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Synthesis, Crystal Structure, and Magnetic Properties of {[Cu(oxbe)]Mn(H2O)[Cu(oxbe)(DMF)]}n·nDMF·nH2O: From Dissymmetrical Mononuclear Entities to a 3D Heterometallic Supramolecular Coordination Polymer

Shuang‐Quan Zang、Ruo‐Jie Tao、Qing‐Lun Wang 等 7 位作者2003-01-04Inorganic Chemistry

Self-assembly of the building block [Cu(oxbe)](-) with Mn(II) led to a novel coordination polymer ([Cu(oxbe)]Mn(H(2)O)[Cu(oxbe)(DMF)])n).nDMF.nH(2)O, where H(3)oxbe is a new dissymmetrical ligand N-benzoato-N'-(2-aminoethyl)oxamido and DMF = dimethylformamide. The crystal forms in the triclinic system, space group Pon…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Hydrothermal Synthesis of Barium Titanate

Huei-Jyh Chen、Yu‐Wen Chen2003-01-04Industrial & Engineering Chemistry Research

Barium titanate fine particles were prepared by hydrothermal synthesis. The synthesis was preformed at a temperature between 75 and 180 °C and for 10 min to 96 h. The reactions were carried out in a strong alkaline solution. Ba(OH) 2 ·8H 2 O was used as the Ba-precursor material. Various Ti precursors were used to inv…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisElectronic and Structural Properties of Oxides

Synthesis and Photomodulation of Rigid Polyphenylene Dendrimers with an Azobenzene Core

Dörthe Grebel-Koehler、Daojun Liu、Steven De Feyter 等 9 位作者2003-01-04Macromolecules

A series of azobenzene-cored polyphenylene dendrimers have been synthesized. The photoresponsive properties of these dendrimers have been investigated by optical spectroscopy and gel permeation chromatography (GPC). These polyphenylene dendrimers exhibit a photoresponsive behavior upon UV and visible irradiation, resu…

Advanced Polymer Synthesis and CharacterizationDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Spatially Selective Deposition of a Reactive Polysaccharide Layer onto a Patterned Template

Liqun Wu、Hyunmin Yi、Sheng Li 等 7 位作者2003-01-04Langmuir

The amine-containing polysaccharide chitosan was selectively deposited onto patterned gold surfaces in response to an applied voltage. Standard microfabrication techniques were used to pattern gold onto silicon wafers, and these gold patterns served as templates for the electric field directed deposition of chitosan.…

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresElectrophoretic Deposition in Materials Science

Polymer Spherulites: A Modern Assessment

D. C. Bassett2003-01-04Journal of Macromolecular Science Part B

Spherulites and spherulitic growth are characteristic of melt-crystallized polymers and exert a profound influence on their mechanical and other properties. They and their formation have, neverthel...

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Structural Order Parameter in the Pyrochlore Superconductor Cd2Re2O7

I. A. Sergienko、S. H. Curnoe2003-01-04arXiv

It is shown that both structural phase transitions in Cd2Re2O7, which occur at T_{s1}=200 K and T_{s2}=120 K, are due to an instability of the Re tetrahedral network with respect to the same doubly degenerate long-wavelength phonon mode. The primary structural order parameter transforms according to the irreducible re…

Materials ScienceSuperconductivity

Magneto−Structural Correlations in 2D and 3D Extended Structures of Manganese(II)−Malonate Systems

Tapas Kumar Maji、Saugata Sain、Golam Mostafa 等 7 位作者2003-01-04Inorganic Chemistry

Two polymeric malonato-bridged manganese(II) complexes of formula [Mn(mal)(H(2)O)(2)](n)() (1) and [Mn(2)(mal)(2)(4,4'-bipy)(H(2)O)(2)](n)() (2) have been synthesized and characterized (mal = malonate dianion; 4,4'-bipy = 4,4'-bipyridine). The crystal structure of complex 1 was already known. Complex 2 crystallizes in…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Chemical and Spectroscopic Aspects of Polymer Ablation: Special Features and Novel Directions

Thomas Lippert、J. T. Dickinson2003-01-04OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChemical and Spectroscopic Aspects of Polymer Ablation: Special Features and Novel DirectionsThomas Lippert and J. Thomas DickinsonView Author Information Paul Scherrer Institut, 5232 Villigen PSI, Switzerland, and Washington State University, Pullman, Washington 99164-2814…

Diamond and Carbon-based Materials ResearchLaser Material Processing TechniquesLaser-induced spectroscopy and plasma

Noncovalent Side-Wall Functionalization of Single-Walled Carbon Nanotubes

Alexander Star、Yi Liu、Kevin R. Grant 等 9 位作者2003-01-04OpenAlex

A family of poly[( m -phenylenevinylene)- co -( p -phenylenevinylene)]s, functionalized in the synthetically accessible C-5 position of the meta-disubstituted phenylene rings have been designed and synthesized: they are essentially poly{(5-alkoxy- m -phenylenevinylene)- co -[(2,5-dioctyloxy- p -phenylene)vinylene]} (P…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsMechanical and Optical Resonators

Formation of Co-continuous Structures in Melt-Mixed Immiscible Polymer Blends

Petra Pötschke、D. R. Paul2003-01-04OpenAlex

Co-continuous structures can be regarded as the coexistence of at least two continuous structures within the same volume. Blends with co-continuous structures may combine the properties of both components in a favorable way, for example, mechanical moduli. This review article deals with the identification, characteriz…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Blends and Reaction Products Prepared from Phenolic Resin and Waste PET. II. Thermal Oxidative Degradation

Tülin Banu İyim、Saadet Özgümüş、Murat Orbay2003-01-03Polymer-Plastics Technology and Engineering

High ortho novolactype phenolic resin and waste poly(ethylene terephthalate) (PET) were used to prepare blends and reaction products. The effect of PET on the thermal oxidative stability of these products was investigated with thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and fourier trans…

Polymer crystallization and propertiesEpoxy Resin Curing ProcessesThermal and Kinetic Analysis

Optical and mechanical characteristics of nanocrystalline boron carbonitride films synthesized by plasma-assisted physical vapor deposition

Zhiqian Cao、H. Oechsner2003-01-03Journal of Applied Physics

Nanocrystalline boron carbonitride thin films were prepared using the electron-cyclotron- wave-resonance plasma-assisted deposition, whereby the energy for precursor ions was adjusted between 70 and 180 eV. Fourier-transform infrared spectroscopy confirmed the presence of ternary sp3-bonded structure and high-resoluti…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

Dynamic response of ceramic-metal composites: The TiC-Steel system

B. Klein、N. Frage、M.P. Dariel 等 4 位作者2003-01-03Journal of Applied Physics

The dynamic response of a titanium carbide (TiC)–carbon steel, ceramic-metal composite, was studied in planar impact experiments, using a copper impactor with velocity in the 80–450 m/s range. The composites were prepared by pressureless infiltration of TiC ceramic preforms by molten steel. The metallic component had…

Metal and Thin Film MechanicsHigh-Velocity Impact and Material BehaviorPowder Metallurgy Techniques and Materials

Solution-State and Solid-State Structural Characterization of Complexes of a New Macrocyclic Ligand Containing the 1,5-Diazacyclooctane Subunit

Chuanjiang Hu、Thoi D. Nguyen、Paul S. Wagenknecht 等 4 位作者2003-01-03Inorganic Chemistry

The synthesis and characterization of a new constrained tetraazamacrocyclic ligand, 1,4,8,11-tetraazabicyclo[9.3.3]heptadecane (1,11-C(3)-cyclam), is reported. Because of its basicity, this ligand (pK(a) of the protonated form >13.5) requires aprotic solvents for its metalation reactions. Two complexes of this ligand,…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Crystal growth and optical properties of Cr4+:Li2TiGeO5

M. Sharonov、A. B. Bykov、S. Owen 等 5 位作者2003-01-03Journal of Applied Physics

Crystal growth and optical properties of Cr4+ centers in Li2TiGeO5 single crystals were investigated. Polarized absorption spectra at low and room temperature indicate a lowering of symmetry of the local environment of the Cr4+ ion from Td to C2 group of symmetry. The crystal field parameter Dq and the Racah papramete…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsCrystal Structures and Properties

Influence of urethane group on properties of crosslinked polyurethane elastomers

Constantin Ciobanu、Xiaozu Han、Constantin N. Caşcaval 等 7 位作者2003-01-03Journal of Applied Polymer Science

Abstract Three series of weakly crosslinked polyurethanes based on a hydroxyterminated polybutadiene, hydroxyterminated butadiene–acrylonitrile copolymer, and hydroxyterminated ethylene–adipate–maleate–fumarate copolymer were prepared while varying the hard segment content between 1.72 and 2.36 mol NHCOO/1000 g pol…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingSynthetic Organic Chemistry Methods

Novel Na-3-Mica: Alkaline Earth Cation Exchange and Immobilization

Tatsuya Kodama、Kumi Hasegawa、Ken‐ichi Shimizu 等 4 位作者2003-01-03Separation Science and Technology

The cation-exchange capacities for the alkaline earth metals Ba, Mg, and Ca, and their immobilization in the interlayers of a novel swelling fluorine mica (Na-3-mica) with a high-layer-charge density were studied. The mica was fully exchanged or saturated with Ba, Mg, and Ca ions and the cation-exchange capacities wer…

Concrete and Cement Materials ResearchAdvanced ceramic materials synthesisGlass properties and applications

Anderson Localization in a Graphene Sheet

Hidekatsu Suzuura、Tsuneya Ando2003-01-03Journal of the Physical Society of Japan

We have analytically evaluated a quantum correction to the classical Boltzmann conductivity in a single graphene sheet. The effective-mass theory is applied to electronic states and we have collected contributions represented by maximally-crossed diagrams in perturbative expansions of the conductivity by Kubo formula.…

Carbon Nanotubes in CompositesGraphene research and applicationsQuantum and electron transport phenomena

Characterization of silsesquioxanes by size‐exclusion chromatography and matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrometry

Jana Falkenhagen、Harald Jancke、Ralph‐Peter Krüger 等 5 位作者2003-01-03Rapid Communications in Mass Spectrometry

Liquid chromatography in combination with spectroscopic methods like matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOFMS) or nuclear magnetic resonance (NMR) spectroscopy is a powerful method to characterize silsesquioxanes and silsesquioxane mixtures. As new examples, the formati…

Metal and Thin Film MechanicsAnalytical Chemistry and SensorsSilicone and Siloxane Chemistry

Azobenzene-Modified Poly(l-glutamic acid) (AZOPLGA): Its Conformational and Photodynamic Properties

Suizhou Yang、Lian Li、Ashok L. Cholli 等 5 位作者2003-01-03Biomacromolecules

Azobenzene-modified poly(l-glutamic acid) (AZOPLGA) polymers with 22 and 35 mol % of azo chromophores in the side chains have been synthesized by condensing 4-methoxy-4'-aminoazobenzene and poly(l-glutamic acid). These polymers have been characterized by NMR, FT-IR, and UV-visible spectroscopic techniques. The conform…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchPhotochromic and Fluorescence Chemistry