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Structural and Electrochemical Properties of Nanocomposite Polymer Electrolyte for Electrochemical Devices

Mohan L. Verma、Manickam Minakshi、Nirbhay Singh2014-09-05Industrial & Engineering Chemistry Research

This report describes the structural and electrochemical properties of the nanocomposite polymer electrolyte (70PEO:30AgI) incorporating SiO 2 filler of different weight percentage (wt %) ranging between 1 and 10 wt %. Studies on inorganic filler in polymer matrix may be quite familiar, but the chosen polymer, the eff…

Supercapacitor Materials and FabricationAdvanced Battery Materials and TechnologiesConducting polymers and applications

Synthesis of Unsymmetric Bipyridine–Pt II –Alkynyl Complexes through Post‐Click Reaction with Emission Enhancement Characteristics and Their Applications as Phosphorescent Organic Light‐Emitting Diodes

Yongguang Li、Daniel Ping‐Kuen Tsang、Carmen Ka‐Man Chan 等 6 位作者2014-09-05Chemistry - A European Journal

Two unsymmetric bipyridine-platinum(II)-alkynyl complexes have been synthesised by a post-click reaction. These metal complexes are found to exhibit emission enhancement properties. The photoluminescence quantum yield can be significantly increased from 0.03 in solution to 0.72 in solid-state thin films. Efficient sol…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Quinone‐Rich Poly(dopamine) Magnetic Nanoparticles for Biosensor Applications

Miriam Martín、Alejandro González Orive、Pablo Lorenzo‐Luis 等 6 位作者2014-09-05ChemPhysChem

Novel core-shell quinone-rich poly(dopamine)-magnetic nanoparticles (MNPs) were prepared by using an in situ polymerization method. Catechol groups were oxidized to quinone by using a thermal treatment. MNPs were characterized by using X-ray diffraction, X-ray photoelectron spectroscopy, atomic force microscopy, magne…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Sulfurization induced surface constitution and its correlation to the performance of solution-processed Cu2ZnSn(S,Se)4 solar cells

Jie Zhong、Zhe Xia、Miao Luo 等 11 位作者2014-09-05Scientific Reports

To obtain high photovoltaic performances for the emerging copper zinc tin sulfide/selenide (CZTSSe) thin film solar cells, much effort has deservedly been placed on CZTSSe phase purification and CZTSSe grain size enhancement. Another highly crucial but less explored factor for device performance is the elemental const…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Porphyrins and phthalocyanines: promising molecules for light-triggered antibacterial nanoparticles

Dhananjoy Mondal、Smritilekha Bera2014-09-05Advances in Natural Sciences Nanoscience and Nanotechnology

Light-triggered treatments in the presence of photosensitizer and oxygen molecule are prevalent for a wide variety of diseases.The reactive oxygen species (ROS), which are produced in the vicinity of malignant tissue by the light activated sensitizers, are considered as active agents in the photodynamic therapy (PDT).…

Nanoplatforms for cancer theranosticsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Efficient removal of elemental mercury (Hg 0 ) by SBA-15-Ag adsorbents

Yijun Xie、Bin Yan、Chong Tian 等 6 位作者2014-09-05Journal of Materials Chemistry A

A novel adsorbent based on Ag-loaded SBA-15 was prepared by a facile wet chemical method for the removal of elemental mercury (Hg0, the most challenging form) for the first time. The adsorbent shows excellent Hg0 removal capacity (>60 μg g−1 at 150 °C) in real flue gas and cyclic performance.

Metal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials ScienceGas Sensing Nanomaterials and Sensors

Structural elucidation of cell membrane-derived nanoparticles using molecular probes

Zhiyuan Fan、Hao Zhou、Peter Y. Li 等 5 位作者2014-09-05Journal of Materials Chemistry B

Cell membrane-derived nanoparticles (CNPs) are a novel class of materials and are superior to synthetic nanomaterials in certain aspects due to their biological origin. Although their medical applications have been actively explored, the fundamental structure of CNPs is rarely studied. For example, the membrane orient…

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesRNA Interference and Gene Delivery

Formation of Mn3O4 nanobelts through the solvothermal process and their photocatalytic property

Khalid Abdelazez Mohamed Ahmed、Kaixun Huang2014-09-05Arabian Journal of Chemistry

Hausmannite Mn3O4 nanobelts were synthesized from manganese acetate and potassium hydroxide precursors in the presence of melamine–ethanol–distill water via the reflux and solvothermal methods. X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopes confirm the composition of the as-prepared produ…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

On-surface synthesis of a two-dimensional porous coordination network: Unraveling adsorbate interactions

Manfred Matena、Jonas Björk、M.C. Wahl 等 9 位作者2014-09-05Physical Review B

We present a detailed experimental and theoretical characterization of the adsorption of the perylene derivative 4,9-diaminoperylene-quinone-3,10-diimine (DPDI) on Cu(111) and compare it to its threefold dehydrogenated derivative 3deh-DPDI, which forms in a surface reaction upon annealing. While DPDI itself does not g…

Mesoporous Materials and CatalysisMolecular Junctions and NanostructuresSurface Chemistry and Catalysis

A small-sized graphene oxide supramolecular assembly for targeted delivery of camptothecin

Ying‐Ming Zhang、Yu Cao、Yang Yang 等 5 位作者2014-09-05Chemical Communications

A small-sized graphene oxide supramolecular assembly was obtained by the inclusion complexation of hyaluronated adamantane with β-cyclodextrin and the π-stacking of graphene oxide with camptothecin, exhibiting an excellent stability in the serum environment and a higher inhibition effect toward malignant cells than a…

Nanoparticle-Based Drug DeliveryGraphene research and applicationsGraphene and Nanomaterials Applications

Effect of oxygen incorporation on the structure and elasticity of Ti-Al-O-N coatings synthesized by cathodic arc and high power pulsed magnetron sputtering

Marcus Hans、Moritz to Baben、D. Music 等 9 位作者2014-09-05Journal of Applied Physics

Ti-Al-O-N coatings were synthesized by cathodic arc and high power pulsed magnetron sputtering. The chemical composition of the coatings was determined by means of elastic recoil detection analysis and energy dispersive X-ray spectroscopy. The effect of oxygen incorporation on the stress-free lattice parameters and Yo…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchAdvanced materials and composites

Fabrication and tensile properties of graphene/copper composites prepared by electroless plating for structrual applications

Chao Zhao、Jun Wang2014-09-05physica status solidi (a)

Despite a growing interest in graphene nanoplatelets (GNPs)-based metal matrix composites, developing high-performance GNP/metal composites with full exploration of graphene properties remains a great challenge. Here, we propose an effective method to prepare GNP/Cu composites by an electroless plating process and fol…

Graphene research and applicationsAluminum Alloys Composites PropertiesBoron and Carbon Nanomaterials Research

Masked Rhodamine Dyes of Five Principal Colors Revealed by Photolysis of a 2‐Diazo‐1‐Indanone Caging Group: Synthesis, Photophysics, and Light Microscopy Applications

Vladimir N. Belov、Gyuzel Yu. Mitronova、Mariano L. Bossi 等 10 位作者2014-09-05Chemistry - A European Journal

Caged rhodamine dyes (Rhodamines NN) of five basic colors were synthesized and used as "hidden" markers in subdiffractional and conventional light microscopy. These masked fluorophores with a 2-diazo-1-indanone group can be irreversibly photoactivated, either by irradiation with UV- or violet light (one-photon process…

Advanced Fluorescence Microscopy TechniquesClick Chemistry and ApplicationsPhotochromic and Fluorescence Chemistry

Characterization of electronic states at insulator/(Al)GaN interfaces for improved insulated gate and surface passivation structures of GaN-based transistors

Zenji Yatabe、Yujin Hori、Wancheng Ma 等 7 位作者2014-09-05Japanese Journal of Applied Physics

This paper presents a systematic characterization of electronic states at insulators/(Al)GaN interfaces, particularly focusing on insulator/AlGaN/GaN structures. First, we review important results reported for GaN metal–insulator–semiconductor (MIS) structures. SiO 2 is an attractive material for MIS transistor applic…

GaN-based semiconductor devices and materialsSemiconductor materials and devicesGa2O3 and related materials

Hydrothermal Fabrication of Three‐Dimensional Secondary Battery Anodes

Jinyun Liu、Huigang Zhang、Junjie Wang 等 10 位作者2014-09-05Advanced Materials

A generalized hydrothermal strategy for fabricating three-dimensional (3D) battery electrodes is presented. The hydrothermal growth deposits electrochemically active nanomaterials uniformly throughout the complex 3D mesostructure of the scaffold. Ni inverse opals coated with SnO2 nanoparticles or Co3O4 nanoplatelets,…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesTransition Metal Oxide Nanomaterials

Significantly improved photovoltaic performance of the triangular-spiral TPA(DPP–PN) 3 by appending planar phenanthrene units into the molecular terminals

You‐Ming Zhang、Xichang Bao、Manjun Xiao 等 9 位作者2014-09-05Journal of Materials Chemistry A

A new small molecule of TPA(DPP–PN) 3 was obtained with appending planar phenanthrene units in the molecular terminals, and displayed a maximum PCE of 3.67% in the OSCs.

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Enhancement of Platinum Mass Activity on the Surface of Polymer-wrapped Carbon Nanotube-Based Fuel Cell Electrocatalysts

Inas H. Hafez、Mohamed R. Berber、Tsuyohiko Fujigaya 等 4 位作者2014-09-05Scientific Reports

Cost reduction and improved durability are the two major targets for accelerating the commercialization of polymer electrolyte membrane fuel cells (PEFCs). To achieve these goals, the development of a novel method to fabricate platinum (Pt)-based electrocatalysts with a high mass activity, deposited on durable conduct…

Electrocatalysts for Energy ConversionFuel Cells and Related MaterialsConducting polymers and applications

Measurement of oxidative damage to DNA in nanomaterial exposed cells and animals

Peter Möller、Ditte Marie Jensen、Daniel Vest Christophersen 等 14 位作者2014-09-05Environmental and Molecular Mutagenesis

Increased levels of oxidatively damaged DNA have been documented in studies of metal, metal oxide, carbon-based and ceramic engineered nanomaterials (ENMs). In particular, 8-oxo-7,8-dihydroguanine-2'-deoxyguanosine (8-oxodG) is widely assessed as a DNA nucleobase oxidation product, measured by chromatographic assays,…

Nanoparticles: synthesis and applicationsCarcinogens and Genotoxicity AssessmentMicroplastics and Plastic Pollution

What a Difference a Bond Makes: The Structural, Chemical, and Physical Properties of Methyl-Terminated Si(111) Surfaces

Keith T. Wong、Nathan S. Lewis2014-09-05Accounts of Chemical Research

The chemical, electronic, and structural properties of surfaces are affected by the chemical termination of the surface. Two-step halogenation/alkylation of silicon provides a scalable, wet-chemical method for grafting molecules onto the silicon surface. Unlike other commonly studied wet-chemical methods of surface mo…

Semiconductor materials and devicesMolecular Junctions and NanostructuresSilicon Nanostructures and Photoluminescence

Growth of the [110] Oriented TiO2 Nanorods on ITO Substrates by Sputtering Technique for Dye-Sensitized Solar Cells

Lijian Meng、Hong Chen、Can Li 等 4 位作者2014-09-05Frontiers in Materials

TiO2 films have been deposited on ITO substrates by dc reactive magnetron sputtering technique. It has been found that the sputtering pressure is a very important parameter for the structure of the deposited TiO2 films. When the pressure is lower than 1 Pa, the deposited film has a dense structure and shows a preferre…

TiO2 Photocatalysis and Solar CellsZnO doping and propertiesGas Sensing Nanomaterials and Sensors