Materials Literature
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Pulsed laser deposition has enabled formation of highly oxidized and strained BaTiO3 films on SrTiO3 substrates in a layer-by-layer growth mode to thicknesses of 125nm. Balancing thermodynamics and diffusion lengths enables controlled growth at the higher oxygen pressures required. Growth above 800°C produces an array…
One-step sol–gel syntheses of lamellar organic–inorganic hybrids with a talc like structure are performed using N-phenylaminomethyltrimethoxysilane (PAM-TMS) and phenethyltrimethoxysilane (PE-TMS) as silicon sources. Results obtained by X-ray diffraction and X-ray fluorescence show that after one day of ageing at room…
Potassium nitrate exhibits a reentrant phase transformation, where a metastable ferroelectric phase (γ-KNO 3 ) is formed upon cooling from high temperature. The layered structure of this ferroelectric phase is composed of alternating layers of potassium ions and nitrate groups; wherein, a central nitrogen atom is coor…
The thermal stability of CdZnO∕ZnO multi-quantum-well (MQW) structures was studied using rapid thermal annealing in nitrogen from 300to750°C. Photoluminescence (PL) emission from the MQWs was studied while varying the annealing temperature and time. For 15min annealings, the PL center wavelength showed a 7nm reduction…
A mesoporous γ-Al2O3 without amorphous domains was synthesized using a modified cation–anion double hydrolysis method and was shown to display a remarkably high catalytic activity in the aldol reaction.
Abstract Growing environmental concerns have led to the development of alternative biodegradable polymers with properties comparable to the conventional poly(ethylene), poly(propylene) or poly(ethylene terephthalate). In this paper the thermal degradation of poly(∊-caprolactone) (PCL) and poly(L-lactide) (PLLA) melts…
Abstract Based on first principle FP‐LAPW calculations, we have studied the electronic and magnetic properties of anatase TiO 2 with Ti cation vacancy. We find that the Ti cation vacancy defect can induce a magnetic moment of about 4 μ B /supercell. The magnetic moment mainly comes from p‐orbitals of O atoms which sur…
Etheno-bridged N-confused tetraphenylporphyrin was synthesized through flipping of the confused pyrrole ring and endocyclic extension of [18]annulenic pi-conjugated system was exemplified by the absorption spectra as well as the calculated Kohn-Sham orbitals.
We report here a high-pressure phase-transition induced strengthening in ultrapure zirconium metal. The determined yield strength shows more than sixfold abrupt increase at the transition pressure of Pc=6GPa, from σyα≈180MPa in the low-pressure phase of α-Zr to σyω≈1180MPa in the high-pressure phase of ω-Zr. The obser…
The non-uniform chain manganese(III) complex constructed from EE-azido bridged MnIII3O units, [MnIII3O(Brppz)3-(MeOH)3(N3)] 2MeOH [1, Brppz = 3-(5-bromo-2-phenolate)-pyrazolate], is the first example of 1D azido-bridged coordination polymer showing both solvatomagnetic effect and spin-glass behavior.
Epitaxial films of an alternative multiferroic material, GaFeO3 (GFO), were grown by pulsed laser deposition on yttrium-stabilized zirconia (001) and on conducting buffer layers of indium tin oxide (001). They present a perfect epitaxial growth along the GFO [010] axis and six crystallographic variants in the film’s p…
Using first-principles computations, we studied NH3 adsorption on a series of zigzag (n,0) single-walled BN nanotubes (BNNTs) and the effect of gas coverage. Tube diameter and NH3 coverage play important roles on the tube-NH3 interaction. Chemisorption of a single NH3 molecule on top of B site is energetically prefera…
Zn 0.76 Mg 0.24 O p-n photodiode was fabricated on (000l) Al2O3 substrate by plasma-assisted molecular beam epitaxy. Ni∕Au and In metals deposited using vacuum evaporation were used as p-type and n-type contacts, respectively. Current-voltage measurements on the device showed weak rectifying behavior. The photodetecto…
The recent advances in the study of light emission from matter induced by synchrotron radiation: X-ray excited optical luminescence (XEOL) in the energy domain and time-resolved X-ray excited optical luminescence (TRXEOL) are described. The development of these element (absorption edge) selective, synchrotron X-ray ph…
Enantiodifferentiating photoisomerization of (Z)-cyclooctene included and sensitized by m-methoxybenzoyl-beta-cyclodextrin gave chiral (E)-isomers in up to 46% enantiomeric excess, which is the highest value ever reported for supramolecular photochirogenesis with analogous hosts, thus demonstrating the crucial role of…
We report on a generic approach for immobilizing quantum dots (CdTe nanoparticles) on thin, fluid films consisting of poly(acrylic acid) (PAA) polymer chains tethered by one end to an underlying substrate in a polymer brush configuration. The protocol involves covalent bonding (amide linkage) between amino groups pres…
A new strategy for the encapsulation of magnetic nanobeads was developed by using the in situ self-assembly of an organic-inorganic hybrid polymer. The hybrid polymer of {[Cu(bpy)(BF(4))(2)(H(2)O)(2)](bpy)}(n) (bpy=4,4'-bipyridine) was constructed on the surface of amino-functionalized magnetic beads and the resulting…
Abstract The biaxial stretchability and film properties of polylactide/thermoplastic starch blends were investigated. Polylactide (PLA) and thermoplastic starch (TPS) were blended in various proportions. Blends containing 27, 42 and 60 wt.% TPS were prepared via a twin-screw extrusion process. Interfacial modification…
We present a detailed investigation on the origin of the room-temperature visible luminescence in hydrogenated amorphous silicon nitride films. In combination with Raman spectroscopy and high resolution transmission electron microscopy, we demonstrate clearly that the red light emission originates from amorphous silic…
Two new insoluble transition metal substituted phosphotungstates, (C2N2H10)11[{(B-alpha-PW9O34)Fe3(OH)3}4(PO4)4Fe].38H2O(1) and K4(C2N2H10)12[(alpha-PW10Fe2O39)4].30H2O(2), have been isolated by the hydrothermal reaction of [A-alpha-PW9O34]9-, Fe(III) ions and ethylenediamine. Compound 1 has a tetrahedral symmetry and…