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Elastic scattering effects in the electron mean free path in a graphite overlayer studied by photoelectron spectroscopy and LEED

N. Barrett、E. E. Krasovskii、J.-M. Themlin 等 4 位作者2005-01-31Physical Review B

The energy dependence of the mean free path $\ensuremath{\lambda}(E)$ in graphite at low kinetic energies (below $\ensuremath{\sim}50\phantom{\rule{0.3em}{0ex}}\mathrm{eV}$) is studied using the synchrotron radiation excited Si $2p$ core level photoemission signal from a SiC substrate attenuated by an epitaxial graphi…

Semiconductor materials and devicesX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Synthesis of Poly(3‐hydroxybutyrate‐co‐4‐hydrobutyrate) with a Target Mole Fraction of 4‐Hydroxybutyric Acid Units by Two‐Stage Continuous Cultivation of Delftia acidovorans P4a

Gisela Mothes、Jörg‐Uwe Ackermann2005-01-31Engineering in Life Sciences

Abstract Delftia acidovorans P4a (DSMZ 10474) was grown in mineral medium on acetic acid at pH 8.0 without an additional supply of nutrients like yeast extract or polypeptone. Using acetic acid and γ‐butyrolactone (GBL), copolymers with a 4HB content from 2–90 mol % were detected in batch experiments, depending on the…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesPolyamine Metabolism and Applications

Angular-dependent planar metamagnetism in the hexagonal compounds TbPtIn and TmAgGe

E. Morosan、S.L. Bud’ko、P. C. Canfield2005-01-31Physical Review B

Detailed magnetization measurements $M(T,H,\ensuremath{\theta})$, were performed on single crystals of TbPtIn and TmAgGe (both members of the hexagonal ${\mathrm{Fe}}_{2}\mathrm{P}∕\mathrm{Zr}\mathrm{Ni}\mathrm{Al}$ structure type) for the magnetic field $H$ applied perpendicular to the crystallographic $c$ axis. Thes…

Magnetic properties of thin filmsRare-earth and actinide compoundsIron-based superconductors research

Two-dimensional growth of continuous Cu2O thin films by magnetron sputtering

Z. G. Yin、H. T. Zhang、D. M. Goodner 等 7 位作者2005-01-31Applied Physics Letters

We present results on the in situ, two-dimensional growth (as opposed to the more commonly encountered island-coalescence mechanism) of continuous epitaxial Cu2O films on MgO(011) using dc facing-magnetron sputtering from metallic Cu targets in an oxygen/argon atmosphere. Film growth was studied as a function of depos…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Synthesis of polyether‐based polyurethane‐silica nanocomposites with high elongation property

Sung‐Il Lee、Yoon‐Bong Hahn、Kee Suk Nahm 等 4 位作者2005-01-31Polymers for Advanced Technologies

Abstract The NCO‐terminated prepolymers, prepared by reacting a mixture of poly(tetramethylene glycol) and fumed nanosilica with 4,4′‐diphenylmethane diisocyanate, were chain‐extended with 1,4‐ butanediol to yield polyurethane‐silica nanocomposites. The nanosilica particles were well dispersed in the polyurethane matr…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingSilicone and Siloxane Chemistry

Mechanical properties of woodflour/linseed oil resin composites

Mirna A. Mosiewicki、J. Borrajo、Mirta I. Aranguren2005-01-31Polymer International

Abstract The purpose of this project was to obtain new composites using filler and resin obtained from renewable resources, combining low cost and good mechanical properties. The matrix consisted of a polyester resin synthesized from linseed oil and further crosslinked with styrene in a peroxide‐initiated reaction. Co…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

Acid and basic functionalities of nitrogen and carbon dioxide plasma‐treated polystyrene

Meng‐Jiy Wang、You‐Im Chang、Fabienne Poncin‐Epaillard2005-01-31Surface and Interface Analysis

Abstract The choice of plasma gas can determine the interaction between material and plasma and therefore the applications of the treated materials. Nitrogen plasma can integrate functional groups such as primary amines and carbon dioxide plasma can incorporate carboxylic groups on the surface of polymers. For specifi…

Graphene research and applicationsSurface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting Materials

Single-Beam and Enhanced Two-Beam Second-Harmonic Generation from Silicon Nanocrystals by Use of Spatially Inhomogeneous Femtosecond Pulses

P. Figliozzi、L. Sun、Yongqiang Jiang 等 10 位作者2005-01-31Physical Review Letters

Optical second-harmonic generation (SHG) is used as a noninvasive probe of the interfaces of Si nanocrystals (NCs) embedded uniformly in an ${\mathrm{S}\mathrm{i}\mathrm{O}}_{2}$ matrix. Measurements of the generated SH mode verify that the second-harmonic polarization has a nonlocal dipole form proportional to $(\sta…

Silicon Nanostructures and PhotoluminescenceSpectroscopy and Quantum Chemical StudiesNanowire Synthesis and Applications

Suppression of spontaneous emission and superradiance over macroscopic distances in media with negative refraction

Jürgen Kästel、Michael Fleischhauer2005-01-31Physical Review A

The possibility of negative optical path length in left-handed media (LHM) is shown to lead to complete suppression of spontaneous emission of an atom in front of a mirror with a layer of LHM. For the same reason two atoms put at the foci of a perfect lens formed by a parallel LHM slab [J. B. Pendry, Phys. Rev. Lett.…

Metamaterials and Metasurfaces ApplicationsOrbital Angular Momentum in OpticsQuantum optics and atomic interactions

Lattice dynamics ofNaAlH4from high-temperature single-crystal Raman scattering andab initiocalculations: Evidence of highly stableAlH4−anions

Eric H. Majzoub、Kevin F. McCarty、Vidvuds Ozoliņš2005-01-31Physical Review B

Polarized Raman scattering on single crystals of has been used to determine the symmetry properties and frequencies of the Raman-active vibrational modes over the temperature range from 300 to 425 K, i.e., up to the melting point . Significant softening (by up to 6%) is observed in the modes involving rigid translatio…

Hydrogen Storage and MaterialsNuclear Materials and PropertiesAmmonia Synthesis and Nitrogen Reduction

Colloidally Stable Amphibious Nanocrystals Derived from Poly{[2‐(dimethylamino)ethyl] Methacrylate} Capping

Hongwei Duan、Min Kuang、Dayang Wang 等 5 位作者2005-01-31Angewandte Chemie International Edition

Polymer brushes are grown on both hydrophobic and hydrophilic nanocrystals by surface-initiated atom-transfer radical polymerization. The poly{[2-(dimethylamino)ethyl] methacrylate}-coated nanocrystals are well dispersed in both water and most organic solvents without detectable aggregation and deterioration of their…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesPolymer Surface Interaction Studies

Upconversion photoluminescence in poly(ladder-type-pentaphenylene) doped with metal (II)-octaethyl porphyrins

Stanislav Baluschev、Panagiotis E. Keivanidis、Gerhard Wegner 等 9 位作者2005-01-31Applied Physics Letters

We report on the optimization of the upconversion photoluminescence in films of conjugated polymers doped with platinum porphyrin. The upconversion emission was observed to take place at pump intensities as low as 0.5kW∕cm2. Comparison between the photoluminescence integral intensity of polyfluorene and ladder-type pe…

Organic Electronics and PhotovoltaicsPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Electron-phonon interaction in ultrasmall-radius carbon nanotubes

Ryan Barnett、Eugene Demler、Efthimios Kaxiras2005-01-31Physical Review B

We perform analysis of the band structure, phonon dispersion, and electron-phonon interactions in three types of small-radius carbon nanotubes. We find that the (5,5) nanotube can be described well by the zone-folding method and the electron-phonon interaction is too small to support either a charge-density wave or su…

Carbon Nanotubes in CompositesGraphene research and applicationsBoron and Carbon Nanomaterials Research

Structural and magnetic properties of the single-layer manganese oxideLa1−xSr1+xMnO4

Sophie LaRochelle、Apurva Mehta、Li Lu 等 9 位作者2005-01-31Physical Review B

Using x-ray and neutron scattering, we have studied the structural and magnetic properties of the single-layer manganite ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Sr}}_{1+x}{\mathrm{MnO}}_{4}(0\ensuremath{\leqslant}x<0.7)$. Single crystals were grown by the floating-zone method at $18\phantom{\rule{0.3em}{0ex}}\mat…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Decomposition reactions forNaAlH4,Na3AlH6, and NaH: First-principles study

Xuezhi Ke、Isao Tanaka2005-01-31Physical Review B

The electronic properties and lattice dynamics of the sodium alanate phases have been studied by the density functional calculations. The phases include $\mathrm{Na}\mathrm{Al}{\mathrm{H}}_{4}$ (space group, $I{4}_{1}∕a$), ${\mathrm{Na}}_{3}\mathrm{Al}{\mathrm{H}}_{6}$ (space group, $P{2}_{1}∕n$), and NaH (space group…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsSuperconductivity in MgB2 and Alloys

Integration of metal oxide nanobelts with microsystems for nerve agent detection

Choongho Yu、Qing Hao、Sanjoy Kumar Saha 等 6 位作者2005-01-31Applied Physics Letters

We have assembled tin dioxide nanobelts with low-power microheaters for detecting dimethyl methylphosphonate (DMMP), a nerve agent simulant. The electrical conductance of a heated nanobelt increased for 5% upon exposure to 78 parts per billion DMMP in air. The nanobelt conductance recovered fully quickly after the DMM…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Preparation of As-doped p-type ZnO films using a Zn3As2∕ZnO target with pulsed laser deposition

Veeramuthu Vaithianathan、Byung‐Teak Lee、Sang Sub Kim2005-01-31Applied Physics Letters

We report the preparation of arsenic doped p-type ZnO films using a Zn3As2∕ZnO target by pulsed laser deposition. Zn3As2 was used as a p-type dopant source material for arsenic doping in ZnO. The existence of As in the As-doped ZnO films was confirmed by the x-ray photoelectron spectroscopy study. The p-type behavior…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

The electronic structure of liquid water within density functional theory

David Prendergast、Jeffrey C. Grossman、Giulia Galli2005-01-31arXiv

In the last decade, computational studies of liquid water have mostly concentrated on ground state properties. However recent spectroscopic measurements have been used to infer the structure of water, and the interpretation of optical and x-ray spectra requires accurate theoretical models of excited electronic states,…

Materials ScienceSoft Condensed Matter

Making sense of nanocrystal lattice fringes

P. Fraundorf、W. Qin、Peter Moeck 等 4 位作者2005-01-31arXiv

The orientation-dependence of thin-crystal lattice fringes can be gracefully quantified using fringe-visibility maps, a direct-space analog of Kikuchi maps. As in navigation of reciprocal space with the aid of Kikuchi lines, fringe-visibility maps facilitate acquisition of 3D crystallographic information in lattice im…

Materials Sciencephysics.atm-clusphysics.ins-det

Lanthanide(III) Complexes of a Mono(methylphosphonate) Analogue of H4dota: The Influence of Protonation of the Phosphonate Moiety on the TSAP/SAP Isomer Ratio and the Water Exchange Rate

J. Rudovský、Petr Cígler、Jan Kotek 等 9 位作者2005-01-31Chemistry - A European Journal

A monophosphonate analogue of H4dota, 1,4,7,10-tetraazacyclododecane-4,7,10-tris(carboxymethyl)-1-methylphosphonic acid (H5do3aP), and its complexes with lanthanides were synthesized. Multinuclear NMR studies reveal that, in aqueous solution, lanthanide(III) complexes of the ligand exhibit structures analogous to thos…

Advanced MRI Techniques and ApplicationsRadioactive element chemistry and processingLanthanide and Transition Metal Complexes