Materials Literature
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The research on lead-free piezoelectric ceramics has been one of the important fields worldwide for years for the sustainable development of the world. In recent years, the author and his group concentrated their work on perovskite lead-free piezoelectric ceramics, especially on ( Bi 1/2 Na 1/2 ) TiO 3 ( BNT )- and K…
In this work, we consider the problem of calculating the classical free energies of liquids and solids for molecular models with intramolecular flexibility. We show that thermodynamic integration from the fully-interacting solid of interest to a Debye crystal reference state, with anisotropic harmonic interactions der…
The magnetocaloric effect or "magnetic Grüneisen ratio" Γ(H)=T(-1)(dT/dH)(S) quantifies the cooling or heating of a material when an applied magnetic field is changed under adiabatic conditions. Recently, this property has attracted considerable interest in the field of quantum criticality. Here, we report the develop…
Clotrimazole (CLO) is a local imidazolic antifungal agent. A major problem associated with the successful formulation of effective dosage forms containing CLO is its poor aqueous solubility, which presents a hindrance for the local availability of CLO and limits the effective antifungal therapy. In the present study,…
Layered double hydroxides (LDHs), either having nitrate counter anions or intercalated with organic molecules, have been for the first time partially exfoliated in dimethyl sulfoxide (DMSO) to form a transparent suspension. Atomic force microscopy (AFM) images showed that both the lateral size and the thickness of the…
We present the design and experimental implementation of an RF limiter metamaterial using a sheet of nonlinear metamaterials. We demonstrate that complementary electric inductive-capacitive resonators loaded with nonlinear p-i-n diodes can act as RF limiter unit cells. We design and fabricate limiter metamaterials and…
Hexagonal Co0.85Se with Ni0.85Se-type structure has been successfully synthesized without any surfactants by a solvothermal reduction route. SEM observation indicated that the obtained Co0.85Se nanostructures were of graphene-like morphology with a thickness less than 10 nm. The influence of the reaction temperature a…
Two structurally different Er-formate frameworks, one NaCl-like [dmenH(2)][Er(HCOO)(4)](2) (1) and the other pillared-layer type [tmenH(2)][Er(HCOO)(4)](2) (2), were obtained when templated by the corresponding protonated N,N'-dimethylethylenediamine (dmenH(2)) and N,N,N',N'-tetramethyl- ethylenediamine (tmenH(2)). Th…
AIM: To investigate the apoptotic activities of casticin in hepatocellular carcinoma (HCC) cells and its molecular mechanisms. METHODS: PLC/PRF/5 and Hep G2 cell lines were cultured in vitro and the inhibitory effect of casticin on the growth of cells was detected by 3-[4,5-dimethylthiazol-2-yl]-2,5 diphenyl tetrazoli…
Dysprosium doped yttria stabilized zirconia single crystals grown by the laser floating zone method crystallize in the tetragonal form as confirmed by Raman spectroscopy. In addition to the role of the dysprosium ion as stabilizer, the ion optical activation constitutes an opportunity to explore the zirconia-based mat…
We report the fabrication of BiOCl nanoflake film by a simple and reliable hydrolysis of BiCl(3) ethanol solution at room temperature. The as-prepared film, when modified with 1H,1H,2H,2H,-perfluorodecyltrichlorosilane (FDTS), exhibits excellent superhydrophobicity and long-term durability under UV light irradiation f…
A flexible nanoparticle-based sulfate assay is demonstrated in which the positively-charged gold nanoparticles (cysteamine-AuNPs) act as indicator. The aggregation of cysteamine-AuNPs is selectively induced by sulfate, which allows the rapid colorimetric sensing of sulfate without any precipitant, sample preparation a…
Amyloids are highly organized protein filaments, rich in β-sheet secondary structures that self-assemble to form dense plaques in brain tissues affected by severe neurodegenerative disorders (e.g. Alzheimer's Disease). Identified as natural functional materials in bacteria, in addition to their remarkable mechanical p…
We report the synthesis of ternary bismuth ferrites Bi2Fe4O9 submicrocrystals with tunable morphologies from sheets, plates, to cubes under hydrothermal conditions. These Bi2Fe4O9 submicrocrystals were single crystal with dominating {001}, {110} and {10} facets. The crystal growth and the influence of hydroxide on the…
The polycarbonate film (PC) surface was treated using glow discharge low-pressure air plasma. The modified surface was characterized by contact angle, FTIR, XRD, AFM, and XPS analysis. The surface-modified samples were further investigated using T-peel test for technical applications. The surface energy of the sample…
Nitric oxide (NO)-releasing polyurethanes capable of releasing up to 0.20 μmol NO cm(-2) were synthesized by incorporating active S-nitrosothiol functionalities into hard and soft segment domains using thiol group protection and post-polymerization modifications, respectively. The nitrosothiol position within the hard…
Dielectric studies were carried out on a lead free Sodium Bismuth Titanate, NBT, ( Na 0.5 Bi 0.5 TiO 3 ) composition. The material was synthesized by conventional ceramic method (CS) and microwave sintering (MS). The presence of single phase has been confirmed by X-ray diffraction and scanning electron microscopy of N…
The remarkable mechanical characteristics of the spider silk protein major ampullate spidroin protein suggest this polymer as a promising biomaterial to consider for the fabrication of scaffolds for bone regeneration. Herein, a new functionalized spider silk-bone sialoprotein fusion protein was designed, cloned, expre…
Silver is widely used for fabrication of plasmonic devices because of its unique optical constants. The nanostructure of the Ag layer is mainly influenced during the initial stage of the silver nucleation. Therefore, we focus our attention on studying this stage of silver growth. Nanostructured ultrathin silver layers…
We prepared two Janus dendrimers 1 and 2 bearing a hydrophobic Percec-type minidendron (i.e., 3,4,5-tridodecyloxybenzyl group) and hydrophilic aliphatic ether dendrons with different degrees of branching via stepwise click reactions. The obtained Janus dendrimers have the same hydrophilic volume fraction (f = 0.34), b…