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Carbon Dioxide Conversion by Reverse Water–Gas Shift Chemical Looping on Perovskite-Type Oxides

Yolanda A. Daza、Ryan A. Kent、Matthew M. Yung 等 4 位作者2014-03-19Industrial & Engineering Chemistry Research

Carbon dioxide conversion to carbon monoxide was studied in an intensified chemical looping reverse water–gas shift reaction (RWGS–CL) process using parent perovskite-type oxides as oxygen carriers. Five different strontium-doped lanthanum cobaltites, La 1– X Sr X CoO 3−δ (0 ≤ X ≤1 in steps of 0.25), were synthesized…

Advancements in Solid Oxide Fuel CellsChemical Looping and Thermochemical ProcessesCatalysis and Oxidation Reactions

Dielectrophoresis-Enhanced Plasmonic Sensing with Gold Nanohole Arrays

Avijit Barik、Lauren M. Otto、Daehan Yoo 等 6 位作者2014-03-19Nano Letters

We experimentally demonstrate dielectrophoretic concentration of biological analytes on the surface of a gold nanohole array, which concurrently acts as a nanoplasmonic sensor and gradient force generator. The combination of nanohole-enhanced dielectrophoresis, electroosmosis, and extraordinary optical transmission th…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchMicrofluidic and Bio-sensing Technologies

Rapid and accurate T2 mapping from multi–spin‐echo data using Bloch‐simulation‐based reconstruction

Noam Ben‐Eliezer、Daniel K. Sodickson、Kai Tobias Block2014-03-19Magnetic Resonance in Medicine

PURPOSE: Quantitative T2 -relaxation-based contrast has the potential to provide valuable clinical information. Practical T2 -mapping, however, is impaired either by prohibitively long acquisition times or by contamination of fast multiecho protocols by stimulated and indirect echoes. This work presents a novel postpr…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesAdvanced Neuroimaging Techniques and Applications

Tuning Ideal Tensile Strengths and Intrinsic Ductility of bcc Refractory Alloys

Qi Liang、D. C. Chrzan2014-03-19Physical Review Letters

An important theoretical ductility criterion for group V and VI metal-based refractory alloys in body-centered cubic (bcc) lattices is the mechanical failure mode of their perfect crystals under tension along the weakest direction [100]. Pure Mo and W fail by cleavage and are deemed intrinsically brittle. However, fir…

Intermetallics and Advanced Alloy PropertiesSemiconductor materials and interfacesMetallurgical and Alloy Processes

Cooperation between Coulomb and Electron–Phonon Interactions in Fulleride Superconductors

Satoshi Yamazaki、Yoshio Kuramoto2014-03-19Proceedings of the 12th Asia Pacific Physics Conference (APPC12)

We study cooperative effects between Coulomb and electron-phonon interactions in Alkali-metal doped fullerides (A 3 C 60 ) using multiorbital Hubbard-Holstein model. By taking the random phase approximation, we find that the isotropic superconductivity (SC) is stabilized mainly by the electronphonon interaction in str…

Physics of Superconductivity and MagnetismIron-based superconductors researchSuperconductivity in MgB2 and Alloys

Ultraviolet-induced free radical reactions in ENR50/alkyd blend leading to significant increase in cross-linking

Yoke Kum Khong、Desmond Teck‐Chye Ang、Seng Neon Gan2014-03-19Journal of Elastomers & Plastics

In this work, the potential of palm stearin alkyd as a cross-linking agent for rubber compounding was investigated. Alkyd carrying pendent –COOH groups was blended with epoxidised natural rubber (ENR50) via solvent casting technique at ambient temperature. Spectroscopic characterisations show that ENR50 and alkyd have…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingPolymer Nanocomposite Synthesis and Irradiation

Influence of ethylene–propylene–diene terpolymer addition on processing parameters, phase structure and thermal behaviour of polypropylene/low-density polyethylene blends

Nina Vranješ Penava、Vesna Rek、Miroslav Šlouf 等 4 位作者2014-03-19Journal of Elastomers & Plastics

The influence of blend composition and ethylene–propylene–diene terpolymer (EPDM) content on the processing parameters, phase structure and thermal behaviour of polypropylene (PP) and low-density polyethylene (LDPE) blends was studied. Processing parameters of blends in twin-screw extruder were followed by output ( Q)…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Electrochemical and gravimetric studies of the corrosion inhibition of mild steel in HCl medium by cephalexin drug

I. A. Akpan、Nnanake‐Abasi O. Offiong2014-03-19OpenAlex

The inhibition effect of cephalexin drug on the corrosion of mild steel in hydrochloric acid medium was investigated by electrochemical and gravimetric techniques at room temperature. The results obtained show that the drug significantly increased the polarization resistance of mild steel by reducing corrosion current…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsConcrete Corrosion and Durability

Effect of Silica Nanoparticles Modification on the Thermal, Structural, and Decomposition Properties of a β‐Nucleated Poly(propylene‐co‐ethylene) Matrix

Dimitrios G. Papageorgiou、G. Vourlias、Dimitrios Ν. Bikiaris 等 4 位作者2014-03-19Macromolecular Chemistry and Physics

In the current investigation, nanocomposites containing a β‐nucleated poly(propylene‐co‐ethylene) (PPR) matrix filled with untreated (SiO2) and methacrylate‐modified silica nanoparticles (SiO2‐MAA) are prepared. Transmission electron microscopy (TEM) reveals the improvement in the quality of dispersion due to the surf…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Effect of multiwalled carbon nanotube and temperature on dielectric and impedance spectroscopy of chlorobutyl elastomer nanocomposites

Shashi Kant Tiwari、Ram Naresh Prasad Choudhary、S. P. Mahapatra2014-03-19Journal of Elastomers & Plastics

Dielectric relaxation characteristics of multiwalled carbon nanotube (MWCNT)-reinforced chlorobutyl (CIIR) nanocomposites have been studied as a function of frequency (100–10 6 Hz) at different filler loadings (0, 2, 4, 6 and 8 phr) over a wide range of temperatures (30–120°C). The effect of MWCNT loadings and tempera…

Polymer Nanocomposites and PropertiesConducting polymers and applicationsDielectric materials and actuators

Temperature Dependence of Internal Field by Analysis of Specific Heat on an Organic Conductor λ-BETS2FeCl4

Kazuo Shimada、Hiroshi Akiba、Naoya Tajima 等 8 位作者2014-03-19Proceedings of the 12th Asia Pacific Physics Conference (APPC12)

-BETS2FeCl4 (BETS = bis (ethylenedithio) tetraselenafulvalene) system exhibits a mysterious paramagnetic metal (PM)–antiferromagnetic insulator (AFI) phase transition. Just after AF ordering, the large entropy of the Fe 3d localized spin still remains. To investigate why the mysterious free 3d spin exists in the  sp…

Perovskite Materials and ApplicationsMagnetism in coordination complexesOrganic and Molecular Conductors Research

Antireflection-enhanced color by a natural graded refractive index (GRIN) structure

Chad M. Eliason、Matthew D. Shawkey2014-03-19Optics Express

Nanostructured materials like graded refractive index (GRIN) structures in moth eyes have inspired the design of novel antireflective coatings. Such structures are more flexible than uniform coatings, but applications have been mainly limited to broadband antireflection in solar cells and LEDs. Here we show that cylin…

Photonic Crystals and ApplicationsOptical Coatings and GratingsFern and Epiphyte Biology

Synthesis of 4H-SrMnO3.0 Nanoparticles from a Molecular Precursor and Their Topotactic Reduction Pathway Identified at Atomic Scale

Irma N. González-Jiménez、Almudena Torres‐Pardo、A.E. Sánchez 等 8 位作者2014-03-19Chemistry of Materials

Stoichiometric 4H-SrMnO 3.0 nanoparticles have been synthesized from thermal decomposition of a new molecular heterometallic precursor [SrMn(edta)(H 2 O) 5 ]· 3 / 2 H 2 O whose crystal structure has been solved by single crystal X-ray diffraction. From this precursor, highly homogeneous 4H-SrMnO 3.0 nanoparticles, wit…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Supramolecular Assemblies of Nucleoside Functionalized Carbon Nanotubes: Synthesis, Film Preparation, and Properties

Alessandra Micoli、Antonio Turco、Elsie Araujo 等 6 位作者2014-03-19Chemistry - A European Journal

Nucleoside-functionalized multi-walled carbon nanotubes (N-MWCNTs) were synthesized and characterized. A self-organization process using hydrogen bonding interactions was then used for the fabrication of self-assembled N-MWCNTs films free of stabilizing agents, polymers, or surfactants. Membranes were produced by usin…

Carbon Nanotubes in CompositesElectrochemical sensors and biosensorsConducting polymers and applications

Evaluation of corrosion performance of two Mn-containing stainless steel alloys

Ihsan‐ul‐Haq Toor2014-03-19International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract 300 series austenitic stainless steels (SSs) are widely used as structural materials in various corrosive environments because of their excellent corrosion resistance and good mechanical properties. However, due to the rapid increase in Ni cost over the last few years, there have been attempts to develop chea…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual Stresses

Thermal conductivity of simple liquids: Origin of temperature and packing fraction dependences

Yoshiki Ishii、Keisuke Sato、Mathieu Salanne 等 5 位作者2014-03-19The Journal of Chemical Physics

The origin of both weak temperature dependence and packing fraction dependence of T(1/4)η(3/2) in the thermal conductivity of the simple Lennard-Jones (LJ) liquid is explored. In order to discuss the relative contributions from attractive or repulsive part of the interaction potential separately, the thermal conductiv…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermal properties of materials

Microscopic model of domain wall motion

Andreas Leschhorn、Stephane Djoumbou、H. Kliem2014-03-19Journal of Applied Physics

Polarization switching is simulated using a model based on a sequence of single dipole flips. The single dipole flips are assumed to be thermally activated with transition rates depending on the local field. The time to switch a single dipole depends on the deterministic transition rate and on a probabilistic factor.…

Ferroelectric and Piezoelectric MaterialsAdvanced Memory and Neural ComputingTransition Metal Oxide Nanomaterials

Evolution of thermo‐physical properties of diamond/Cu composite materials under thermal shock load

Hong Guo、Zhi-Hui Bai、Ximin Zhang 等 6 位作者2014-03-19Rare Metals

Abstract In this paper, the two‐flume method was used to study the change laws of the thermal conductivity and thermal expansion coefficient of diamond/Cu composite materials with 100, 300, and 500 cycle numbers, under the action of thermal shock load between −196 and 85 °C; the X‐ray diffraction method (XRD) was used…

Advanced ceramic materials synthesisDiamond and Carbon-based Materials ResearchHigh-Velocity Impact and Material Behavior

Quantitative analysis of cell distribution in injection molded microcellular foam

SJA Rizvi、M. Hossein Alaei、Ashutosh Yadav 等 4 位作者2014-03-19Journal of Cellular Plastics

The microstructure of cellular materials, in particular microcellular polymers, is commonly characterized by the mean cell size and cell population density. Although the physical properties of foamed polymers are highly dependent on cell distribution, very insignificant work has been carried out to quantify the distri…

Cellular and Composite StructuresInjection Molding Process and PropertiesPolymer Foaming and Composites

Orange peel‐derived pectin jelly and corn starch‐based biocomposite film with layered silicates

Zerrin Çokaygil、Müfide Banar、A. Tuğrul Seyhan2014-03-19Journal of Applied Polymer Science

ABSTRACT Orange peel‐derived pectin jelly/corn starch‐based biocomposite films with and without layered silicates (LSs) were prepared using melt extrusion followed by film die casting. To enhance interfacial compatibility, corn starch and LSs were chemically modified. Regardless of chemical modification or LS weight c…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties