Determination of the Minimum Surface Enrichment of Molybdenum Required to Inhibit Active Dissolution of an Fe‐Cr‐Ni‐Mo Alloy
Abstract not Available.
Materials Literature
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Evidence of a coupling between magnetic and chemical interactions in FeV alloys: metallurgical aspects
The influence of magnetism on the short-range order (SRO) and its temperature dependence is clearly pointed out in a Fe 0.9 V 0.1 alloy. Emphasis is placed on the metallurgical aspects of the study carried out by means of residual resistivity and nuclear magnetic resonance (NMR) measurements at low temperature. The or…
Iron(III) phthalocyanines: oxidation and spin states of iron in iron phthalocyanines with carboxyl groups
Mössbauer and e.s.r. spectroscopy have revealed that 2,3,9,10,16,17,23,24-octacarboxy-(1), 2,9,16,23-tetracarboxy-(2), and 2,9 (or 10)- and 2,16 (or 17)-bis(3′,4′-dicarboxybenzoyl)-phthalocyaninatoiron (3) are mixtures of high-spin iron (III) and low-spin iron (III) complexes and that intermediate-spin species may be…
Synthesis of poly-peri-naphthalene by vapour-phase polymerization: an approach to a one-dimensional graphite
Very fine whiskers grown via vapour-phase polymerization of 3,4,9,10-peryleneteracarboxylic dianhydride have a poly-peri-naphthalene structure.
Fracture Mechanics: Fifteenth Symposium
Description Subjects covered fall into several categories: theoretical, numerical, and experimental aspects of the mechanics of fracture; high-cycle fatigue; material influences on fracture; and elasto-plastic fracture mechanics.
Dissolution behavior of chlorpropamide polymorphs.
The dissolution profiles of chlorpropamide (CPM) polymorphs, especially the metastable form II reported by Al-Saieq et al., were investigated kinetically in detail by a dispersed amount method and a stationary disk method in comparison with those of the stable form. Form II showed a dissolution phenomenon involving si…
Encyclopedia of textiles, fibers, and nonwoven fabrics
This encyclopedia is another in the series of carefully selected reprints from the world-renowned Kirk-Othmer Encylopedia of Chemical Technology, designed to provide specific audiences with articles grouped by a central theme. As a handy desk reference, it incorporates all the original articles related to textiles, fi…
Deformation mechanism and dislocation structure of high‐purity molybdenum single crystals at low temperatures
Abstract High purity molybdenum single crystals were deformed in tension and compression along the symmetric double slip orientation [110] in the temperature range from 300 K down to 0.5 K with strain rates between 10 −3 and 10 −5 s −1 . The activation volume was measured by stress relaxation tests. The dislocation st…
Charge Density Wave-Soliton Model for Se and Te
A new microscopic theory is proposed for the electronic and lattice structures of crystal and defects of Se and Te. Consideration of the valence bond picture shows that electron correlation in valence p electrons produces a charge density wave (CDW) of vector nature, the vector CDW (VCDW), which has the period of thre…
Neutron diffraction structural study of pyroelectric Li2SO4⋅H2O at 293, 80, and 20 K
Lithium sulfate monohydrate has been studied at 293, 80, and 20 K by neutron diffraction using the same ground spherical crystal. Li2SO4⋅H2O is monoclinic, space group P21, with lattice dimensions at 293 K of a=5.450(3), b=4.872(3), c=8.164(4) Å, β=107.31(3)°; at 80 K: a=5.449(2), b=4.832(2), c=8.141(2) Å, β=107.21(1)…
Composition and Crystallinity of Electroless Nickel
Abstract not Available.
Smectic X : the first truly ferroelectric liquid crystal
We report the identification of the first truly ferroelectric liquid crystal in a compound which also shows chiral C, I and G' phases at higher temperatures. In the new phase the director can be oriented in a bistable way with an electric field V in a time τ such that V.ln τ is proportional to temperature. Furthermore…
Microstructural changes in as-cast M2 grade high speed steel during high temperature treatment
An optical and electron metallographic study has been carried out on chill and sand cast M2 grade high speed steel in the as-cast condition and after reheating to temperatures typical of those for hot working for times up to 200 h. The as-cast material contains M2C, MC, and M6C particles, but the M2C decomposes rapidl…
Continuous serial thin sectioning for electron microscopy
Abstract The process of serial sectioning for electron microscopy has been refined such that loss of thin sections is kept below 0.1% and the series is continued at will. The method relies on microscopic control of all manipulative steps, Formvar casting on plate glass for coated slot grids, coating of the block with…
Radiation-induced Formation of Thymine-thymine Crosslinks
The formation of dimers upon gamma-irradiation of thymine, thymidine and thymidine-5'-monophosphate in N2O-saturated aqueous solution is reported. A method using capillary gas chromatography-mass spectrometry was developed for their separation and identification. Quantitative measurements reveal that about 50 per cent…
Behaviour of poly(pyrrole) and poly(N‐methylpyrrole) electrodes in acetonitrile
Abstract The impedance of poly(pyrrole) (PP) and poly( N ‐methylpyrrole) (PMP) films on platinum in an acetonitrile, LiClO 4 solution has been measured. At potentials more positive than a characteristic value, the electrodes exhibit porous behaviour and the impedance is determined by the double‐layer capacitance and t…
Molecular orientation and anchoring energy at the nematic-isotropic interface of 7CB
The properties of the nematic-isotropic interface of the nematic liquid crystal 7CB are studied by optical reflectometry. It is found that at the interface the director is tilted with respect to the vertical axis. Measurements are reported of the tilt angle θt, of the thickness of the interface, and of the anchoring e…
Effect of oxy radicals on several types of collagen.
Fibrils of collagen reconstituted in vitro by dialysis against sodium formate are exposed to free oxy radicals generated by three different systems: (i) xanthine oxidase + hypoxanthine, (ii) gamma-rays originating from a cobalt bomb; (iii) pulse radiolysis in a particle accelerator. A degradation of the collagen fibre…
Observations on Rhizosolenia clevei Ostenfeld (Bacillariophyceae) and Richelia intracellularis Schmidt (Cyanophyceae)
Article Observations on Rhizosolenia clevei Ostenfeld (Bacillariophyceae) and Richelia intracellularis Schmidt (Cyanophyceae) was published on January 1, 1984 in the journal Botanica Marina (volume 27, issue 8).
Nature of S ⋯· O interaction in short X –S ⋯· O contacts: charge density experimental studies and theoretical interpretation
2-(2-Chlorobenzoylimino)-1,3-thiazolidine (I) and 3-benzoylimino-4-methyl-1,2,4-oxathiazane (II) present short intramolecular S ⋯· O contacts of 2.68 and 2.24 Å, respectively. X-Ray and neutron diffraction at 122 K performed on (II), for comparison with (I), already studied, led to experimental charge density deformat…