Materials Literature
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Atomically precise Au nanoclusters (NCs) have emerged as fascinating fluorescent nanomaterials and attracted considerable research interest in both fundamental research and practical applications. Due to enhanced quantum confinement, they possess extraordinary optical, electronic, and magnetic properties and therefore…
We use direct numerical simulations of the Poisson-Nernst-Planck equations to study the charging kinetics of porous electrodes and to evaluate the predictive capabilities of effective circuit models, both linear and nonlinear. The classic transmission line theory of de Levie holds for general electrode morphologies, b…
A supramolecular strategy is presented for the assembly of growth factors employing His6-tagged single-domain antibodies (VHH). A combination of orthogonal supramolecular interactions of β-cyclodextrin (βCD)-adamantyl (Ad) host-guest and N-nitrilotriacetic acid (NTA)-histidine (His) interactions was employed to genera…
Electrons in graphene aligned with hexagonal boron nitride are modeled by Dirac fermions in a correlated random-mass landscape subject to a scalar- and vector-potential disorder. We find that the system is insulating in the commensurate phase since the average mass deviates from zero. At the transition the mean mass i…
Environmental context Silver nanoparticles discharged with municipal wastewater may contaminate surface waters and harm aquatic ecosystems. We applied several analytical techniques to investigate the persistence and transformation of silver nanoparticles in a natural lake environment, and show, through multiple lines…
This paper describes the enhancement of the quantum yield of photoluminescence (PL) of CdSe quantum dots (QDs) upon the adsorption of an exciton-delocalizing ligand, phenyldithiocarbamate. Increasing the apparent excitonic radius by only 10% increases the value of the radiative rate constant by a factor of 1.8 and the…
The coupling of multiple plasmonic resonators that sustain bright or dark modes provide intriguing spectral signatures. However, probing the onset of coupling effects while engaging the resonators with an increasing proximity has not yet been studied experimentally in detail. Nevertheless, this is of utmost importance…
The growth of high quality graphene layers by chemical vapor deposition (CVD) has been found to strongly depend on growth conditions with results varying greatly from one laboratory to another for nominally identical conditions. We report the results of a systematic investigation of the role of hydrogen and oxidizing…
We propose a microscopic framework based on nonequilibrium statistical mechanics to connect the microscopic level of particle self assembly with the macroscopic rheology of colloidal gelation. The method is based on the master kinetic equations for the time evolution of the colloidal cluster size distribution, from wh…
We demonstrate a one-step, facile chemical synthesis of heterostructures based on two-dimensional (2D) transition metal dichalcogenides (TMDCs) with vertically aligned 2D layers. Specifically, by using a chemical vapor transport method, we synthesize molybdenum (Mo)/tungsten (W)-based disulfide and diselenide heterost…
Three key positions of graphene on a catalyst surface can be identified based on precise computations, namely as sunk (S), step-attached (SA), and on-terrace (OT). Surprisingly, the preferred modes are not all alike but vary from metal to metal, depending on the energies of graphene-edge "wetting" by the catalyst: on…
Modern drilling areas often involve extremely abrasive formations in conjunction with drilling practices that can include high build rates - short radius well bore sections, long extended horizontal sections, laterals, HDLS, spiraling - tortuous wellbores with high torque and drag. Any one of these conditions taken si…
In this article, first, we show that by contact work function engineering, electrostatic doping and proper scaling of both the oxide thickness and the flake thickness, high performance p- and n-type WSe2 field effect transistors (FETs) can be realized. We report record high drive current of 98 μA/μm for the electron c…
The structural preciseness of dendrimers makes them perfect drug delivery carriers, particularly in the form of dendrimer-drug conjugates. Current dendrimer-drug conjugates are synthesized by anchoring drug and functional moieties onto the dendrimer peripheral surface. However, functional groups exhibiting the same re…
In this work, the novel relationships of N 2 selectivity of NO reduction over MnO x –CeO 2 with the gas hourly space velocity (i.e., GHSV) and the reactants’ concentrations were discovered. Meanwhile, the mechanism of N 2 O formation during the low temperature selective catalytic reduction reaction (SCR) over MnO x –C…
An emulsion-based serial crystallographic technology has been developed, in which nanolitre-sized droplets of protein solution are encapsulated in oil and stabilized by surfactant. Once the first crystal in a drop is nucleated, the small volume generates a negative feedback mechanism that lowers the supersaturation. T…
Nanostructuring has spurred a revival in the field of direct thermoelectric energy conversion. Nanograined materials can now be synthesized with higher figures of merit (ZT) than the bulk counterparts. This leads to increased conversion efficiencies. Despite considerable effort in optimizing the known and discovering…
Using first-principles calculations, we investigated the impact of chromium (Cr) and vanadium (V) impurities on the magnetic anisotropy and spin polarization in Fe/MgO magnetic tunnel junctions. It is demonstrated, using layer resolved anisotropy calculation technique, that while the impurity near the interface has a…
We employ molecular beam epitaxy to stabilize ${\mathrm{Ba}}_{2}{\mathrm{IrO}}_{4}$ thin films and utilize in situ angle-resolved photoemission spectroscopy to investigate the evolution of its electronic structure through the N\'eel temperature ${T}_{\mathrm{N}}$. Our measurements indicate that dispersions of the rela…
We report magneto-resistive properties of direct and indirect band gap Bismuth-Antimony (Bi-Sb) alloys. Band gap increases with magnetic field. Large positive magnetoresistance (MR) approaching to 400% is observed. Low field MR experiences quadratic growth and at high field it follows a nearly linear behavior without…