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Bonding in silicates; investigation of the Si L (sub 2,3) edge by parallel electron energy-loss spectroscopy

L. A. J. Garvie、Peter R. Buseck1999-06-01American Mineralogist

For two series of aluminosilicate glasses on the SiO 2 -NaAlO 2 and SiO 2 -CaAl 2 O 4 joins, 29 Si magic- angle-spinning (MAS) NMR spectra were measured. Systematic variations in peak positions and widths with composition are closely related to the extent of ordering of Si and Al cations. A statistical thermodynamic m…

Glass properties and applicationsNuclear materials and radiation effectsX-ray Diffraction in Crystallography

Anodizing of aluminium alloys

G.E. Thompson、H. Habazaki、Ken‐ichi Shimizu 等 7 位作者1999-06-01Aircraft Engineering and Aerospace Technology

Anodizing is used widely in the surface treatment of aluminium alloys for aerospace applications. Considers recent advances in understanding of the influences of alloying elements in anodizing of aluminium alloys and, in particular, their applicability to second phase particles during anodizing of commercial alloys. T…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityAnodic Oxide Films and Nanostructures

Voronoi-Delaunay analysis of voids in systems of nonspherical particles

Valériy Luchnikov、N. N. Medvedev、Luc Oger 等 4 位作者1999-06-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

The Voronoi network is known to be a useful tool for the structural description of voids in the packings of spheres produced by computer simulations. In this article we extend the Voronoi-Delaunay analysis to packings of nonspherical convex objects. Main properties of the Voronoi network, which are known for systems o…

Material Dynamics and PropertiesTheoretical and Computational PhysicsTopological and Geometric Data Analysis

Diffusion of low molecular weight siloxane from bulk to surface

Hiroya Homma、T. Kuroyagi、Kunikazu Izumi 等 6 位作者1999-06-01IEEE Transactions on Dielectrics and Electrical Insulation

Silicone-based materials for outdoor insulators have the advantage that low molecular weight (LMW) components migrate through the material and coat the surface, thereby restoring hydrophobicity over a period of hours. By measuring the IR absorption of siloxane migrating to the silicone surface through a thin carbon co…

Surface Modification and SuperhydrophobicityHigh voltage insulation and dielectric phenomenaAnalytical Chemistry and Sensors

Streamer propagation along insulating surfaces

N.L. Allen、Pantelis N. Mikropoulos1999-06-01IEEE Transactions on Dielectrics and Electrical Insulation

Results concerning the propagation of streamers along insulating surfaces under uniform electric field are presented. The basic properties of streamers, namely the electric field required for a stable propagation and the propagation velocity, have been measured and compared with propagation in air alone as a reference…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationThermal Analysis in Power Transmission

Hall Effect Measurements of Surface Conductive Layer on Undoped Diamond Films in NO2 and NH3 Atmospheres

Ri Sung Gi、Kazuhiro Tashiro、Seiichi Tanaka 等 7 位作者1999-06-01Japanese Journal of Applied Physics

In order to clarify the mechanism of change in resistance of the surface conductive layer exposed to oxidizing and reducing gases, the Hall effect measurements of the surface conductive layer on as-grown undoped diamond films in NO 2 and NH 3 gas atmospheres were carried out. It was found that holes were generated in…

Diamond and Carbon-based Materials ResearchElectron and X-Ray Spectroscopy TechniquesSurface Roughness and Optical Measurements

In vitroAnti-Helicobacter pylori Activity of Some Flavonoids and Their Metabolites

Eun‐Ah Bae、Myung Woul Han、Dong‐Hyun Kim1999-06-01Planta Medica

The inhibitory effect of flavonoids and phenolic acids, which could be transformed from flavonoids by human intestinal microflora, on the growth of Helicobacter pylori (HP) was investigated. Ponciretin, hesperetin, naringenin and diosmetin were active against HP. Among them, ponciretin was the most potent and its MIC…

Helicobacter pylori-related gastroenterology studiesMicrobial Applications in Construction MaterialsPhytochemistry and Bioactive Compounds

The Organic‐Inorganic Polyaniline / V 2 O 5 System. Application as a High‐Capacity Hybrid Cathode for Rechargeable Lithium Batteries

Mónica Lira‐Cantú、Pedro Gómez‐Romero1999-06-01Journal of The Electrochemical Society

The application of a hybrid polyaniline / V 2 O 5 cathode material in reversible lithium electrochemical cells is reported. We have studied the influence of synthesis conditions and subsequent treatments of this hybrid electrode under oxygen in order to optimize its performance as a lithium‐insertion cathode. The temp…

Supercapacitor Materials and FabricationConducting polymers and applicationsTransition Metal Oxide Nanomaterials

Novel Poly(arylene ether)s with Pendent Trifluoromethyl Groups

Susanta Banerjee、Gerhard Maier、Martin Bürger1999-06-01Macromolecules

Six novel perfluoroalkyl-activated bishalo monomers 4a,b − 6a,b have been synthesized successfully using Pd(0)-catalyzed cross-coupling reaction of 4-chloro- or 4-fluoro-3-trifluoromethylphenylboronic acid with 1,4-dibromobenzene, 2,6-dibromopyridine, and 2,5-dibromothiophene. These monomers were converted to poly(ary…

Catalytic Cross-Coupling ReactionsFluorine in Organic ChemistrySynthesis and properties of polymers

Smectite transformation in high molar KOH solutions

Andreas Bauer、B. Velde1999-06-01Clay Minerals

Abstract Batch reactor experiments were performed at 35°C and 80°C to determine the effect of high molar KOH solutions on the mineralogy and solution chemistry of two different smectites. The Ceca smectite is a nearly pure montmorillonite, and the Ibeco clay has a significant component of 35% beidellitic charge. Each…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisClay minerals and soil interactions

Solid Oxide Fuel Cells with Doped Lanthanum Gallate Electrolyte and LaSrCoO3 Cathode, and Ni‐Samaria‐Doped Ceria Cermet Anode

Radenka Marić、Satoshi Ohara、Takehisa Fukui 等 7 位作者1999-06-01Journal of The Electrochemical Society

The electrode performance of a single solid‐fuel cell (SOFC) was evaluated using a 500 μm thick (LSGM) as the electrolyte membrane. A doped lanthanum cobaltite, was selected as the cathode material, and a samaria‐doped ceria‐NiO composite powder was used as the anode material. The spray‐pyrolysis method was applied fo…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Al-O-Al oxygen sites in crystalline aluminates and aluminosilicate glasses; high-resolution oxygen-17 NMR results

Jonathan F. Stebbins、Sung Keun Lee、Jane V. Oglesby1999-06-01American Mineralogist

We report paragenesis and chemistry of a new occurrence of the rare trioctahedral Al-rich sodium mica preiswerkite. The preiswerkite occurs in a tourmaline-biotite-scapolite rock in the contact zone of a gabbroic boudin surrounded by Proterozoic metasediments near the Blengsvatn, Bamble sector, southern Norway. The pr…

Glass properties and applicationsClay minerals and soil interactionsNMR spectroscopy and applications

Effects of Hydrogen on Semiconductivity of Passive Films and Corrosion Behavior of 310 Stainless Steel

Mingzhang Yang、Jing‐Li Luo、Qimeng Yang 等 6 位作者1999-06-01Journal of The Electrochemical Society

The effects of hydrogen on the semiconductive properties and compositions of passive films on AISI 310 stainless steel (310 SS) and their corrosion behavior were investigated by Mott‐Schottky plot, polarization, noise resistance analyses, and secondary ion mass spectrometry (SIMS). The results indicate that the suscep…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing Techniques

Model for single-particle dynamics in supercooled water

Chen Sh、C. Y. Liao、Francesco Sciortino 等 5 位作者1999-06-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We analyze a set of 10 M-step molecular dynamics (MD) data of low-temperature SPC/E model water with a phenomenological analytical model. The motivation is twofold: to extract various k-dependent physical parameters associated with the single-particle or the self-intermediate scattering functions (SISFs) of water at a…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Removal of Endotoxin during Purification of Poly(3-Hydroxybutyrate) from Gram-Negative Bacteria

Sang Yup Lee、Jong‐il Choi、Kyuboem Han 等 4 位作者1999-06-01Applied and Environmental Microbiology

Poly(3-hydroxybutyrate) (PHB) was produced by cultivating several gram-negative bacteria, including Ralstonia eutropha, Alcaligenes latus, and recombinant Escherichia coli. PHB was recovered from these bacteria by two different methods, and the endotoxin levels were determined. When PHB was recovered by the chloroform…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionBiopolymer Synthesis and Applications

Anomalous percolation transition in carbon-black–epoxy composite materials

Lionel Flandin、Torsten Prasse、Ruediger Schueler 等 6 位作者1999-06-01Physical review. B, Condensed matter

ac and electrical properties of carbon-black--epoxy composites measured in the frequency range of 100 Hz to 1 MHz are reported. Experimental results are in remarkable disagreement with the predictions of the statistical percolation theory for real and imaginary parts of the conductivity. They both exhibited, in partic…

Carbon Nanotubes in CompositesAdvanced Sensor and Energy Harvesting MaterialsHigh voltage insulation and dielectric phenomena

Gelatin Behaviour in Dilute Aqueous Solution: Designing a Nanoparticulate Formulation

Claude Farrugia、Michael J. Groves1999-06-01Journal of Pharmacy and Pharmacology

Although it has been claimed that nanoparticles can be produced from gelatin, a naturally occurring polypeptide, the commercial conversion of animal collagen to gelatin results in a heterogeneous product with a wide molecular-weight range. This is probably responsible for the widely observed variation in the experimen…

Proteins in Food SystemsCollagen: Extraction and Characterization

Interaction between Salts (NaCl, CsCl) and Calcium Silicate Hydrates (C−S−H)

H. Viallis、P. Faucon、Jean‐Claude Petit 等 4 位作者1999-06-01The Journal of Physical Chemistry B

High resolution 29 Si, 23 Na, and 133 Cs solid-state NMR spectroscopy was used to study the interaction of sodium and cesium chloride salts with calcium silicate hydrates (C−S−H), the main components of hydrated Portland cement. Spectra were collected at different levels of moisture and suggested that Cs + and Na + in…

Glass properties and applicationsClay minerals and soil interactionsChemical Synthesis and Characterization

Serial bideposition of anisotropic thin films with enhanced linear birefringence

Ian J. Hodgkinson、Qi Wu1999-06-01Applied Optics

We describe a serial bideposition technique in which a tilted substrate is rotated stepwise by half a turn about a normal axis during the evaporation of a metal oxide from a single electron-beam source. Coatings formed by the new method develop a columnar nanostructure that is perpendicular to the substrate and has gr…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Elastic modulus of the crystalline regions of chitin and chitosan

Takashi Nishino、Ryousuke Matsui、Katsuhiko Nakamae1999-06-01Journal of Polymer Science Part B Polymer Physics

The elastic moduli El of the crystalline regions of α-chitin and chitosan in the direction parallel to the chain axis were measured by X-ray diffraction. The El values were 41 GPa for α-chitin, and 65 GPa for chitosan, respectively, at 20°C. The contracted skeletons of α-chitin and chitosan are the key factor for the…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced CompositesAdvanced Cellulose Research Studies