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Metallkomplexe mit 2,2'-Dipyridylamin als Liganden: Kristallstrukturen der Komplexe mit CdX2 (X = Cl, Br, I) und CuCN / Metal Complexes with 2,2'-Dipyridylamine as Ligand: Crystal Structures of the Complexes with CdX2 (X = Cl, Br, I) and CuCN

Joachim Pickardt、B. Staub1999-03-01Zeitschrift für Naturforschung B

Reactions of 2,2′-dipyridylamine (dpyam) with cadmium halides yield crystals of [Cd(dpyam)(H 2 O )Cl 2 ] (1), [Cd(dpyam)Br 2 ] (2), and [Cd(dpyam)I 2 ] (3). With CuCl 2 and KCN a complex [Cu(dpyam )CN] · H 2 O (4) is obtained. Depending on the size of the halide ions the coordination changes from octahedral in 1 to tr…

Metal complexes synthesis and propertiesMagnetism in coordination complexesFerrocene Chemistry and Applications

The Relationship Between In Vitro Drug Dissolution and In Vivo Absorption

Adrian Dunne、John Devane、Tom O’Hara1999-03-01Journal of the Royal Statistical Society Series D (The Statistician)

The rate at which a drug enters the bloodstream is an important characteristic of any drug product because it may have a marked influence on the biological response elicited by the drug. Before entering the bloodstream a solid dosage form (tablet or capsule) must first dissolve and then the drug in solution is absorbe…

Drug Solubulity and Delivery SystemsStatistical Methods in Clinical TrialsCrystallization and Solubility Studies

Electron Energy-Loss Spectroscopy Study of the Metal-Insulator Transition in (V1-xCrx)2O3 (x=0.012)

Hiroyuki Abe Hiroyuki Abe、Masami Terauchi Masami Terauchi、Michiyoshi Tanaka Michiyoshi Tanaka 等 4 位作者1999-03-01Japanese Journal of Applied Physics

Electron energy-loss spectra of (V 1- x Cr x ) 2 O 3 ( x =0.012) at the antiferromagnetic insulating (AFI), paramagnetic metallic (PM) and paramagnetic insulating (PI) phases have been measured using a high-resolution transmission electron energy-loss spectroscopy (EELS) microscope. The changes in the EELS spectra at…

Transition Metal Oxide NanomaterialsAdvanced Condensed Matter PhysicsGa2O3 and related materials

Andisols of the Kitakami mountain range, Northeastern Japan: Their characterization and classification

T. A. Adjadeh、Katsuhiro Inoue1999-03-01Soil Science & Plant Nutrition

Andisols of the Kitakami mountain range were derived from a mixture of tephras and long range eolian dust deposited during the Quaternary. Thus, the relative proportions of the components of the mixture determined the unique properties of the soils. Soils of the northern and central parts of the mountain range were de…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Synthesis and characterization of novel ferroelectric liquid crystals and copolymers containing biphenyl azobenzene and / or phenyl biphenyl carboxylate mesogenic groups

Zusheng Xu1999-03-01Liquid Crystals

Two new ferroelectric liquid crystals, 4-[(S)-1-(ethoxycarbonyl)]ethyl 4-[4-(9-decenyloxy)biphenyl]azobenzoate (10) and its ester analogue 4-[(S)-1-(ethoxycarbonyl)]ethyl {[4-(9-decenyloxy)]biphenyl-4'-yl}carbonyloxybenzoate (17), and side chain polysiloxane copolymers and terpolymers containing various amounts of 10…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsSynthesis and Properties of Aromatic Compounds

Dimer formation of a stilbenesulphonic acid salt in aqueous solution

Jan Alsins、Mikael Björling、István Furó 等 4 位作者1999-03-01Journal of Physical Organic Chemistry

The steady-state and time-resolved fluorescence and 1H NMR spectra of a stilbenesulphonic acid salt, commonly used as an optical brightening agent, was studied as a function of concentration in aqueous solution. The aggregates, formed at higher concentrations, were shown to be predominantly dimers with the central sti…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Stably coalescent stochastic froths

J. M. C. Clark、Vassilis Katsouros1999-03-01Advances in Applied Probability

A model of a stochastic froth is introduced in which the rate of random coalescence of a pair of bubbles depends on an inverse power law of their sizes. The main question of interest is whether froths with a large number of bubbles can grow in a stable fashion; that is, whether under some time-varying change of scale…

Enhanced Oil Recovery TechniquesTheoretical and Computational PhysicsPickering emulsions and particle stabilization

A comparative study of the grain size effects on ferro-para phase transition in barium titanate ceramics

Liliana Mitoşeriu、Vasile Ţura、Constantin Papusoi 等 5 位作者1999-03-01Ferroelectrics

Barium titanate ceramics having grain sizes between 0.5μm and 20μm were used in a comparative investigation of the ferro-para phase transition, by recording the temperature dependencies of the heat capacity and pyrocharge. The experimental results and the theoretical approach suggest that internal stresses are the mai…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisMicrowave Dielectric Ceramics Synthesis

Kikuchi-Band Analysis of X-Ray Photoelectron Diffraction Fine Structure of Si(100) by Precise Angle-Resolved X-Ray Photoelectron Spectroscopy

T. Katayama、Hidekazu Yamamoto、Yoji Mashiko 等 6 位作者1999-03-01Japanese Journal of Applied Physics

X-ray photoelectron diffraction fine structure of Si(100) is studied with precise angle-resolved X-ray photoelectron spectroscopy. Polar-angle intensity distributions of the Si 2p photoelectron emission excited by Al Kα X-rays are measured from H-terminated Si(100) along some azimuthal angles, and are qualitatively in…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Influence of phosphate on zinc reaction in variable charge soils

M. T. Pardo1999-03-01Communications in Soil Science and Plant Analysis

The influence of phosphate (P) on the adsorption‐desorption of zinc (Zn) and on Zn fractions was examined for four variable charge soils. The soils were two kaolinitic Alfisols and two Andisols containing high amount of amorphous materials. Zinc adsorption‐desorption isotherms were produced using a batch protocol invo…

Heavy metals in environmentClay minerals and soil interactionsIron oxide chemistry and applications

Mechanism of organotin stabilization of poly(vinyl chloride). 2: Significance for PVC stabilization of structure and equilibria of alkyltin thioglycolates/chlorides

Michael H. Fisch、Radu Bacaloglu、Keith Biesiada 等 4 位作者1999-03-01Journal of Vinyl and Additive Technology

Abstract The stabilization effect of alkyltin thioglycolates was determined by the measurement of discoloration of PVC formulations. The results were interpreted considering the structure of these compounds, their equilibration with alkyltin chlorides, and their postulated association with chlorine atoms at PVC primar…

Advanced Polymer Synthesis and CharacterizationThermal and Kinetic AnalysisPolymer Science and PVC

A Control-Oriented Carbon Canister Model

In Kwang Yoo、Devesh Upadhyay、Giorgio Rizzoni1999-03-01SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">Carbon canisters have been adapted for automobile use since the early 1970s to control evaporative emissions. Stringent emission regulations and the requirement for an enhanced evaporative emissions test procedure, make this an important issue. The air and evaporative fuel from th…

Catalytic Processes in Materials ScienceVehicle emissions and performance

Measurement of thermal expansion coefficient of substrate GGG and its epitaxial layer YIG

Ruisheng Liang、F.C. Liu1999-03-01Powder Diffraction

A new method is used in measuring the linear thermal expansion coefficients in composite consisting of a substrate Gd 3 Ga 2 Ga 3 O 12 (GGG) and its epitaxial layer Y 3 Fe 2 Fe 3 O 12 (YIG) within the temperature range 13.88 °C–32.50 °C. The results show that the thermal expansion coefficient of GGG in composite is la…

Photonic and Optical DevicesOptical Coatings and GratingsMagneto-Optical Properties and Applications

Gilluyite Tl 2 (As,Sb) 8 S 13 ; reinterpretation of the crystal structure and order-disorder phenomena

Emil Makovicky、T. Balić-Žunić1999-03-01American Mineralogist

The crystal structure of gillulyite Tl 2 (As, Sb) 8 S 13 was reinterpreted based on the average structure determined by Foit et al. (1995). It consists of alternating PbS-like slabs comprised of As-S polyhedra and Tl-bearing slabs with partly zeolitic properties. In the latter, TlS 5 and As 2 S 5 groups alternate regu…

Crystal Structures and PropertiesPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Three‐Dimensional Thoracic Modeling for an Anatomical Compatibility Study of the Implantable Total Artificial Heart

Bin Zhang、Toru Masuzawa、Eisuke Tatsumi 等 7 位作者1999-03-01Artificial Organs

Anatomical compatibility with the thoracic cavity is important in developing a completely implantable total artificial heart (TAH). The purpose of this study was to examine the optimal morphology of our TAH and to develop a computer implantation simulation environment for preoperational discussion. As the first stage,…

Cardiac Valve Diseases and TreatmentsElectrospun Nanofibers in Biomedical ApplicationsCardiac Structural Anomalies and Repair

Production of carbon nanotubes by the solar route

T. Guillard、S. Cetout、Laurent Alvarez 等 8 位作者1999-03-01The European Physical Journal Applied Physics

The high intensity of concentrated solar radiation obtained with the Odeillo (France) solar furnace facilities can be used to produce carbon nanotubes by direct vaporization of carbon bi-metal targets under inert gas atmosphere. Electron microscope pictures and Raman spectra show that the structure of the produced car…

Carbon Nanotubes in CompositesGraphene research and applicationsFiber-reinforced polymer composites

Wave-front control and aberration correction with a diffractive optical element

Salman Noach、Yoel Arieli、Naftali Eisenberg1999-03-01Optics Letters

A method that permits aberration correction and wave-front reshaping with a diffractive optical element (DOE) is described. Two aligned DOE's made of two different dispersive materials are used. The different dispersions of the two materials in addition to freedom in choosing their thicknesses enables the chromatic ab…

Advancements in Photolithography TechniquesAdvanced optical system designOptical Coatings and Gratings

EEMCO guidance for the assessment of skin topography1

Jean Luc Lévêque1999-03-01Journal of the European Academy of Dermatology and Venereology

Abstract Numerous factors can modify the visibility or the actual dimensions of the skin microrelief and wrinkles. To quantify these changes, several methods, including clinical and non‐invasive ones, have been proposed. This article reviews the advantages et drawbacks of all of them and lists some experimental recomm…

Skin Protection and AgingTextile materials and evaluationsSurface Roughness and Optical Measurements

Successive phase transitions in the highly ordered complex perovskite PbLu1/2Nb1/2O3

Yung Park、Kevin M. Knowles、Kurn Cho1999-03-01Phase Transitions

The structural phase transitions and the electrical behaviour of the complex perovskite PbLu1/2Nb1/2O3 have been investigated using X-ray powder diffraction, dielectric constant measurements, differential scanning calorimetry and measurement of the polarisation as a function of applied electric field. The high-tempera…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis