Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
The partial oxidation of propane and the mechanism of the selective catalytic reduction (SCR) of NO by C3H8 over CoO(x)/Al2O3 catalysts were investigated using in situ infrared spectroscopy. Emphases are placed on the formation and reactivity of surface oxygenates during the SCR reaction. The SCR reaction starts with…
Short-range order involves local clusters of atoms that occur either more or less frequently than predicted by a random distribution. Infrared spectroscopy in the principal (OH)-stretching region is sensitive to such local arrangements, and hence the (OH) group can be used as a local probe of short-range arrangements…
Aluminum fluoride (AlF3) was deposited by a resistive heating boat. To obtain a low optical loss and high laser-induced damage threshold (LIDT) at 193 nm, the films were investigated under different substrate temperatures, deposition rates, and annealing after coating. The optical property (the transmittance, refracti…
The deformation of the Mg alloy AZ31 has been investigated in the temperature range from room temperature to 250°C. Microstructural investigation of samples compressed at 150°C showed extensive twinning only in samples where the basal plane normals were initially aligned approximately perpendicular to the compressive…
Long chain aliphatic 1,2-diols like 1,2-hexanediol and 1,2-octanediol can be converted to the corresponding α-hydroxy-alkanoates with total chemoselectivity, in an oxidation catalyzed by an aqueous gold sol under O 2 atmosphere. The sol is stabilized with poly(vinylalcohol), and the reaction is performed in alcohol so…
Carbide-derived carbon (CDC) is a form of carbon produced by reacting metal carbides, such as SiC or TiC, with halogens at temperatures high enough to produce fast kinetics, but too low to permit the rearrangement of the carbon atoms into an equilibrium graphitic structure. The structure of CDC is derivative of the or…
This article describes findings of an investigation of the thin-film assembly of binary metal nanoparticles via interparticle linkages of dicarboxylic acid mediators at selective metal sites. Decanethiol- (DT-) capped gold−silver (Au−Ag) alloy nanoparticles of ∼3-nm core sizes were chosen as a model system because of…
The corrosion and de-adhesion of polymers from reactive metal surfaces will be described in this paper. Corrosion protection by polymeric coatings is mainly due to the electronic structure of the electrified interface, which allows the transfer of electrons but not the transfer of ions, and therefore behaves remarkabl…
The influences of surface roughness on the boundary conditions for a simple fluid flowing over hydrophobic and hydrophilic surfaces are investigated by molecular dynamics (MD) simulation. The degree of slip is found to decrease with surface roughness for both the hydrophobic and hydrophilic surfaces. The flow rates me…
Abstract Acrylonitrile butadiene rubber (NBR)/poly(vinyl chloride) (PVC) alloy, filled with anhydrous copper sulfate (CuSO 4 ) particles, was investigated for the first time. The material could be crosslinked in the existence of CuSO 4 by heat pressing, without any other crosslink agents. The crosslinking in the mater…
Abstract The addition of inorganic filler into commodity plastics has a long history. Today, polymer composites based on nanosized filler are popular among polymer scientists from academia and industries due to their ability to enhance a number of physical properties. In this work, we investigate the dispersion and re…
A high-contrast, fast-response, and polarizer-free reflective display using a dye-doped dual-frequency liquid crystal gel is demonstrated. The high contrast ratio originates from the combination of light scattering from the microdomain polymer gel and absorption from the black dyes. The fast response is due to the fre…
A metal-dimer assembled system, M(2)(dtp)(4) (M = Ni, Pd; dtp = dithiopropionate, C(2)H(5)CS(2-)), was synthesized and analyzed by the X-ray single-crystal diffraction method, UV-vis-near-IR spectra of solutions, solid-state diffuse reflectance spectroscopies, and electrical conductivity measurements. The structures e…
Orientation imaging microscopy has been used to investigate the effects of Nb doping on the grain boundary plane distributions in TiO 2 (rutile). By comparing the grain boundary plane distribution of the undoped material with theoretical estimates of grain boundary energy anisotropy of pure rutile, it is possible to s…
Accurate assessment of cable insulation conditions can be achieved by implementing advanced diagnostic and simulation techniques that assist the measurement and monitoring of the properties related to aging and failure of the insulation system. It is well recognized that the electric field distribution is the dominant…
Abstract A new method to characterise the coefficient of friction of textile fabrics is proposed. The principle is based on the dry clutch, where an annular shaped flat upper body that is kept still, rubs against a lower flat surface, which rotates around a vertical axis at a constant angular velocity. Friction coeffi…
A new group of ABO 3 -type lead-free piezoelectric ceramics, [Bi 0.5 (Na 1- x Ag x ) 0.5 ] 1- y Ba y TiO 3 , was developed, and the corresponding invention patent was submitted. The ceramics were synthesized by the conventional ceramic sintering technique using electronic grade raw materials, and the preparation techn…
A novel 1,2-dithiolate ligand, that is, the 2-(trifluoromethyl)acrylonitrile-1,2-dithiolate, abbreviated here as tfadt, is prepared from the corresponding cyclic dithiocarbonate. This ligand, substituted with both a CN and a CF(3) group, is compared with the well-known maleonitrile- and bis(trifluoromethyl)ethane-1,2-…
A low-power wavelength dispersive x-ray fluorescence (WDXRF) system with a spatial resolution of 25μm has been built to measure thin-film thickness. By using advanced x-ray optics and a 50-W air-cooled x-ray tube, the system achieved a detection limit equivalent to that of a conventional WDXRF system that employs a 4-…
This review presents the results concerning a comparatively new trend in physics of plasma electrolysis, surface-treatment technology, deposition of coatings, and processes of plasma–electrolyte saturation. Physical and chemical principles of plasma electrolysis are discussed. As shown, this way of materials treatment…