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A Density Functional Study of Ethylene Insertion into the M-CH3 Bond of the Constrained Geometry Catalysts [(SiH2-C5H4-NH)MCH3]+ (M = Ti, Zr, Hf) and (SiH2-C5H4-NH)TiCH3

Liangyou Fan、Daryll G. Harrison、Tom K. Woo 等 4 位作者1995-04-01Organometallics

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA Density Functional Study of Ethylene Insertion into the M-CH3 Bond of the Constrained Geometry Catalysts [(SiH2-C5H4-NH)MCH3]+ (M = Ti, Zr, Hf) and (SiH2-C5H4-NH)TiCH3Liangyou Fan, Daryll Harrison, Tom K. Woo, and Tom ZieglerCite this: Organometallics 1995, 14, 4, 2018–202…

Organometallic Complex Synthesis and CatalysisChemical Synthesis and AnalysisDendrimers and Hyperbranched Polymers

Bacterial adhesion to hydroxyl- and methyl-terminated alkanethiol self-assembled monolayers

K. Wiencek、Madilyn Fletcher1995-04-01Journal of Bacteriology

The attachment of bacteria to solid surfaces is influenced by substratum chemistry, but to determine the mechanistic basis of this relationship, homogeneous, well-defined substrata are required. Self-assembled monolayers (SAMs) were constructed from alkanethiols to produce a range of substrata with different exposed f…

Advanced biosensing and bioanalysis techniquesPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

A Model for Antiplasticization in Polystyrene

S. L. Anderson、Eric A. Grulke、P. T. DeLassus 等 6 位作者1995-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA Model for Antiplasticization in PolystyreneS. L. Anderson, E. A. Grulke, P. T. DeLassus, P. B. Smith, C. W. Kocher, and B. G. LandesCite this: Macromolecules 1995, 28, 8, 2944–2954Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Science and PVC

Radical Carbonylation of Alkanes via Polyoxotungstate Photocatalysis

B. Scott Jaynes、Craig L. Hill1995-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRadical Carbonylation of Alkanes via Polyoxotungstate PhotocatalysisB. Scott Jaynes and Craig L. HillCite this: J. Am. Chem. Soc. 1995, 117, 16, 4704–4705Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissue 1 April 1995https:/…

Polyoxometalates: Synthesis and ApplicationsCarbon dioxide utilization in catalysisChemical Synthesis and Reactions

High-efficiency metallic diffraction gratings for laser applications

Robert Boyd、Jerald A. Britten、D. Decker 等 7 位作者1995-04-01Applied Optics

The design and fabrication of large-area, high-efficiency metallic gratings for use in high-power laser systems is described. The gratings exhibit a diffraction efficiency in excess of 95% in the m = -1 order (Littrow mount) and have a high threshold for laser damage. Computations and experimental measurements are pre…

Solid State Laser TechnologiesOptical Coatings and GratingsOptical Systems and Laser Technology

Polysilane Dendrimers

Akira Sekiguchi、Masato Nanjo、Chizuko Kabuto 等 4 位作者1995-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolysilane DendrimersAkira Sekiguchi, Masato Nanjo, Chizuko Kabuto, and Hideki SakuraiCite this: J. Am. Chem. Soc. 1995, 117, 14, 4195–4196Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissue 1 April 1995https://doi.org/10.102…

Molecular Junctions and NanostructuresDendrimers and Hyperbranched PolymersFerrocene Chemistry and Applications

V 2 O 5 Xerogel Films as Intercalation Hosts for Lithium: I . Insertion Stoichiometry, Site Concentration, and Specific Energy

H. ‐K. Park、W. H. Smyrl、Michael D. Ward1995-04-01Journal of The Electrochemical Society

Li is intercalated into (XRG) films up to a stoichiometry of . The spin‐coated films are highly reversible hosts for Li and do not support cointercalation of solvent molecules. The specific energy , and specific capacity are higher than any reported previously for xerogel materials or for other vanadium oxides. It is…

Transition Metal Oxide NanomaterialsPolyoxometalates: Synthesis and Applications

Water-Soluble Poly(aniline-co-o-anthranilic acid) Copolymers

My T. Nguyên、Arthur F. Diaz1995-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTWater-Soluble Poly(aniline-co-o-anthranilic acid) CopolymersMy T. Nguyen and Arthur F. DiazCite this: Macromolecules 1995, 28, 9, 3411–3415Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissue 1 April 1995https://pubs.acs.org/d…

Advanced Polymer Synthesis and CharacterizationMesoporous Materials and CatalysisDendrimers and Hyperbranched Polymers

Nonstandard relaxation behavior in ionically conducting materials

Philipp Maass、Martin S. Meyer、Armin Bunde1995-04-01Physical review. B, Condensed matter

We investigate by Monte Carlo simulations the diffusion of ions in ordered and structurally disordered lattices, where the Coulomb interaction between the mobile ions is explicitly taken into account. Results for tracer diffusion, conductivity, the diffusion-induced spin-lattice relaxation rate, and the incoherent int…

Material Dynamics and PropertiesIonic liquids properties and applicationsElectrochemical Analysis and Applications

Influence of Alumina Reaction Tube Impurities on the Oxidation of Chemically‐Vapor‐Deposited Silicon Carbide

Elizabeth J. Opila1995-04-01Journal of the American Ceramic Society

Pure coupons of chemically vapor deposited (CVD) SiC were oxidized for 100 h in dry flowing oxygen at 1300°C. The oxidation kinetics were monitored using thermogra‐vimetry (TGA). The experiments were first performed using high‐purity alumina reaction tubes. The experiments were then repeated using fused quartz reactio…

Advanced ceramic materials synthesisSemiconductor materials and devicesHigh-Temperature Coating Behaviors

Novel Blends of Hyperbranched Polyesters and Linear Polymers

Dennis J. Massa、K. A. Shriner、S. Richard Turner 等 4 位作者1995-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNovel Blends of Hyperbranched Polyesters and Linear PolymersD. J. Massa, K. A. Shriner, S. R. Turner, and B. I. VoitCite this: Macromolecules 1995, 28, 9, 3214–3220Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissue 1 April 1…

Dendrimers and Hyperbranched PolymersFerrocene Chemistry and ApplicationsSynthesis and Characterization of Heterocyclic Compounds

A phase field model of capillarity

L. K. Antanovskiĭ1995-04-01Physics of Fluids

The phenomenological derivation of a phase field model of capillarity that accounts for the structure of an interfacial layer formed by two immiscible incompressible liquids is addressed. A rheological expression for the reversible component of capillary stresses is obtained in terms of the free energy of a binary flu…

Solidification and crystal growth phenomenaFluid Dynamics and Thin Filmsnanoparticles nucleation surface interactions

Refined treatment of the model of linearly coupled anharmonic oscillators and its application to the temperature dependence of the zone-center soft-mode frequencies ofKTaO3andSrTiO3

H. Vogt1995-04-01Physical review. B, Condensed matter

The temperature behavior of the zone-center soft modes of ${\mathrm{KTaO}}_{3}$ and ${\mathrm{SrTiO}}_{3}$ is remeasured betwen 5 and 300 K by the technique of hyper-Raman spectroscopy, the experimental errors of soft-mode frequency and damping constant being reduced to below \ifmmode\pm\else\textpm\fi{}1 ${\mathrm{cm…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Chemical Compatibility between Strontium‐Doped Lanthanum Manganite and Yttria‐Stabilized Zirconia

Guido Stochniol、E. Syskakis、Aristides Naoumidis1995-04-01Journal of the American Ceramic Society

Equimolar powder mixtures and multilayer pellets of single‐phase Sr‐doped lanthanum manganite perovskite materials La y‐x Sr x MnO 3 with La content y = 1 and 0.95 and Sr content 0 ≤ x ≤ 0.5 were annealed in air with 8 mol% Y 2 O 3 ‐ZrO 2 at 1470 K, up to 400 h and at 1670 K. up to 200 h. X‐ray diffraction and electro…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Surface Structure and Reactivity in the Cyclization of Acetylene to Benzene with Pd Overlayers and Pd/Au Surface Alloys on Au{111}

Christopher J. Baddeley、R. Mark Ormerod、A. Stephenson 等 4 位作者1995-04-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSurface Structure and Reactivity in the Cyclization of Acetylene to Benzene with Pd Overlayers and Pd/Au Surface Alloys on Au{111}Christopher J. Baddeley, R. Mark Ormerod, Andrew W. Stephenson, and Richard M. LambertCite this: J. Phys. Chem. 1995, 99, 14, 5146–5151Publicatio…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Substituent Effects on Valence Ionization Potentials of Free Base Porphyrins: A Local Density Functional Study

Abhik Ghosh1995-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSubstituent Effects on Valence Ionization Potentials of Free Base Porphyrins: A Local Density Functional StudyAbhik GhoshCite this: J. Am. Chem. Soc. 1995, 117, 16, 4691–4699Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissue…

Advanced Chemical Physics StudiesPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies

Adsorption of Hydrophilic-Hydrophobic Block Copolymers on Silica from Aqueous Solutions

Catherine Amiel、Mohan Sikka、James Schneider 等 6 位作者1995-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAdsorption of Hydrophilic-Hydrophobic Block Copolymers on Silica from Aqueous SolutionsCatherine Amiel, Mohan Sikka, James W. Schneider Jr., Yi-Hua Tsao, Matthew Tirrell, and Jimmy W. MaysCite this: Macromolecules 1995, 28, 9, 3125–3134Publication Date (Print):April 1, 1995P…

Diatoms and Algae Research

Metallomesogenic Polymers

Luís Oriol、José Luís Serrano1995-04-01Advanced Materials

Processible, molecularly ordered metal‐containing systms result when metallomesogens, liquid crystalline systems containing a metal atom, are integrated into the structure of a plymer (see Figure). The structural design of metallomesogenic polymers is reviewed and the potential applications of these interesting materi…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingSilicone and Siloxane Chemistry

Polyaniline: conformational changes induced in solution by variation of solvent and doping level

Jamshid K. Avlyanov、Yonggang Min、Alan G. MacDiarmid 等 4 位作者1995-04-01Synthetic Metals

The reduced viscosity of mixtures of polyaniline (emeraldine base, EB) and d,l-camphorsulfonic acid (HCSA) in solutions of m-cresol or chloroform (or in mixtures of these solvents) was investigated. Viscosity measurements as a function of (a) increasing m-cresol content in the mixed solvent for a fully protonated ‘EBH…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Luminescent Platinum(II) Complexes of Quinoxaline-2,3-dithiolate

Scott D. Cummings、Richard Eisenberg1995-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLuminescent Platinum(II) Complexes of Quinoxaline-2,3-dithiolateScott D. Cummings and Richard EisenbergCite this: Inorg. Chem. 1995, 34, 8, 2007–2014Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissue 1 April 1995https://pubs…

Organic Light-Emitting Diodes ResearchMolecular Junctions and NanostructuresOrganic and Molecular Conductors Research