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A turn-on fluorogenic Zn( ii ) chemoprobe based on a terpyridine derivative with aggregation-induced emission (AIE) effects through nanofiber aggregation into spherical aggregates

Sung Ho Jung、Ki‐Young Kwon、Jong Hwa Jung2014-09-01Chemical Communications

The self-assembly of a terpyridine-based ligand in a DMSO/water solvent mixture (1 : 99 v/v) with a high content of water formed a nanofibrillar structure and showed a non-emissive process. On the other hand, the self-assembly of the terpyridine-based ligand exhibited strong emission in the presence of Zn(2+) due to t…

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Rational Design of Gold Nanoparticle Toxicology Assays: A Question of Exposure Scenario, Dose and Experimental Setup

Ulrike Taylor、Christoph Rehbock、Carmen Streich 等 5 位作者2014-09-01Nanomedicine

Many studies have evaluated the toxicity of gold nanoparticles, although reliable predictions based on these results are rare. In order to overcome this problem, this article highlights strategies to improve comparability and standardization of nanotoxicological studies. To this end, it is proposed that we should adap…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsHealthcare and Environmental Waste Management

Poly(ε-caprolactone)-based polymer electrolyte for electrical double-layer capacitors

H. J. Woo、Chiam–Wen Liew、S.R. Majid 等 4 位作者2014-09-01High Performance Polymers

The potential of electrical double-layer capacitors (EDLCs) fabricated from symmetry activated carbon electrodes and poly(ε-caprolactone) (PCL)-based polymer electrolytes (PE) have been studied. PEs that consisted of PCL, ammonium thiocyanate, and ethylene carbonate (EC) were prepared by solution casting. In this syst…

Supercapacitor Materials and FabricationAdvanced Battery Materials and TechnologiesConducting polymers and applications

Synthesis and Characterization of Poly(Methyl Methacrylate) PMMA and Evaluation of Cytotoxicity for Biomedical Application

Paulo Emílio Feuser、Pâmela Cristina Gaspar、Eduardo Ricci‐Júnior 等 7 位作者2014-09-01Macromolecular Symposia

Summary The objective this work was the synthesis, characterization and evaluation of cytotoxicity poly(methyl methacrylate), PMMA, nanoparticles (NPs) produced using miniemulsion polymerization technique adopting azobisisobutylonitrile (AIBN) as initiator and biocompatible and biodegradable surfactant, lecithin and c…

Nanoparticle-Based Drug DeliveryAdvanced Polymer Synthesis and CharacterizationSurfactants and Colloidal Systems

Modelling of projectile penetration using transparent soils

Zhibo Chen、Mehdi Omidvar、Magued Iskander 等 4 位作者2014-09-01International Journal of Physical Modelling in Geotechnics

This paper presents a novel physical modelling method to study projectile penetration problems. The method employs a recently developed transparent synthetic soil made of oil-saturated fused quartz, which represents the macroscopic behaviour of silica sand. Digital image correlation (DIC, also known as particle image…

Landslides and related hazardsHigh-Velocity Impact and Material BehaviorElectromagnetic Launch and Propulsion Technology

Controlled stimulation-burst targeted release by smart decentered core–shell microcapsules in gravity and magnetic field

Xue-Hui Ge、Jin-Pei Huang、Jianhong Xu 等 4 位作者2014-09-01Lab on a Chip

By combining gravity and magnetic force, we have developed a versatile and facile microfluidic method for forming magnetic decentered core-shell microcapsules in which the directions of the oil core and the magnetic nanoparticles are either opposed or the same. When the temperature rises above the LCST of the PNIPAm,…

Micro and Nano RoboticsPickering emulsions and particle stabilizationElectrohydrodynamics and Fluid Dynamics

On Sr1–xNaxSiO3–0.5x New Superior Fast Ion Conductors

Ivana Radosavljević Evans、John S. O. Evans、Heather G. Davies 等 5 位作者2014-09-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTOn Sr1–xNaxSiO3–0.5x New Superior Fast Ion ConductorsIvana Radosavljevic Evans*, John S. O. Evans, Heather G. Davies, Abby R. Haworth, and Matthew L. TateView Author Information Department of Chemistry, Durham University, Science Site, South Road, Durham, DH1 3LE, Unit…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Normalized evaluation of thermal shock resistance for ceramic materials

Kai Li、Dalei Wang、Han Chen 等 4 位作者2014-09-01Journal of Advanced Ceramics

A normalized method for evaluation of thermal shock resistance for ceramic materials was proposed. A thermal shock resistance index (TSRI), Г , in the range of 1 to 100, was introduced, based on a normalized formula obtained directly by a simple testing process of determining the changes in flexural strength before an…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

Moving towards the cold region or the hot region? Thermocapillary migration of a droplet attached on a horizontal substrate

Yi Sui2014-09-01Physics of Fluids

We study computationally thermocapillary migration of a two-dimensional droplet attached on a horizontal substrate with a constant temperature gradient. A level-set approach is employed to track the droplet interface and a Navier slip boundary condition is imposed to alleviate a stress singularity at the moving contac…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferFluid Dynamics and Thin Films

Physical-Mechanical Properties of the Modified Fine-Grained Concrete Subjected to Thermal Effects up to 200°С

Volodymyr I. Korsun、Nikolai Vatin、Artem Korsun 等 4 位作者2014-09-01Applied Mechanics and Materials

The article introduces the results of the experimental research of the influence of elevated temperatures on the modified fine-grained concrete strength and strain under axial compression.

Construction Management and SustainabilityStructural mechanics and materialsAdvanced Energy Technologies and Civil Engineering Innovations

Influence of different extrusion processes on mechanical properties of magnesium alloy

Qingshan Yang、Bin Jiang、Hucheng Pan 等 8 位作者2014-09-01Journal of Magnesium and Alloys

AZ31 Mg alloy sheets were processed by the conventional symmetrical extrusion (CSE) and the asymmetric extrusion (ASE). Progressive-asymmetric extrusion (PASE) and severe strain-asymmetric extrusion (SASE) were employed for ASE processes. The texture at near-surface and mid-layer zones of ASE sheets was diverse penetr…

Magnesium Alloys: Properties and ApplicationsAluminum Alloys Composites PropertiesAdvanced Welding Techniques Analysis

Effect of Ca addition on modification of primary Mg2Si, hardness and wear behavior in Mg–Si hypereutectic alloys

M. E. Moussa、Mostafa I. Waly、A.M. El-Sheikh2014-09-01Journal of Magnesium and Alloys

The effect of Ca addition on modification of primary Mg2Si, hardness and wear behavior in Mg–5 wt.%Si hypereutectic alloy has been investigated. The results showed clearly that without Ca addition, most of primary Mg2Si appeared as coarse dendritic morphology with average size of about 215 μm. With the addition of 0.1…

Metal and Thin Film MechanicsMagnesium Alloys: Properties and ApplicationsAluminum Alloys Composites Properties

Landau theory for helical nematic phases

E. I. Kats、V. V. Lebedev2014-09-01Journal of Experimental and Theoretical Physics Letters

We propose Landau phenomenology for the phase transition from the conventional nematic into the conical helical orientationally non-uniform structure recently identified in liquid crystals formed by “banana”-shaped molecules. The mean field predictions are mostly in agreement with experimental data. Based on the analo…

Liquid Crystal Research AdvancementsPlant Reproductive BiologyMolecular spectroscopy and chirality

How much do nanoparticle fillers improve the modulus and strength of polymer foams?

Juan Lobos、Sachin Velankar2014-09-01Journal of Cellular Plastics

Nanofiller reinforcing agents can significantly improve the strength and modulus of polymer foams. But these improvements are often accompanied by changes in foam density (or equivalently the expansion ratio or void volume). The efficacy of nanofillers as reinforcing agents can only be judged once the density differen…

Polymer Nanocomposites and PropertiesTribology and Wear AnalysisPolymer Foaming and Composites

Synthesis, characterization, and bioactivity of carboxylic acid-functionalized titanium dioxide nanobelts

Raymond F. Hamilton、Nianqiang Wu、Chengcheng Xiang 等 8 位作者2014-09-01Particle and Fibre Toxicology

BACKGROUND: Surface modification strategies to reduce engineered nanomaterial (ENM) bioactivity have been used successfully in carbon nanotubes. This study examined the toxicity and inflammatory potential for two surface modifications (humic acid and carboxylation) on titanium nanobelts (TNB). METHODS: The in vitro ex…

Bone Tissue Engineering MaterialsNanoparticles: synthesis and applicationsMarine Biology and Environmental Chemistry

Multimodal Magneto‐Plasmonic Nanoclusters for Biomedical Applications

Chun‐Hsien Wu、Jason Cook、Stanislav Emelianov 等 4 位作者2014-09-01Advanced Functional Materials

Multimodal nanostructures can help solve many problems in the biomedical field including sensitive molecular imaging, highly specific therapy, and early cancer detection. However, the synthesis of densely packed, multicomponent nanostructures with multimodal functionality represents a significant challenge. Here, a ne…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and Applications

Influence of N-thiazolyl-2-cyanoacetamide derivatives on the corrosion of aluminum in 0.01 M sodium hydroxide

M. Abdallah、Omar A. Hazazi、Ahmed Fawzy 等 5 位作者2014-09-01Protection of Metals and Physical Chemistry of Surfaces

The effect of N-thiazolyl-2-cyanoacetamide derivatives on the corrosion of aluminum in 0.01N sodium hydroxide has been studied using weight-loss and glvanostatic polarization techniques. The inhibition efficiency was found to increase with increasing the concentration of inhibitor and with decreasing temperature. The…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityAnodic Oxide Films and Nanostructures

Subwavelength silicon through-hole arrays as an all-dielectric broadband terahertz gradient index metamaterial

Sang-Gil Park、Kanghee Lee、Daehoon Han 等 5 位作者2014-09-01Applied Physics Letters

Structuring at subwavelength scales brings out artificial media with anomalous optical features called metamaterials. All-dielectric metamaterials have high potential for practical applications over the whole electromagnetic spectrum owing to low loss and optical isotropy. Here, we report subwavelength silicon through…

Metamaterials and Metasurfaces ApplicationsTerahertz technology and applicationsAdvanced Antenna and Metasurface Technologies

Desorption Behaviours of Lithium Alanate with Metal Oxide Nanopowder Additives

M. Ismail、Azhar Mohd Sinin、Chan Kok Sheng 等 4 位作者2014-09-01International Journal of Electrochemical Science

The effects of metal oxide nanopowder (Fe2O3, Cr2O3, ZnO and MoO3) additions by dry ball milling on the hydrogen desorption behaviours of LiAlH4 have been investigated. Among them, adding Fe2O3 leads to the most pronounced improvement on the onset dehydrogenation temperature and desorption kinetic rate. The dehydrogen…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsAmmonia Synthesis and Nitrogen Reduction

Tuning Energy Splitting and Recombination Dynamics of Dark and Bright Excitons in CdSe/CdS Dot-in-Rod Colloidal Nanostructures

Louis Biadala、Benjamin Siebers、Raquel Guttierres Gomes 等 6 位作者2014-09-01The Journal of Physical Chemistry C

We report on a time-resolved study of the photoluminescence of core/shell CdSe/CdS dot-in-rod colloidal nanocrystals having various geometries. By studying the exciton recombination dynamics, we unveil a quadratic dependence of the bright–dark exciton energy splitting and the dark exciton radiative recombination rate…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films