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Water–Gas Shift Catalysis at Corner Atoms of Pt Clusters in Contact with a TiO2(110) Support Surface

Salai Cheettu Ammal、Andreas Heyden2014-09-08ACS Catalysis

The redox and associative carboxyl pathways of the water–gas shift reaction have been investigated at a corner Pt site of the Pt/TiO 2 (110) interface using density functional theory and microkinetic modeling techniques. Overall rates calculated from the microkinetic model suggest that the redox pathway dominates in t…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Heparinized PLLA/PLCL nanofibrous scaffold for potential engineering of small‐diameter blood vessel: Tunable elasticity and anticoagulation property

Weizhong Wang、Jin-Wei Hu、Chuanglong He 等 9 位作者2014-09-08Journal of Biomedical Materials Research Part A

The success of tissue engineered vascular grafts depends greatly on the synthetic tubular scaffold, which can mimic the architecture, mechanical, and anticoagulation properties of native blood vessels. In this study, small-diameter tubular scaffolds were fabricated with different weight ratios of poly(l-lactic acid) (…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesTissue Engineering and Regenerative Medicine

Light upconversion by triplet–triplet annihilation in diphenylanthracene-based copolymers

Soo Hyon Lee、Mathieu A. Ayer、Roberto Vadrucci 等 5 位作者2014-09-08Polymer Chemistry

Low-power light upconversion by triplet–triplet annihilation (TTA-UC) was only recently achieved in glassy materials. Here, a new strategy based on covalent tethering of diphenylanthracene (DPA) emitters to a polymeric backbone is reported. The design aims to optimize the efficiency of this photophysical process in gl…

Luminescence Properties of Advanced MaterialsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Enhanced Transformer Model for Low- and Mid-Frequency Transients—Part I: Model Development

Afshin Rezaei‐Zare2014-09-08IEEE Transactions on Power Delivery

Based on an enhanced topological representation of the transformer core, flux air paths, and tank, a duality-based transformer model is proposed for low and mid-frequency transients analysis. In the developed transformer model, the core and tank iron are represented based on a frequency-dependent hysteresis model. The…

Silicon Carbide Semiconductor TechnologiesMagnetic Properties and ApplicationsPower Transformer Diagnostics and Insulation

Tunable Nanoparticle Arrays at Charged Interfaces

Sunita Srivastava、Dmytro Nykypanchuk、Masafumi Fukuto 等 4 位作者2014-09-08ACS Nano

Structurally tunable two-dimensional (2D) arrays of nanoscale objects are important for modulating functional responses of thin films. We demonstrate that such tunable and ordered nanoparticles (NP) arrays can be assembled at charged air-water interfaces from nanoparticles coated with polyelectrolyte chains, DNA. The…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanowire Synthesis and Applications

One-Step Synthesis of Graphene/Polypyrrole Nanofiber Composites as Cathode Material for a Biocompatible Zinc/Polymer Battery

Sha Li、Kewei Shu、Chen Zhao 等 7 位作者2014-09-08ACS Applied Materials & Interfaces

The significance of developing implantable, biocompatible, miniature power sources operated in a low current range has become manifest in recent years to meet the demands of the fast-growing market for biomedical microdevices. In this work, we focus on developing high-performance cathode material for biocompatible zin…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Laser surface modification of AZ31B Mg alloy for bio-wettability

Yee‐Hsien Ho、Hitesh D. Vora、Narendra B. Dahotre2014-09-08Journal of Biomaterials Applications

Magnesium alloys are the potential degradable materials for load-bearing implant application due to their comparable mechanical properties to human bone, excellent bioactivity, and in vivo non-toxicity. However, for a successful load-bearing implant, the surface of bio-implant must allow protein absorption and layer f…

Bone Tissue Engineering MaterialsMetal and Thin Film MechanicsMagnesium Alloys: Properties and Applications

Graphene field emission devices

Sunil Kumar、Georg S. Duesberg、Rudra Pratap 等 4 位作者2014-09-08Applied Physics Letters

Graphene field emission devices are fabricated using a scalable process. The field enhancement factors, determined from the Fowler-Nordheim plots, are within few hundreds and match the theoretical predictions. The devices show high emission current density of ∼10 nA μm−1 at modest voltages of tens of volts. The emissi…

Carbon Nanotubes in CompositesGraphene research and applicationsMechanical and Optical Resonators

Hydrogenated black ZnO nanoparticles with enhanced photocatalytic performance

Ting Xia、Petra Wallenmeyer、Alicia D. Anderson 等 6 位作者2014-09-08RSC Advances

Following our previous findings on hydrogenated black TiO2 nanoparticles, here, we would like to present our exciting findings on hydrogenated black ZnO nanoparticles, which have displayed long-wavelength absorption and excellent photocatalytic performance. This further demonstrates that hydrogenation is a powerful to…

Advanced Photocatalysis TechniquesZnO doping and propertiesCopper-based nanomaterials and applications

Combined effect of thermoplastic and thermosetting adhesives on properties of particleboard with rice husk core

Jin Heon Kwon、Nadir Ayrılmış、Tae Hyung Han2014-09-08Materials Research

This study investigated the combined effect of adhesive type and content on the dimensional stability and mechanical properties of three-layer particleboards made from a mixture of wood particles (face layer: 30 wt %) and rice husk particles (core layer: 70 wt %). Two types of thermosetting adhesives, liquid urea-form…

Wood Treatment and PropertiesNatural Fiber Reinforced CompositesLignin and Wood Chemistry

Analysis of thin bifacial silicon solar cells with locally diffused and selective back surface field

Adriano Moehlecke、Vanessa da Conceição Osório、Izete Zanesco2014-09-08Materials Research

The aim of this work is to present the development and comparison of thin n+pp+ industrial bifacial silicon solar cells produced with the local screen-printed Al back surface field (BSF) to those with the selective BSF doped with aluminum-boron. To produce solar cells with selective BSF, the boron diffusion based on s…

Thin-Film Transistor TechnologiesSilicon and Solar Cell TechnologiesSilicon Nanostructures and Photoluminescence

Microwave-assisted hydrothermal synthesis of magnetite nanoparticles with potential use as anode in lithium ion batteries

Camila Soares Xavier、C. A. Paskocimas、F.V. Motta 等 9 位作者2014-09-08Materials Research

Rechargeable solid-state batteries have long been considered an attractive power source for a wide variety of applications, and in particular, lithium-ion batteries are emerging as the technology of choice for portable electronics. One of the main challenges in the design of these batteries is to ensure that the elect…

Advancements in Battery MaterialsMagnetic Properties and Synthesis of FerritesExtraction and Separation Processes

Microstructural developments of poly (p-phenylene terephthalamide) fibers during heat treatment process: a review

Ahmed Dawelbeit、Zhong Hongpeng、Kong Haijuan 等 6 位作者2014-09-08Materials Research

Poly (p-phenylene terephthalamide) fibers prepared by wet or dry-jet wet spinning processes have a notable response to very brief heat treatment (seconds) under tension. The modulus of the as-spun fiber can be greatly affected by the heat treatment conditions (temperature, tension and duration). The crystallite orient…

Polymer crystallization and propertiesFiber-reinforced polymer compositesSynthesis and properties of polymers

Heterojunction between Al2O3 and SnO2 thin films for application in transparent FET

Miguel H. Boratto、Luis V. A. Scalvi、Jorge L. B. Maciel 等 5 位作者2014-09-08Materials Research

Alternative materials for use in electronic devices have grown interest in the past recent years. In this paper, the heterojunction SnO2/Al2O3 is tested concerning its use as a transparent insulating layer for use in FETs. The alumina layer is obtained by thermal annealing of metallic Al layer, deposited by resistive…

ZnO doping and propertiesSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Targeted delivery of a novel anticancer compound anisomelic acid using chitosan-coated porous silica nanorods for enhancing the apoptotic effect

Rajendran Senthilkumar、Didem Şen Karaman、Preethy Paul 等 7 位作者2014-09-08Biomaterials Science

Targeted cancer therapies are currently a strong focus in biomedical research. The most common approach is to use nanocarrier-based targeting to specifically deliver conventional anticancer drugs to enhance their therapeutic efficacy, increase bioavailability, and decrease the side-effects on normal cells. A step furt…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryNatural Compounds in Disease Treatment

Determination of the Lateral Dimension of Graphene Oxide Nanosheets Using Analytical Ultracentrifugation

Johannes Walter、Thomas J. Nacken、Cornelia Damm 等 6 位作者2014-09-08Small

In this paper, a method to determine the lateral dimensions of 2D nanosheets directly in suspension by analytical ultracentrifugation (AUC) is shown. The basis for this study is a well-characterized and stable dispersion of graphene oxide (GO) monolayers in water. A methodology is developed to correlate the sedimentat…

Graphene research and applicationsMembrane Separation TechnologiesGraphene and Nanomaterials Applications

An Epitaxial Ferroelectric Tunnel Junction on Silicon

Zhipeng Li、Xiao Guo、Hui‐bin Lu 等 10 位作者2014-09-08Advanced Materials

Epitaxially grown functional perovskites on silicon (001) and the ferroelectricity of a 3.2 nm thick BaTiO3 barrier layer are demonstrated. The polarization-switching-induced change in tunneling resistance is measured to be two orders of magnitude. The obtained results suggest the possibility of integrating ferroelect…

Ferroelectric and Piezoelectric MaterialsSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Degradation of PLA fibers at elevated temperature and humidity

Mary K. Mitchell、Douglas E. Hirt2014-09-08Polymer Engineering and Science

The hydrolytic degradation of poly(lactic acid) (PLA) devices has previously been reported as size dependent for devices such as plates, microspheres, and films between 2 and 0.3 mm in thickness or diameter. In this study, the effect of fiber diameter on the degradation characteristics of PLA fiber of two diameters, 3…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionGraphene and Nanomaterials Applications

Mechanisms of Failure in Nanoscale Metallic Glass

X. Wendy Gu、Mehdi Jafary‐Zadeh、David Chen 等 7 位作者2014-09-08Nano Letters

The emergence of size-dependent mechanical strength in nanosized materials is now well-established, but no fundamental understanding of fracture toughness or flaw sensitivity in nanostructures exists. We report the fabrication and in situ fracture testing of ∼70 nm diameter Ni-P metallic glass samples with a structura…

Silicon Nanostructures and PhotoluminescenceSemiconductor materials and interfacesAnodic Oxide Films and Nanostructures

Reversible Ferromagnetic Phase Transition in Electrode‐Gated Manganites

Bin Cui、Cheng Song、Guangyue Wang 等 11 位作者2014-09-08Advanced Functional Materials

The electronic phase transition has been considered as a dominant factor in the phenomena of colossal magnetoresistance, metal‐insulator transition, and exchange bias in correlated electron systems. However, the effective manipulation of the electronic phase transition has remained a challenging issue. Here, the rever…

Advanced Memory and Neural ComputingMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides