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Electrochemical Characterization of Chemically Synthesized Polythiophene Thin Films: Performance of Asymmetric Supercapacitor Device

Bebi Patil、Swati J. Patil、C.D. Lokhande2014-09-01Electroanalysis

Abstract Polythiophene (PT) thin films have been prepared by chemical bath deposition (CBD) method at room temperature (300 K) via oxidative polymerization of thiophene using ammonium peroxodisulfate (APS) as an oxidizing agent. Globular particulates of PT are deposited on the stainless steel and glass substrates. The…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Heterostructures based on inorganic and organic van der Waals systems

Gwan‐Hyoung Lee、Chul‐Ho Lee、Arend M. van der Zande 等 10 位作者2014-09-01APL Materials

The two-dimensional limit of layered materials has recently been realized through the use of van der Waals (vdW) heterostructures composed of weakly interacting layers. In this paper, we describe two different classes of vdW heterostructures: inorganic vdW heterostructures prepared by co-lamination and restacking; and…

Graphene research and applications2D Materials and ApplicationsAdvanced Thermoelectric Materials and Devices

Cancer Theranostics with Gold Nanoshells

Jun Zhao、Michael B. Wallace、Marites P. Melancon2014-09-01Nanomedicine

Gold nanoshells (AuNSs) present a vivid example of integrating nanoscience in order to solve a biomedical problem. AuNSs exhibit tunable surface plasmon resonance, which can be tuned to the near-infrared region in order to realize optimal tissue penetration. The highly efficient light-to-heat transformation by AuNSs d…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsNanoplatforms for cancer theranostics

Control of shell pigmentation by secretory tubules in the abalone mantle

Alyssa M. Budd、Carmel McDougall、Kathryn Green 等 4 位作者2014-09-01Frontiers in Zoology

Molluscan shells exhibit a wide diversity of pigmentation patterns and are often used as models for understanding the mechanisms underlying biological pattern formation. Numerous mathematical models have been put forward to describe these patterns, but all rely on assumptions regarding the nature of the pigments and t…

Marine Bivalve and Aquaculture StudiesCalcium Carbonate Crystallization and InhibitionMarine Biology and Environmental Chemistry

Synthesis and Characterizations of Poly (Lactic Acid) by Ring-Opening Polymerization for Biomedical Applications

Milena Savioli Lopes、André Luiz Jardini、Rubens Maciel Filho2014-09-01Chemical engineering transactions

The development of biomaterials for application in medicine is one of the great challenges of research in material science. The poly (a-hydroxy acids) are the principal biodegradable and bioresorbable polymers used in tissue engineering. Among the biomaterials (biopolymers) used in the medical field, the poly (lactic…

biodegradable polymer synthesis and propertiesAdditive Manufacturing and 3D Printing TechnologiesCarbon dioxide utilization in catalysis

A Top Coat with Solvent Annealing Enables Perpendicular Orientation of Sub‐10 nm Microdomains in Si‐Containing Block Copolymer Thin Films

Eun‐jin Kim、Wonjung Kim、Kwang Hee Lee 等 5 位作者2014-09-01Advanced Functional Materials

Achieving sub‐10 nm high‐aspect‐ratio patterns from diblock copolymer self‐assembly requires both a high interaction parameter (χ, which is determined by the incompatibility between the two blocks) and a perpendicular orientation of microdomains. However, these two conditions are extremely difficult to achieve simulta…

Organic Electronics and PhotovoltaicsBlock Copolymer Self-AssemblyFluid Dynamics and Thin Films

High electron mobility thin-film transistors based on Ga2O3 grown by atmospheric ultrasonic spray pyrolysis at low temperatures

Stuart R. Thomas、George Adamopoulos、Yen‐Hung Lin 等 9 位作者2014-09-01Applied Physics Letters

We report on thin-film transistors based on Ga2O3 films grown by ultrasonic spray pyrolysis in ambient atmosphere at 400–450 °C. The elemental, electronic, optical, morphological, structural, and electrical properties of the films and devices were investigated using a range of complementary characterisation techniques…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

New experimental methodology, setup and LabView program for accurate absolute thermoelectric power and electrical resistivity measurements between 25 and 1600 K: Application to pure copper, platinum, tungsten, and nickel at very high temperatures

L. Abadlia、F. Gasser、K. Khalouk 等 5 位作者2014-09-01Review of Scientific Instruments

In this paper we describe an experimental setup designed to measure simultaneously and very accurately the resistivity and the absolute thermoelectric power, also called absolute thermopower or absolute Seebeck coefficient, of solid and liquid conductors/semiconductors over a wide range of temperatures (room temperatu…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Expansion and Ionic Conductivity

Green biosynthesis of silver nanoparticles using Torreya nucifera and their antibacterial activity

Duraisamy Kalpana、Jung H. Han、Whoa Shig Park 等 6 位作者2014-09-01Arabian Journal of Chemistry

Silver nanoparticles were biosynthesized with the aid of a novel and eco-friendly biological material Torreya nucifera. Temperature and extract concentration were found to influence the size and shape of the biosynthesized silver nanoparticles. Morphological images of biosynthesized nanomaterials revealed that the par…

Nanoparticles: synthesis and applicationsGraphene and Nanomaterials ApplicationsLaser-Ablation Synthesis of Nanoparticles

Anti-corrosive Properties and Quantum Chemical Study of (E)- 4-Methoxy-N-(Methoxybenzylidene)Aniline and (E)-N-(4- Methoxybenzylidene)-4-Nitroaniline Coating on Mild Steel in Molar Hydrochloric.

H. Elmsellem、H. Nacer、F. Halaimia 等 10 位作者2014-09-01International Journal of Electrochemical Science

The effect of (E)-4-methoxy-N-(methoxybenzylidene)aniline (P1) and (E)-N-(4-methoxybenzylidene) -4-nitroaniline (P2) on the corrosion of steel in molar hydrochloric acid studied by weight loss and electrochemical polarisation. The results obtained reveal that the compounds reduce the corrosion rate. The inhibition eff…

Corrosion Behavior and InhibitionElectrochemical Analysis and ApplicationsConcrete Corrosion and Durability

Evaluation Techniques for the Corrosion Resistance of SelfHealing Coatings

Eman M. Fayyad、Mariam Al Ali Al‐Maadeed、A.H. Jones 等 4 位作者2014-09-01International Journal of Electrochemical Science

Self-healing coatings, materials that autonomically repair damage, are a method of extending the life of corrosion prevention coatings. The different types of self-healing coatings are briefly outlined. A review of the evaluation methods of the performance of self-healing coatings using electrochemical, surface and mi…

Corrosion Behavior and InhibitionPolymer composites and self-healingConcrete Corrosion and Durability

Generation of aminoborane monomers RR′NBH 2 from amine–boronium cations [RR′NH–BH 2 L] + : metal catalyst-free formation of polyaminoboranes at ambient temperature

Owen J. Metters、Andy M. Chapman、Alasdair P. M. Robertson 等 7 位作者2014-09-01Chemical Communications

Protonation of MeRNH·BH3 (R = Me or H) with HX (X = B(C6F5)4, OTf, or Cl), followed by immediate, spontaneous H2 elimination, yielded the amine-boronium cation salt [MeRNH·BH2(OEt2)][B(C6F5)4] and related polar covalent analogs, MeRNH·BH2X (X = OTf or Cl). These species can be deprotonated to conveniently generate rea…

Hydrogen Storage and MaterialsOrganoboron and organosilicon chemistryBoron Compounds in Chemistry

Dynamic spreading on pillar-arrayed surfaces: Viscous resistance versus molecular friction

Quanzi Yuan、Xianfu Huang、Ya-Pu Zhao2014-09-01Physics of Fluids

The dynamic spreading of a liquid droplet on micropillar-arrayed surfaces is experimentally investigated. A theoretical model is proposed to include energy dissipations raised from both the viscous resistance at mesoscale and the molecular friction at microscale in the triple-phase region. The scaling laws and spreadi…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferFluid Dynamics and Thin Films

3D Bioprinting of Cellulose Structures from an Ionic Liquid

Kajsa Markstedt、Johan Sundberg、Paul Gatenholm2014-09-013D Printing and Additive Manufacturing

Abstract This article reports on 3D bioprinting of dissolved cellulose to produce small feature structures with a tailored design of regenerated cellulose. The process consists of dissolving cellulose with different origins and molecular weight in an ionic liquid (1-ethyl-3-methylimidazolium acetate), controlled multi…

Advanced Cellulose Research StudiesAdditive Manufacturing and 3D Printing Technologies3D Printing in Biomedical Research

Polymeric nanocarriers for expected nanomedicine: current challenges and future prospects

Bihter Daglar、E. Ozgur、M. Emin Çorman 等 5 位作者2014-09-01RSC Advances

Polymeric nanocarriers have an increasingly growing potential for clinical applications. The current and future expectation from a polymeric nanocarrier is to exhibit both diagnostic and therapeutic functions. Living organisms are very complex systems and have many challenges for a carrier system such as biocompatibil…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsGraphene and Nanomaterials Applications

Antibacterial activity and cytotoxicity of multi-walled carbon nanotubes decorated with silver nanoparticles

Jonghoon Choi、Youngmin Seo、Jangsun Hwang 等 6 位作者2014-09-01International Journal of Nanomedicine

Recently, various nanoscale materials, including silver (Ag) nanoparticles, have been actively studied for their capacity to effectively prevent bacterial growth. A critical challenge is to enhance the antibacterial properties of nanomaterials while maintaining their biocompatibility. The conjugation of multiple nanom…

Nanoparticles: synthesis and applicationsGraphene and Nanomaterials ApplicationsNanotechnology research and applications

Preparation of folic acid-conjugated, doxorubicin-loaded, magnetic bovine serum albumin nanospheres and their antitumor effects in vitro and in vivo

Rui Yang、Qiusha Tang、Yanli An 等 6 位作者2014-09-01International Journal of Nanomedicine

BACKGROUND: This study aimed to generate targeted folic acid-conjugated, doxorubicin-loaded, magnetic iron oxide bovine serum albumin nanospheres (FA-DOX-BSA MNPs) that lower the side effects and improve the therapeutic effect of antitumor drugs when combined with hyperthermia and targeting therapy. A new nanodrug usi…

Nanoparticle-Based Drug DeliveryChemotherapy-induced cardiotoxicity and mitigationProtein Interaction Studies and Fluorescence Analysis

Equivalent circuit model of an ultra-thin polarization-independent triple band metamaterial absorber

Somak Bhattacharyya、Saptarshi Ghosh、Kumar Vaibhav Srivastava2014-09-01AIP Advances

This paper presents equivalent circuit modeling of an ultra-thin polarization-independent metamaterial microwave absorber consisting of three concentric closed ring resonators (CRR). The unit cell size as well as the other geometrical dimensions like radii and widths of the rings are optimized so that absorptions take…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Evaluation of the fatigue macro-cracking behavior of crumb rubber modified bituminous mixes

F. Moreno-Navarro、M. C. Rubio-Gámez、E. Tomás-Fortún 等 5 位作者2014-09-01Materiales de Construccion

The use of crumb rubber modified bitumen (CRMB) in asphalt mixes is a road engineering technology that has become increasingly important in recent years. Given the many economic and environmental benefits of this type of binder, the goal is to give CRMB the same level of performance as conventional polymer-modified bi…

Laboratory comparison of aging characteristics of warm mix asphalts involving natural and synthetic water containing additives

Ali Topal、Peyman Aghazadeh Dokandari2014-09-01Materials Research

When comparing the aging characteristics of hot and warm mix asphalts from a technical point of view, it can intuitively be expected that a warm mix asphalt would be less subjected to aging-induced failures due to lower application temperatures. Since the side effects of warm asphalt technology should be investigated…