnO transistors. Low-temperature annealing in air is found to significantly improve device…

ZnO doping and propertiesSemiconductor materials and devicesThin-Film Transistor Technologies

Combustion and Material Characterization of Highly Tunable On‐Chip Energetic Porous Silicon

Nicholas W. Piekiel、Christopher J. Morris、Wayne A. Churaman 等 6 位作者2014-09-29Propellants Explosives Pyrotechnics

Abstract We present a comprehensive investigation into the tunable combustion of on‐chip porous silicon energetic materials. The exothermic reaction occurs between high surface area nanoscale porous silicon and a solution‐deposited sodium perchlorate oxidizer that penetrates each pore. The resulting burn rates spanned…

Energetic Materials and CombustionSilicon Nanostructures and Photoluminescence

Anti-Inflammatory Effect of 3-O-[(6'-O-Palmitoyl)-β-D-glucopyranosyl Sitosterol] from Agave angustifolia on Ear Edema in Mice

Elizabeth Hernández-Valle、Maribel Herrera‐Ruíz、Gabriela Salgado 等 8 位作者2014-09-29Molecules

In Mexico Agave angustifolia has traditionally been used to treat inflammation. The aim of this study was to measure the anti-inflammatory effect of the extract of A. angustifolia, the isolation and identification of active compounds. From the acetone extract two active fractions were obtained, (AsF13 and AaF16). For…

Natural product bioactivities and synthesisPhytochemical Studies and BioactivitiesPhytochemistry and Bioactive Compounds

Poly‐(Alizarin Red S)‐Modified Glassy Carbon Electrode for Simultaneous Electrochemical Determination of Levodopa, Homovanillic Acid and Ascorbic Acid

Abdolhamid Hatefi‐Mehrjardi、Nasrin Ghaemi、Mohammad Ali Karimi 等 5 位作者2014-09-29Electroanalysis

Abstract A polymeric film of Alizarin Red S was formed on a glassy carbon electrode and used for electrochemical detection of Levodopa (L‐DOPA) and homovanillic acid (HVA) in the presence of ascorbic acid (AA). The sensor represented excellent electrocatalytic activity for their oxidations. The resultant differential…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Structural heterogeneity of milk casein micelles: a SANS contrast variation study

Antoine Bouchoux、Jorge Ventureira、Geneviève Gésan-Guiziou 等 9 位作者2014-09-29Soft Matter

We examine the internal structure of milk casein micelles using the contrast variation method in Small-Angle Neutron Scattering (SANS). Experiments were performed with casein dispersions of different origins (i.e., milk powder or fresh milk) and extended to very low q-values (∼9 × 10(-4) Å(-1)), thus making it possibl…

Proteins in Food SystemsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Enhanced photoelectrochemical performance by synthesizing CdS decorated reduced TiO 2 nanotube arrays

Qian Zhang、Ling Wang、Jiangtao Feng 等 5 位作者2014-09-29Physical Chemistry Chemical Physics

The efficient utilization of solar spectrum and photo-induced charge transport are critical aspects in improving the light conversion efficiency of solar cells and hydrogen generation. In this work, reduced TiO2 nanotube arrays with CdS decoration were fabricated through the simple cathodic polarization of annealed Ti…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

Synthesis of MA POSS–PMMA as an intraocular lens material with high light transmittance and good cytocompatibility

Bailiang Wang、Quankui Lin、Chenghui Shen 等 6 位作者2014-09-29RSC Advances

Poly(methyl methacrylate) (PMMA) has been widely used for intraocular lenses (IOL) but may lead to posterior capsule opacification (PCO) after implantation due to its undesirable hydrophilicity and surface morphology. A novel methacrylisobutyl polyhedral oligomeric silsesquioxane-co-poly methyl methacrylate copolymer…

Intraocular Surgery and LensesMarine Biology and Environmental ChemistrySilicone and Siloxane Chemistry

Cationic Vesicles Based on Amphiphilic Pillar[5]arene Capped with Ferrocenium: A Redox‐Responsive System for Drug/siRNA Co‐Delivery

Yincheng Chang、Kui Yang、Wei Peng 等 7 位作者2014-09-29Angewandte Chemie

Abstract A novel ferrocenium capped amphiphilic pillar[5]arene (FCAP) was synthesized and self‐assembled to cationic vesicles in aqueous solution. The cationic vesicles, displaying low cytotoxicity and significant redox‐responsive behavior due to the redox equilibrium between ferrocenium cations and ferrocenyl groups,…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

High Temperature Corrosion under Laboratory Conditions Simulating Biomass-Firing: A Comprehensive Characterization of Corrosion Products

Sunday Chukwudi Okoro、Melanie Montgomery、Flemming Frandsen 等 4 位作者2014-09-29Energy & Fuels

An austenitic stainless steel (TP 347H FG) was coated with a synthetic deposit and exposed, under laboratory conditions simulating straw-firing at 560 °C, for 1 week. Microscopic, diffraction, and spectroscopic techniques were employed for cross-sectional and plan view “top-down” microstructural characterization of th…

Thermochemical Biomass Conversion ProcessesCorrosion Behavior and InhibitionHigh-Temperature Coating Behaviors

Advances in Light Emission from Group-IV Alloys via Lattice Engineering and n-Type Doping Based on Custom-Designed Chemistries

Charutha Senaratne、James C. Gallagher、Toshihiro Aoki 等 5 位作者2014-09-29Chemistry of Materials

Intrinsic and n-type Ge 1– y Sn y alloys with y = 0.003–0.11 have been grown on Ge-buffered Si via reactions of Ge 3 H 8 and SnD 4 hydrides using UHV-CVD techniques. The films exhibit large thicknesses ( t > 600 nm), low dislocation densities (10 7 /cm 2 ), planar surfaces (AFM RMS ≈ 2 for intrinsic films) and mostly…

Photonic and Optical DevicesThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence

The Immobilization of Glucose Oxidase at Manganese Dioxide Particles-Decorated Reduced Graphene Oxide Sheets for the Fabrication of a Glucose Biosensor

A.T. Ezhil Vilian、Veerappan Mani、Shen–Ming Chen 等 5 位作者2014-09-29Industrial & Engineering Chemistry Research

Here, we describe a simple approach for the efficient immobilization of poly- l -lysine (PLL) impregnated glucose oxidase (GOx) at a manganese dioxide (MnO 2 )-decorated chemically reduced graphene oxide (CRGO) composite film modified electrode. The MnO 2 /CRGO film was analyzed by various techniques such as scanning…

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsConducting polymers and applications

Critical route for coherent perfect absorption in a Fano resonance plasmonic system

Ming Kang、Y. D. Chong、Hui‐Tian Wang 等 5 位作者2014-09-29Applied Physics Letters

We develop a method for realizing coherent perfect absorption in thin metamaterial systems, based on the coupled-mode theory of Fano resonance. Coherent perfect absorption refers to the complete absorption of symmetric plane waves incident on opposite sides of the system, due to critical coupling into the dissipative…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchOrbital Angular Momentum in Optics

Tunable Fano Resonance in E-Shape Plasmonic Nanocavities

Bo Sun、Lixia Zhao、Chao Wang 等 7 位作者2014-09-29The Journal of Physical Chemistry C

The optical properties of e-shape plasmonic nanocavities have been studied. Due to the destructive interference of the quadrupole resonance of the c-shape nanoring with the overlapping dipolar resonance of the nanorod, a tunable Fano resonance within a wide range of spectra from visible light to mid-infrared (mid-IR)…

Gold and Silver Nanoparticles Synthesis and ApplicationsMetamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon Research

Demonstration of Multiple Logic Operations in a Heteroditopic Pyrene–Phenylimidazole–Terpyridine Conjugate Based on Optical Responses by Selective Anions and Cations: An Experimental and Theoretical Investigation

Srikanta Karmakar、Dinesh Maity、Sourav Mardanya 等 4 位作者2014-09-29The Journal of Physical Chemistry A

Combined experimental and density functional theory (DFT) and time-dependent density functional theory (TD-DFT) studies were carried out to investigate the structural and electronic properties of a terpyridyl-phenylimidazole system covalently linked to pyrene, 10-(4-[2,2':6',2"-terpyridine]terpyridin-4'-yl-phenyl)-9H-…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors

Folding pathway of a multidomain protein depends on its topology of domain connectivity

Takashi Inanami、Tomoki P. Terada、Masaki Sasai2014-09-29Proceedings of the National Academy of Sciences

How do the folding mechanisms of multidomain proteins depend on protein topology? We addressed this question by developing an Ising-like structure-based model and applying it for the analysis of free-energy landscapes and folding kinetics of an example protein, Escherichia coli dihydrofolate reductase (DHFR). DHFR has…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function

Electromagnetically induced transparency with large group index induced by simultaneously exciting the electric and the magnetic resonance

Haiming Li、Shaobin Liu、Siyuan Liu 等 4 位作者2014-09-29Applied Physics Letters

In this paper, we numerically and experimentally demonstrate classical analogy of electromagnetically induced transparency (EIT) with simultaneously exciting the electric and the magnetic resonance. The cut wire and the split-ring resonator (SRR) are chosen as the bright and the quasi-dark EIT resonators, respectively…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchQuantum optics and atomic interactions

Boosting the extensibility potential of fibre networks: A review

Alexey Vishtal、Elias Retulainen2014-09-29BioResources

Production of paper-based packaging is growing at the present moment and has great future prospects. However, the development of new packaging concepts is creating a demand for an improvement in the mechanical properties of paper. Extensibility is one of these properties. Highly extensible papers have the potential to…

Advanced Cellulose Research StudiesTextile materials and evaluationsMaterial Properties and Processing