Materials Literature
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Abstract We have synthesized a series of fully aliphatic polyimides (APIs) from bicyclo[2,2,2]oct‐7‐ene‐2,3,5,6‐tetracarboxylic dianhydride (BOCA) and various aliphatic diamines, including linear aliphatic, flexible alicyclic, and rigid adamantyl diamines. We performed the polymerization reactions using one‐step synth…
A new nanophase-separated structure with parallel double periodicity has been identified for an undecablock terpolymer in bulk. The polymer includes two long poly(2-vinypyridine) ($P$) chains on each end, with five short polyisoprene ($I$) and four short polystyrene ($S$) chains at the center. This polymer exhibits a…
Abstract The present article summarizes an experimental study on the mechanical and dynamic mechanical behavior of sisal fiber reinforced HDPE composites. Variations in mechanical strength, storage modulus ( E ′), loss modulus ( E ″), and damping parameter (tan δ) with the addition of fibers and coupling agents were i…
Microphase-ordered block copolymers serve as model systems to elucidate the potential of molecular self-assembly and organic templates to fabricate functionalized polymeric materials. Both aspects are related to the incorporation of secondary species such as low-molar-mass compounds or nanoparticles within the copolym…
The nanocluster literature contains a wide variety of nanocluster stabilizing agents. In addition to the plethora of putative stabilizing additives, 12 claims appear of "solvent-only" stabilization of transition-metal nanoclusters-a hypothesis that is tested for the first time as part of the present studies. When the…
Abstract Electrospinning of poly(3‐hydroxybutyrate) (PHB), poly(3‐hydroxybutyrate‐ co ‐3‐hydroxyvalerate) (PHBV), and their blends was first carried out in chloroform at 50 °C on a stationary collector. The average diameter of the as‐spun fiber from PHB and PHBV solutions decreased with increasing collection distance…
An exceptional evaporation pattern is observed on special micro–nano hierarchically structured superhydrophobic natural lotus and biomimetic polymer surfaces. The evaporation process is simulated by the ellipsoidal cap-geometry model, which fits the experimental data well. The picture shows the contact angle (CA) and…
Ultrathin polyelectrolyte gel pH-responsive membranes with sub-micrometer pore size are synthesized on planar substrates. The membranes are thin porous films made of a crosslinked polyelectrolyte that can be easily transferred onto various porous and nonporous substrates for the fabrication of devices with pH-controll…
We present evidence via molecular simulation that the supercooled fluid states of SPC/E water as well as the "repulsive" and "attractive" supercooled fluid states of a recently introduced model for colloids with short-ranged attractions are characterized by the same functional relationship between self-diffusivity and…
Abstract The crystallization behavior of PVDF (poly (vinylidene) fluoride) in PVDF‐dimethylphthalate(DMP) system was investigated in the liquid–liquid (L–L) phase separation region, solid–liquid (S–L) phase separation region and different quenching conditions via thermally induced phase separation (TIPS). Differential…
The dispersion of small-diameter single-walled carbon nanotubes (SWNTs) produced by the CoMoCAT method in tetrahydrofuran (THF) with the use of amine was studied. The absorption, photoluminescence, and Raman spectroscopies showed that the dispersion and centrifugation process leads to an effective separation of metall…
Composite nanostructures (approximately 200 nm wide and several micrometers long) of metal and polyaniline (PANI) in two new variations of core-shell (PANI-Au) and segmented (Au-PANI and Ni-Au-PANI) architectures were fabricated electrochemically within anodized aluminum oxide (AAO) membranes. Control over the structu…
Abstract Thermal analysis (TGA and DTA) of samples of PAA, PVP, PAA–PVP complexes, containing different weight fractions of PAA and ternary polymer–metal–polymer complexes, were studied. The activation energy parameters for the thermal degradation were also calculated. The study of the effect of FeCl 3 , NiCl 2 , and…
The synthesis and structural, photophysical, and second-order nonlinear optical (NLO) properties of a novel lanthanide terpyridyl-like complex family LLn(NO(3))(3) (Ln = La, Gd, Dy, Yb, and Y) are reported. The isostructural character of this series in solution and in the solid state has been established on the basis…
Abstract In this letter, the authors present the design of a resonant microwave absorber made by a proper array of split ring resonators (SRRs). The physical mechanism behind the operation of the proposed component is based on the SRR resonance, arising when the structure is excited by a properly polarized impinging w…
We compute from first principles the infrared dispersion of the nonlinear susceptibility $χ^{(2)}$ in zincblende semiconductors. At terahertz frequencies the nonlinear susceptibility depends not only on the purely electronic response $χ^{(2)}_{\infty}$, but also on three other parameters $C_1$, $C_2$ and $C_3$ describ…
We investigate the peel front dynamics and acoustic emission of an adhesive tape within the context of a recent model by including an additional dissipative energy that mimics bursts of acoustic signals. We find that the nature of the peeling front can vary from smooth to stuck-peeled configuration depending on the va…
The dispersion relations for collective magnon modes for square-planar arrays of vortex-state magnetic dots, having closure magnetic flux are calculated. The array dots have no direct contact between each other, and the sole source of their interaction is the magnetic dipolar interaction. The magnon formalism using Bo…
We present a comparative study of the coupled-tetrahedra quantum spin systems Cu2Te2O5X2, X=Cl, Br (Cu-2252(X)) and the newly synthesized Cu4Te5O12Cl4 (Cu-45124(Cl)) based on ab initio Density Functional Theory calculations. The magnetic behavior of Cu-45124(Cl) with a phase transition to an ordered state at a lower c…
We theoretically study transport properties of a two-dimensional electron system on a hydrogen-passivated Si(111) surface in the field-effect-transistor (FET) configuration. We calculate the density and temperature dependent mobility and resistivity for the recently fabricated Si(111)-vacuum FET by using a semiclassic…