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Thickness-Controlled Synthesis of Colloidal PbS Nanosheets and Their Thickness-Dependent Energy Gaps

Ghadendra Bhandari、Kamal Subedi、Yufan He 等 9 位作者2014-09-08Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTThickness-Controlled Synthesis of Colloidal PbS Nanosheets and Their Thickness-Dependent Energy GapsGhadendra B. Bhandari†, Kamal Subedi†, Yufan He‡§, Zhoufeng Jiang†§, Matthew Leopold†, Nick Reilly†, H. Peter Lu‡§, Alexey T. Zayak†§, and Liangfeng Sun*†§View Author In…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Hyperbranched poly(phosphoester)s as flame retardants for technical and high performance polymers

Karoline Täuber、Filippo Marsico、Frederik R. Wurm 等 4 位作者2014-09-08Polymer Chemistry

A structurally novel hyperbranched halogen-free poly(phosphoester) (hbPPE) is proposed as a flame retardant in poly(ester)s and epoxy resins. hb polymeric flame retardants combine several advantages that make them an extraordinary approach for future flame retardants. hbPPE was synthesized by olefin metathesis polymer…

Flame retardant materials and propertiesDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Higher-Order Nanostructures of Two-Dimensional Palladium Nanosheets for Fast Hydrogen Sensing

Yung‐Tin Pan、Xi Yin、Kam Sang Kwok 等 4 位作者2014-09-08Nano Letters

Two-dimensional (2D) materials often show a range of intriguing electronic, catalytic, and optical properties that differ greatly from conventional nanoparticles. While planar configuration is often desirable, a range of applications such as catalysis and sensing benefit greatly from the accessibility to large surface…

Graphene research and applicationsGas Sensing Nanomaterials and SensorsMXene and MAX Phase Materials

Tailoring of High‐Order Multiple Emulsions by the Liquid–Liquid Phase Separation of Ternary Mixtures

Martin F. Haase、Jasna Brujić2014-09-08Angewandte Chemie International Edition

Multiple emulsions with an "onion" topology are useful vehicles for drug delivery, biochemical assays, and templating materials. They can be assembled by ternary liquid phase separation by microfluidics, but the control over their design is limited because the mechanism for their creation is unknown. Herein we show th…

Proteins in Food SystemsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Toward 300 mm Wafer-Scalable High-Performance Polycrystalline Chemical Vapor Deposited Graphene Transistors

Somayyeh Rahimi、Li Tao、Sk. Fahad Chowdhury 等 9 位作者2014-09-08ACS Nano

The largest applications of high-performance graphene will likely be realized when combined with ubiquitous Si very large scale integrated (VLSI) technology, affording a new portfolio of "back end of the line" devices including graphene radio frequency transistors, heat and transparent conductors, interconnects, mecha…

Graphene research and applications2D Materials and ApplicationsNanowire Synthesis and Applications

Effect of Percolation on the Capacitance of Supercapacitor Electrodes Prepared from Composites of Manganese Dioxide Nanoplatelets and Carbon Nanotubes

Thomas M. Higgins、David McAteer、João Coelho 等 11 位作者2014-09-08ACS Nano

Here we demonstrate significant improvements in the performance of supercapacitor electrodes based on 2D MnO2 nanoplatelets by the addition of carbon nanotubes. Electrodes based on MnO2 nanoplatelets do not display high areal capacitance because the electrical properties of such films are poor, limiting the transport…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Mussel-Inspired One-Step Copolymerization to Engineer Hierarchically Structured Surface with Superhydrophobic Properties for Removing Oil from Water

Shouying Huang2014-09-08ACS Applied Materials & Interfaces

In the present study, a superhydrophobic polyurethane (PU) sponge with hierarchically structured surface, which exhibits excellent performance in absorbing oils/organic solvents, was fabricated for the first time through mussel-inspired one-step copolymerization approach. Specifically, dopamine (a small molecular bioa…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Hybrid White Light Emitting Diode Based on Silicon Nanocrystals

Batu Ghosh、Yoshitake Masuda、Yutaka Wakayama 等 12 位作者2014-09-08Advanced Functional Materials

A novel design of white light emitting diodes (WLEDs) emerges to meet the growing global demand for resource sustainability while preserving health and environment. To achieve this goal, a facile method is developed for the chemical synthesis of a luminescent silicon nanocrystal (ncSi) with a large Stokes shift betwee…

Quantum Dots Synthesis And PropertiesSilicon Nanostructures and PhotoluminescenceCarbon and Quantum Dots Applications

Fabry-Pérot Interference in Gapped Bilayer Graphene with Broken Anti-Klein Tunneling

Anastasia Varlet、Ming‐Hao Liu、Viktor Krueckl 等 10 位作者2014-09-08Physical Review Letters

We report the experimental observation of Fabry-Pérot interference in the conductance of a gate-defined cavity in a dual-gated bilayer graphene device. The high quality of the bilayer graphene flake, combined with the device's electrical robustness provided by the encapsulation between two hexagonal boron nitride laye…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Thermal stability of magnetic nanoparticles coated by blends of modified chitosan and poly(quaternary ammonium) salt

Marta Ziegler-Borowska、Dorota Chełminiak-Dudkiewicz、Halina Kaczmarek2014-09-08Journal of Thermal Analysis and Calorimetry

Magnetite nanoparticles (Fe 3 O 4 NPs) coated by modified chitosan (m-CS) rich of amino groups and its mixture with poly[ N -benzyl-2-(methacryloxy)- N , N- dimethylethanaminium bromide] (PQ) with various mass ratios were prepared by co-precipitation method. The thermal stability of magnetic materials has been investi…

Nanoparticle-Based Drug DeliveryNanocomposite Films for Food PackagingPolymer Nanocomposites and Properties

Tunable asymmetric magnetoimpedance effect in ferromagnetic NiFe/Cu/Co films

E.F. Silva、M. Gamino、A. M. H. de Andrade 等 6 位作者2014-09-08Applied Physics Letters

We investigate the magnetization dynamics through the magnetoimpedance effect in ferromagnetic NiFe/Cu/Co films. We observe that the magnetoimpedance response is dependent on the thickness of the non-magnetic Cu spacer material. We verify asymmetric magnetoimpedance in films with biphase magnetic behavior and explore…

Magnetic properties of thin filmsMetallic Glasses and Amorphous AlloysMagnetic Properties and Applications

Degenerate resistive switching and ultrahigh density storage in resistive memory

Andrew J. Lohn、Patrick R. Mickel、Conrad D. James 等 4 位作者2014-09-08Applied Physics Letters

We show that in tantalum oxide resistive memories, activation power provides a multi-level variable for information storage that can be set and read separately from the resistance. These two state variables (resistance and activation power) can be precisely controlled in two steps: (1) the possible activation power st…

Advanced Memory and Neural ComputingTransition Metal Oxide NanomaterialsFerroelectric and Negative Capacitance Devices

Magnetic properties of epitaxial Fe3O4 films with various crystal orientations and tunnel magnetoresistance effect at room temperature

Taro Nagahama、Y. Matsuda、Kazuya Tate 等 9 位作者2014-09-08Applied Physics Letters

Fe3O4 is a ferrimagnetic spinel ferrite that exhibits electric conductivity at room temperature (RT). Although the material has been predicted to be a half metal according to ab-initio calculations, magnetic tunnel junctions (MTJs) with Fe3O4 electrodes have demonstrated a small tunnel magnetoresistance (TMR) effect.…

Magnetic properties of thin filmsMultiferroics and related materialsMagnetic Properties and Synthesis of Ferrites

Effect of polarization fatigue on the Rayleigh coefficients of ferroelectric lead zirconate titanate thin films: Experimental evidence and implications

Xiaojie Lou、Haolan Zhang、Zheng‐Dong Luo 等 11 位作者2014-09-08Applied Physics Letters

The effect of polarization fatigue on the Rayleigh coefficients of ferroelectric lead zirconate titanate (PZT) thin film was systematically investigated. It was found that electrical fatigue strongly affects the Rayleigh behaviour of the PZT film. Both the reversible and irreversible Rayleigh coefficients decrease wit…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesDielectric materials and actuators

Determining sample alignment in x-ray reflectometry using thickness and density from GaAs/AlAs multilayer certified reference materials

Donald Windover、David Gil、Yasushi Azuma 等 4 位作者2014-09-08Measurement Science and Technology

X-ray reflectometry (XRR) provides researchers and manufacturers with a non-destructive way to determine thickness, roughness, and density of thin films deposited on smooth substrates. Due to the nested nature of equations modeling this phenomenon, the inter-relation between instrument alignment and parameter estimati…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesX-ray Diffraction in Crystallography

Phonon thermal conductivity of monolayer MoS2: A comparison with single layer graphene

Xiaolin Wei、Yongchun Wang、Yulu Shen 等 7 位作者2014-09-08Applied Physics Letters

We investigate the size and edge roughness dependence on thermal conductivity of monolayer MoS2 (MLMoS2) by phonon Boltzmann transport equation combined with relaxation time approximation. The relative contribution of spectral phonons to thermal conductivity is explored, and we compared the characteristics of phonon t…

Graphene research and applicationsAdvanced Thermoelectric Materials and DevicesThermal properties of materials

Charged Point Defects in the Flatland: Accurate Formation Energy Calculations in Two-Dimensional Materials

Hannu‐Pekka Komsa、Natalia Berseneva、Arkady V. Krasheninnikov 等 4 位作者2014-09-08Physical Review X

Technologically important semiconductors rely on impurities of foreign atoms. Researchers successfully model charged defects in two-dimensional semiconductors and insulators by assuming a specific dielectric constant profile.

Graphene research and applications2D Materials and ApplicationsElectronic and Structural Properties of Oxides

Enhanced Photoelectrochemical Water Splitting Performance of Anodic TiO2Nanotube Arrays by Surface Passivation

Qunfang Gui、Zhen Xu、Haifeng Zhang 等 10 位作者2014-09-08ACS Applied Materials & Interfaces

One-dimensional anodic titanium oxide nanotube (TONT) arrays provide a direct pathway for charge transport, and thus hold great potential as working electrodes for electrochemical energy conversion and storage devices. However, the prominent surface recombination due to the large amount surface defects hinders the per…

TiO2 Photocatalysis and Solar CellsTransition Metal Oxide NanomaterialsAnodic Oxide Films and Nanostructures

A Highly Sensitive Graphene‐Organic Hybrid Photodetector with a Piezoelectric Substrate

W. D. Tan、Wei‐Heng Shih、Yang‐Fang Chen2014-09-08Advanced Functional Materials

To create a sensitive photodetector, the transparent and conductive properties of graphene and the optical and photovoltaic properties of poly(3‐hexylthiophene) (P3HT) are combined as a hybrid composite. Based on the inherent nature of the band alignment between graphene and P3HT, the photogenerated holes are able to…

Graphene research and applicationsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Modeling of Growth Morphology of Core–Shell Nanoparticles

Vyacheslav Gorshkov、Vasily Kuzmenko、Vladimir Privman2014-09-08The Journal of Physical Chemistry C

We model shell formation of core–shell noble metal nanoparticles. A recently developed kinetic Monte Carlo approach is utilized to reproduce growth morphologies realized in recent experiments on core–shell nanoparticle synthesis, which reported smooth epitaxially grown shells. Specifically, we identify not only growth…

Gold and Silver Nanoparticles Synthesis and Applicationsnanoparticles nucleation surface interactionsLaser-Ablation Synthesis of Nanoparticles