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Preparation and characterization of fluorine‐containing aromatic condensation polymers. I. Preparation and characterization of fluorine‐containing polycarbonate and copolycarbonates by two‐phase phase‐transfer‐catalyzed polycondensation of 2,2‐bis (4‐hydroxyphenyl)‐1,1,1,3,3,3‐hexafluoropropane and/or 2,2‐bis (4‐hydroxyphenyl)propane with trichloromethyl chloroformate

Yasuo Saegusa、Minoru Kuriki、Akihiro Kawai 等 4 位作者1990-11-01Journal of Polymer Science Part A Polymer Chemistry

Abstract A series of fluorine‐containing homopolycarbonate and copolycarbonates with a wide range of unit ratio were synthesized by the two‐phase phase‐transfer‐catalyzed plycondensation of 2,2‐bis (4‐hydroxyphenyl)‐1,1,1,3,3,3‐hexafluoropropane (Bisphenol AF) and/or 2,2‐bis (4‐hydroxy‐phenyl) propane (Bisphenol A) wi…

Surface Modification and SuperhydrophobicityMembrane Separation and Gas TransportSynthesis and properties of polymers

Structural and spectral consequences of ion pairing. 4. Theoretical study of alkali metal tetrafluoroborates (M+BF4-; M = lithium, sodium, potassium, and rubidium)

Joseph S. Francisco、Ian H. Williams1990-11-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructural and spectral consequences of ion pairing. 4. Theoretical study of alkali metal tetrafluoroborates (M+BF4-; M = lithium, sodium, potassium, and rubidium)Joseph S. Francisco and Ian H. WilliamsCite this: J. Phys. Chem. 1990, 94, 23, 8522–8529Publication Date (Print)…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

New columnar liquid crystals Correlation between molecular structure and mesomorphic behaviour

Stefanio Bonsignore、G. Cometti、Enrico Dalcanale 等 4 位作者1990-11-01Liquid Crystals

The effect of molecular structural changes on the mesomorphic nature of a new class of macrocyclic columnar liquid crystal is reported. Twenty-six new compounds with general molecular structure I were prepared, characterized and compared. Only dodecasubstituted ester derivatives 2d-h exhibit thermotropic mesophases. T…

Liquid Crystal Research Advancements

Polysaccharide Effects on Cross‐Flow Microfiltration of Two Red Wines with a Microporous Alumina Membrane

Marie‐Pierre Belleville、Jean Marc Brillouet、B. TARODO DE LA FUENTE 等 4 位作者1990-11-01Journal of Food Science

ABSTRACT Two red wines, from the same cultivar, differing by polysaccharide content were filtered using cross‐flow microfiltration with an alumina membrane, pore size 0.2 μm. Filtration flow rates were different. The wine richest in polysaccharides (A) showed a typical external fouling profile with progressive stabili…

Membrane Separation TechnologiesElectrospun Nanofibers in Biomedical ApplicationsPlant Surface Properties and Treatments

Copper oxide thin-film growth using an oxygen plasma source

P. Luzeau、Xiang Xu、M. Laguës 等 9 位作者1990-11-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

We present measurements of the oxidation level (Cu+ and Cu2+ concentration) of copper thin films deposited using a new type of oxygen plasma source. This oxygen plasma source is operated under ultrahigh vacuum, and allows one to oxidize copper up to nearly pure Cu2+ oxide at rather low temperature (<500 °C) and…

ZnO doping and propertiesSemiconductor materials and devicesCopper-based nanomaterials and applications

The crystal structure of berlinite AIPO4 at high pressure

Erik C. Sowa、J. Macavei、H. Schultz1990-11-01Zeitschrift für Kristallographie - Crystalline Materials

La variete quartz du AlPO 4 cristallise dans P3 1 21 avec a=4,941 et c=10,940 A dans des conditions normales et a=4,605 et c=10,558 A a une pression de 8,51 GPa. L'augmentation de la presion entraine l'augmentation du rapport c/a et la diminution des angles (Al-O-P). Le changement du mode d'empilement de l'oxygene ind…

Glass properties and applicationsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Sensitivity of liquid bridges subject to axial residual acceleration

Yiqiang Zhang、J. Iwan D. Alexander1990-11-01Physics of Fluids A Fluid Dynamics

It has become evident that the float zone crystal growth method and isothermal liquid bridges may be very sensitive to the residual acceleration environment of a spacelab. Indeed, the shape equilibria show a high degree of sensitivity and, thus, even the small steady acceleration associated with the effective low grav…

Solidification and crystal growth phenomenaGeomagnetism and Paleomagnetism StudiesCharacterization and Applications of Magnetic Nanoparticles

Polyarylenes and poly(arylenevinylene)s, 3. Oligomeric model compounds for poly(9,10‐anthrylenevinylene)

Hans‐Peter Weitzel、Angelika Bohen、Kläus Müllen1990-11-01Die Makromolekulare Chemie

Abstract Some reactions for the synthesis of poly(phenylenevinylene), PPV, are examined for their capability to form poly(9,10‐anthrylenevinylene). The reasons for the failure of these reactions are described. Soluble oligomers with up to seven anthracene units are synthesized. The properties of the oligomers are stud…

Inorganic and Organometallic ChemistryMaterial Properties and ApplicationsSynthesis of Tetrazole Derivatives

Synthesis of 2-(alkanoyloxy)-5-alkoxytropones. Novel monocyclic rod-type liquid crystals

Akira Mori、Hitoshi Takeshita、Katsuhiko Kida 等 4 位作者1990-11-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis of 2-(alkanoyloxy)-5-alkoxytropones. Novel monocyclic rod-type liquid crystalsAkira Mori, Hitoshi Takeshita, Katsuhiko Kida, and Minoru UchidaCite this: J. Am. Chem. Soc. 1990, 112, 23, 8635–8636Publication Date (Print):November 1, 1990Publication History Published…

Liquid Crystal Research AdvancementsMolecular spectroscopy and chiralitySynthesis and Reactivity of Sulfur-Containing Compounds

Photoluminescence-based correlation of semiconductor electric field thickness with adsorbate Hammett substituent constants. Adsorption of aniline derivatives onto cadmium selenide

Catherine J. Murphy、George C. Lisensky、Larry K. Leung 等 5 位作者1990-11-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotoluminescence-based correlation of semiconductor electric field thickness with adsorbate Hammett substituent constants. Adsorption of aniline derivatives onto cadmium selenideCatherine J. Murphy, George C. Lisensky, Larry K. Leung, Glen R. Kowach, and Arthur B. EllisCite…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesAmmonia Synthesis and Nitrogen Reduction

Thermal Analysis of Precursors of Barium Titanate Prepared by Coprecipitation

Tsang‐Tse Fang、Horng‐Bin Lin、Jim‐Bin Hwang1990-11-01Journal of the American Ceramic Society

Thermal analysis was performed on coprecipitated materials and on individual components. The detailed decomposition schemes of coprecipitates and individual components are proposed and discussed. According to the proposed decomposition schemes, the values of the observed weight loss are in good agreement with those of…

Calcium Carbonate Crystallization and InhibitionThermal and Kinetic AnalysisChemical Synthesis and Characterization

Composition and structure of boron nitride films deposited by chemical vapor deposition from borazine

John Kouvetakis、V. Patel、Chadd Miller 等 4 位作者1990-11-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

The composition and structure of boron nitride films prepared by thermal and plasma enhanced chemical vapor deposition (CVD) using borazine as a precursor have been studied. Thermal CVD at temperatures between 475 and 550 °C using either a hot-wall or cold-wall reactor results in amorphous boron-rich films of approxim…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsBoron and Carbon Nanomaterials Research

A novel synthetic route to scandium porphyrin derivatives and the first structurally characterized metalloporphyrin-.eta.5-cyclopentadienyl sandwich compound

John Arnold、Caroline G. Hoffman1990-11-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA novel synthetic route to scandium porphyrin derivatives and the first structurally characterized metalloporphyrin-.eta.5-cyclopentadienyl sandwich compoundJohn Arnold and Caroline G. HoffmanCite this: J. Am. Chem. Soc. 1990, 112, 23, 8620–8621Publication Date (Print):Novem…

Porphyrin and Phthalocyanine ChemistrySynthetic Organic Chemistry MethodsMetal-Catalyzed Oxygenation Mechanisms

Glass transition and self-consistent mode-coupling theory

Shankar P. Das1990-11-01Physical Review A

The implications of a self-consistent mode-coupling theory of dense fluids for the liquid-glass transition are considered. First, we show that when higher-order corrections are ignored from our model, there is a dynamic transition of the hard-sphere fluid at an intermediate density to an ideal glassy phase. This is in…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Densification Behavior of Single‐Crystal and Polycrystalline Spherical Particles of Zirconia

Elliott B. Slamovich、Frederick F. Lange1990-11-01Journal of the American Ceramic Society

Micrometer size polydispersed spheres of zirconia were produced via electrostatic atomization and pyrolysis of aqueous zirconium acetate‐yttrium acetate precursors. Varying the precursor composition in the ZrO 2 ‐rich region of the ZrO 2 ‐Y 2 O 3 binary system resulted in the production of either single‐crystal (0 and…

Catalytic Processes in Materials ScienceCoagulation and Flocculation StudiesPickering emulsions and particle stabilization

Crystallization kinetics and melting of caprolactone random copolymers

Louise Goulet、Robert E. Prud’homme1990-11-01Journal of Polymer Science Part B Polymer Physics

Abstract Spherulitic growth rates and overall rates of crystallization of poly(ε‐caprolactone‐co‐ε‐methyl‐ε‐caprolactone), poly(CL‐co‐MCL), were analyzed over a composition range from pure poly (ε‐caprolactone) (PCL) to a copolymer containing 40% MCL with an equation which contains the classical nucleation and transpo…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Influence of preparation method on the metal cluster size of platinum/ZSM-5 catalysts as studied with EXAFS

F.W.H. Kampers、C.W.R. Engelen、J.H.C. van Hooff 等 4 位作者1990-11-01The Journal of Physical Chemistry

The size of Pt particles introduced into the channels of ZSM-5 zeolite by two different preparation methods has been studied\nwith EXAFS. ZSM-5 was loaded with 2 wt 5% Pt by ion exchange and by impregnation. By careful calcination of the catalysts\nthe dispersion was maintained. The EXAFS measurements were performed o…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Studies of third-order optical nonlinearities of model compounds containing benzothiazole, benzimidazole and benzoxazole units

Mingtang Zhao、Marek Samoć、Paras N. Prasad 等 10 位作者1990-11-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStudies of third-order optical nonlinearities of model compounds containing benzothiazole, benzimidazole and benzoxazole unitsMingtang Zhao, Marek Samoc, Paras N. Prasad, Bruce A. Reinhardt, Marilyn R. Unroe, Mark Prazak, Robert C. Evers, James J. Kane, Chetan Jariwala, and…

Nonlinear Optical Materials ResearchPhotochemistry and Electron Transfer StudiesNonlinear Optical Materials Studies

Microminiaturization of electron optical systems

T. H. P. Chang、D. P. Kern、L. P. Muray1990-11-01Journal of Vacuum Science & Technology B Microelectronics Processing and Phenomena

The performance of miniaturized electron optical systems comprising a field emission microsource and a microlens for probe forming has been studied. A complete system measuring millimeters in length and diameter with performance exceeding that of a conventional system over a wide range of potentials (100 V–10 kV) and…

Advancements in Photolithography TechniquesElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

The phase diffusion and mean drift equations for convection at finite Rayleigh numbers in large containers

Alan C. Newell、T. Passot、M. Souli1990-11-01Journal of Fluid Mechanics

We derive the phase diffusion and mean drift equations for the Oberbeck–Boussinesq equations in large-aspect-ratio containers. We are able to recover all the long-wave instability boundaries (Eckhaus, zigzag, skew-varicose) of straight parallel rolls found previously by Busse and his colleagues. Moreover, the developm…

Theoretical and Computational PhysicsSolidification and crystal growth phenomenaCharacterization and Applications of Magnetic Nanoparticles