Materials Literature
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Abstract Environment‐friendly carboxymethyl cellulose (CMC) hydrogel beads were successfully prepared using epichlorohydrin (ECH) as a crosslinking agent in the suspension of fluid wax. There was an ether linkage formed between ECH and CMC, which was identified from bands in FTIR spectra of the prepared hydrogel. The…
A wide range of vanadium oxides have been obtained via the hydrothermal treatment of aqueous V(V) solutions. They exhibit a large variety of nanostructures ranging from molecular clusters to 1D and 2D layered compounds. Nanotubes are obtained via a self-rolling process while amazing morphologies such as nano-spheres,…
We present a transparent and flexible optoelectronic material composed of vertically aligned ZnO NWs grown on reduced graphene/PDMS substrates. Large-area reduced graphene films were prepared on PDMS substrates by chemical exfoliation from natural graphitevia oxidative aqueous dispersion and subsequent thermal reducti…
We demonstrate a controllable electromagnetic wave reflector/absorber for different polarizations with metamaterial involving electromagnetic resonant structures coupled with diodes. Through biasing at different voltages to turn ON and OFF the diodes, we are able to switch the structure between nearly total reflection…
The use of methylene-bridged calix[4]arenes in 3d/4f chemistry produces a family of clusters of general formula [Mn(III)(4)Ln(III)(4)(OH)(4)(C4)(4)(NO(3))(2)(DMF)(6)(H(2)O)(6)](OH)(2) (where C4 = calix[4]arene; Ln = Gd (1), Tb (2), Dy (3)). The molecular structure describes a square of Ln(III) ions housed within a squ…
We have studied the electronic structure of the nonmagnetic LiFeAs (T(c)∼18 K) superconductor using angle-resolved photoemission spectroscopy. We find a notable absence of the Fermi surface nesting, strong renormalization of the conduction bands by a factor of 3, high density of states at the Fermi level caused by a v…
The interaction of Li(+) with single and few layer graphene is reported. In situ Raman spectra were collected during the electrochemical lithiation of the single- and few-layer graphene. While the interaction of lithium with few layer graphene seems to resemble that of graphite, single layer graphene behaves very diff…
Interacting on all levels: A supramolecular polymer with a high degree of polymerization has been constructed on the basis of multiple host-stabilized charge-transfer interactions (see picture; DADV is a dianthracenyl bis(bipyridinium bromide), CB[8]=cucurbit[8]uril). Through interactions between supramolecular polyme…
Synergistic graphenes: The chemical and electrical synergies between graphene derivatives enable a simple, cost-effective and environmentally friendly strategy for solution-phase processing of graphene oxide (GO) and carbon nanotubes (CNTs). The new nanohybrid exhibits high performance when used as electrodes for supe…
Nanoscale carbon materials hold great promise for biotechnological and biomedical applications. Fluorescent nanodiamond (FND) is a recent new addition to members of the nanocarbon family. Here, we report long-term in vivo imaging of FNDs in Caenorhabditis elegans (C. elegans) and explore the nano-biointeractions betwe…
The growth of graphene on single crystal Cu(111) has been achieved by thermal decomposition of ethylene in an ultrahigh vacuum chamber for the first time. The structural and electronic properties of graphene on Cu(111) have been investigated by scanning tunneling microscopy and spectroscopy. The nucleation of monolaye…
Nanoparticles (NPs) can potentially cause adverse effects on organ, tissue, cellular, subcellular, and protein levels due to their unusual physicochemical properties (e.g., small size, high surface area to volume ratio, chemical composition, crystallinity, electronic properties, surface structure reactivity and functi…
High quality ZnO nanowires were synthesized by chemical vapor deposition using both a catalyst-assisted vapor-liquid-solid and a catalyst-free vapor-solid deposition approach. And their optical properties studied using photoluminescence and Raman spectroscopy combined with confocal laser scanning microscopy. Strong UV…
Abstract This paper presents an overview of the recent work on ultrathin polymer blend films containing cellulose. Three systems prepared via trimethylsilyl cellulose derivative, which is subsequently hydrolyzed to cellulose, are presented: polystyrene/cellulose, poly(methyl methacrylate)/cellulose and polystyrene‐ bl…
A new simple method for quantitatively evaluating the dynamic Bauschinger effect has been developed based on the measurement of elastoplastic loading-unloading profiles for a sample dynamically loaded by direct impact. The proposed method has been verified by testing a D16 aluminum alloy.
Molecular dynamical simulation is carried out to investigate the effects of the incident energy on a-C:H film growth from C and H atomic flux. Our simulations show that the film growth at low incident energy (1 eV) is dominated by the adsorption of H and C atoms. At moderate incident energy (10 and 20 eV), the abstrac…
The questions of strength and seismic stability of a new water-moderated water-cooled research reactor are examined. A computational method is developed and numerical investigation of static capacity and stability, brittle fracture resistance, long-term static capacity, long-term cyclic strength, and seismic load resp…
Various forms of underwater low-resistance scarfskins provide abundant shape resources for the manufacturing of the biomimetic drag-reducing surfaces. The drag-reducing surface based on scale groove of shark skin is one of the issue researches. A new bio- machining technology named bio-replicated forming based on crea…
A micromechanical constitutive model for responding the macroscopic behavior of porous shape memory alloys (SMA) has been proposed in this work. According to the micromechanical method, the stiffness tensor of the porous SMA is obtained. The critical stresses are calculated by elastic mechanics. Based on the general c…
This paper studies the influence of adsorption of methanol and iodine molecules on the conductivity of para-tetradecyloxybenzyliden-amino-2-methylbutyl-cyanocinnamate that was obtained using the Langmuir-Blodgett method. The growth of conductivity of the studied films at methanol absorption and the reduction of conduc…