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Partially oxidized graphene as a precursor to graphene

Goki Eda、James M. Ball、Cecilia Mattevi 等 9 位作者2011-01-01Journal of Materials Chemistry

Solution exfoliation of graphite holds promise for large-scale bulk synthesis of graphene. Non-covalent exfoliation is attractive because the electronic structure of graphene is preserved but the yield is low and the lateral dimensions of the sheets are small. Chemical exfoliation via formation of graphite oxide is a…

Advancements in Battery MaterialsGraphene research and applications2D Materials and Applications

Urchin-like Co3O4 microspherical hierarchical superstructures constructed by one-dimension nanowires toward electrochemical capacitors

Linrui Hou、Changzhou Yuan、Long Yang 等 6 位作者2011-01-01RSC Advances

We describe in this report a novel synthetic strategy for synthesizing urchin-like Co3O4 microspherical hierarchical superstructures constructed by one-dimension Co3O4 nanowires, precipitating hydroxides followed by a calcinating process. Electrochemical data reveals that the as-synthesized urchin-like Co3O4 superstru…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Constant-Phase-Element Behavior Caused by Coupled Resistivity and Permittivity Distributions in Films

Marco Musiani、Mark E. Orazem、Nadine Pébère 等 5 位作者2011-01-01Journal of The Electrochemical Society

A recent proposed model showed that the impedance of a film with a uniform permittivity and a resistivity that varies along its thickness according to a power-law is in the form of a constant phase element (CPE). This model is further considered in order to assess the effect of non-uniform permittivity profiles. It is…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Ratiometric luminescent molecular oxygen sensors based on uni-luminophores of C⁁N Pt(ii)(acac) complexes that show intense visible-light absorption and balanced fluorescence/phosphorescence dual emission

Yifan Liu、Huimin Guo、Jianzhang Zhao2011-01-01Chemical Communications

Uni-luminophores of C^N cyclometalated Pt(II) complexes with balanced room temperature fluorescence/phosphorescence dual emission were prepared for ratiometric oxygen sensing in both intensity mode and lifetime mode.

Organic Light-Emitting Diodes ResearchLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors

Characterization of Multiwalled Carbon Nanotubes Dispersing in Water and Association with Biological Effects

Xuelian Cheng、Jun Zhong、Jie Meng 等 8 位作者2011-01-01Journal of Nanomaterials

Biomedical application potentials of carbon nanotubes-based materials have been investigated intensively in recent years; however, characterization and metrology are still facing great technical challenges when the materials are intended to be used as carriers for therapeutics in aqueous solutions. Systematic characte…

Carbon Nanotubes in CompositesNanoparticles: synthesis and applicationsGraphene and Nanomaterials Applications

Matrix-embedded silicon quantum dots for photovoltaic applications: a theoretical study of critical factors

Jun‐Wei Luo、Paul Stradins、Alex Zunger2011-01-01Energy & Environmental Science

Si Quantum dots (QD's) are offering the possibilities for improving the efficiency and lowering the cost of solar cells. In this paper we study the PV-related critical factors that may affect design of Si QDs solar cell by performing atomistic calculation including many-body interaction. First, we find that the weak a…

Quantum Dots Synthesis And PropertiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Highly symmetric polyhedral Cu2O crystals with controllable-index planes

Shaodong Sun、Chuncai Kong、Shengchun Yang 等 7 位作者2011-01-01CrystEngComm

Novel highly symmetric multi-faceted polyhedral Cu2O crystals enclosed by controllable high-index facets and different low-index facets have been synthesized via a template-free complex-precursor solution route. The formation and evolution of these polyhedral shapes can be attributed to the aggregation and ripening me…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Synthesis and photocatalytic activity of iodine-doped ZnO nanoflowers

Fatiha Barka-Bouaifel、Brigitte Sieber、Nacer Bezzi 等 8 位作者2011-01-01Journal of Materials Chemistry

The paper reports on the preparation and photocatalytic activity of thin films of iodine-doped ZnO nanoflowers deposited on glass substrate using a simple growth process based on hydrothermal synthesis. Addition of iodic acid (5–20 vol%) in the reaction mixture allows the introduction of iodine ions in the form of I−…

Advanced Photocatalysis TechniquesZnO doping and propertiesCopper-based nanomaterials and applications

Synthesis of highly porous borazine-linked polymers and their application to H2, CO2, and CH4 storage

Karl T. Jackson、Mohammad Gulam Rabbani、Thomas E. Reich 等 4 位作者2011-01-01Polymer Chemistry

The synthesis of highly porous borazine-linked polymers (BLPs) and their gas uptakes are reported. BLPs exhibit high surface areas up to 2866 m2 g−1 and can store significant amounts of H2 (1.93 wt%) and CO2 (12.8 wt%) at 77 K and 273 K, respectively at 1.0 bar with respective isosteric heats of adsorption of 6.0 and…

Metal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas TransportCovalent Organic Framework Applications

Controlled protein release from microcapsules with composite shells using high frequency ultrasound—potential for in vivo medical use

Anton M. Pavlov、Verónica Sáez Bernal、Andrew J. Cobley 等 6 位作者2011-01-01Soft Matter

The possibility of protein release from polymeric microcapsules by means of low-power (up to a maximum of 3.2 W) high-frequency (850 kHz) ultrasound was studied. The release efficiency using these ultrasonic parameters that are close to those currently used in medical diagnostic and ultrasound treatment was compared t…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies3D Printing in Biomedical Research

Effect of Ferrofluid on the Performance and Emission Patterns of a Four-Stroke Diesel Engine

Mohammad Behshad Shafii、Fariborz Daneshvar、N. Jahani 等 4 位作者2011-01-01Advances in Mechanical Engineering

Experimental tests were carried out to investigate the effects of adding water-based ferrofluid to diesel fuel in a diesel engine. These effects included the combustion performance and exhaust emission characteristics of the diesel engine. To this end, emulsified diesel fuels of 0, 0.4, and 0.8 ferrofluid/diesel ratio…

Catalytic Processes in Materials ScienceLubricants and Their AdditivesVehicle emissions and performance

Electrospinning-derived Tb2(WO4)3:Eu3+ nanowires: energy transfer and tunable luminescence properties

Zhiyao Hou、Ziyong Cheng、Guogang Li 等 10 位作者2011-01-01Nanoscale

One-dimensional Tb(2)(WO(4))(3) and Tb(2)(WO(4))(3):Eu(3+) nanowires have been prepared by a combination method of sol-gel process and electrospinning. X-Ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), photoluminescence (PL), low voltage cathodoluminescence (CL) and t…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsLuminescence and Fluorescent Materials

Assemblies of perylene diimide derivatives with melamine into luminescent hydrogels

Pradip K. Sukul、Deepak Asthana、Pritam Mukhopadhyay 等 9 位作者2011-01-01Chemical Communications

We report unique and spontaneous formation of hydrogels of perylene derivatives with melamine. The luminescent gel network is formed by H-type aggregation of the perylene core, supramolecularly cross-linked by melamine units. As a result of controlled aggregation in the extended nanofibers, strong exciton fluorescence…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials

Electrodeposition of 1.4-eV-Bandgap p-Copper (II) Oxide Film With Excellent Photoactivity

Masanobu Izaki、Miho Nagai、Keita Maeda 等 8 位作者2011-01-01Journal of The Electrochemical Society

Electrodeposition of 1.4-eV-Bandgap p-Copper (II) Oxide Film With Excellent Photoactivity, Izaki, Masanobu, Nagai, Miho, Maeda, Keita, Mohamad, Fariza Binti, Motomura, Kenjiro, Sasano, Junji, Shinagawa, Tsutomu, Watase, Seiji

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Aqueous room-temperature synthesis of Au–Rh, Au–Pt, Pt–Rh, and Pd–Rh alloy nanoparticles: fully tunable compositions within the miscibility gaps

Elizabeth R. Essinger-Hileman、Danielle DeCicco、James F. Bondi 等 4 位作者2011-01-01Journal of Materials Chemistry

Many binary late transition metal systems have large bulk miscibility gaps, and a variety of synthetic strategies have been developed to generate these non-equilibrium alloys as nanoparticles. While many of these methods strive to co-nucleate both elements by exploiting fast reduction kinetics or co-sequestration with…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceNanomaterials for catalytic reactions

Thermal Desorption Spectroscopy Study on the Hydrogen Trapping States in a Pure Aluminum

Takahiro Izumi、Goroh ITOH2011-01-01MATERIALS TRANSACTIONS

Hydrogen trapping states in pure aluminum foils with 99.99% purity with different amount of blisters have been investigated by means of thermal desorption spectroscopy. Three peaks are seen in the spectra, where the amount of hydrogen from the third peak at the highest temperature range increases with increasing in th…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

Electrical conductivity switching and memory effects in poly(N-vinylcarbazole) derivatives with pendant azobenzene chromophores and terminal electron acceptor moieties

Gang Liu、Bin Zhang、Yu Chen 等 9 位作者2011-01-01Journal of Materials Chemistry

Bistable electrical conductivity switching and non-volatile memory effects were demonstrated in Al/polymer/indium-tin oxide sandwich structure devices, constructed from two poly(N-vinylcarbazole) derivatives with pendant azobenzene chromophores and terminal electron acceptor moieties (–NO2 or –CN). Both polymers (PVK-…

Perovskite Materials and ApplicationsAdvanced Memory and Neural ComputingConducting polymers and applications

Direct study of the f-electron configuration in lanthanide systems

Kristina O. Kvashnina、Sergei M. Butorin、Pieter Glatzel2011-01-01Journal of Analytical Atomic Spectrometry

The valence shell electron configurations within a few electron volts above the Fermi level in cerium, ytterbium, europium and samarium compounds were probed by resonant X-ray emission spectroscopy (RXES) at the L3 absorption pre-edge. The rare earth systems show distinct spectral signatures depending on the f-electro…

Rare-earth and actinide compoundsX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Polyamine–salt aggregate assembly of capsules as responsive drug delivery vehicles

Hitesh G. Bagaria、Michael S. Wong2011-01-01Journal of Materials Chemistry

Responsive capsular delivery systems that can partly mimic the complexity of cellular systems hold great promise for the future of medicine. Simple self-assembled systems like liposomes are already in clinical use and others like polymeric micelles are under clinical trials. Unlike these self-assembled systems, the gr…

Nanoparticle-Based Drug DeliveryPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Existence of Weak Solutions for a Diffuse Interface Model for Two-Phase Flows of Incompressible Fluids with Different Densities

Helmut Abels、Daniel Depner、Harald Garcke2011-01-01University of Regensburg Publication Server (University of Regensburg)

We prove existence of weak solutions for a diffuse interface model for the \now of two\nviscous incompressible Newtonian \nfluids in a bounded domain in two and three space dimensions.\nIn contrast to previous works, we study a new model recently developed by Abels,\nGarcke, and Grün for \nfluids with different densit…

Solidification and crystal growth phenomenaAdvanced Mathematical Modeling in EngineeringFluid Dynamics and Thin Films