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High photocatalytic activity of ‘clicked’ iron phthalocyanine conjugated with carbon nanofibers

Zhenjun Chang、Jing Zeng2014-08-13RSC Advances

Carbon nanofibers were used for the first time as substrates for the immobilization of photocatalytically active iron phthalocyanines by combining electrospinning and ‘click’ chemistry. The hybrid nanofibers exhibited high photocatalytic activity.

Conducting polymers and applicationsElectrospun Nanofibers in Biomedical ApplicationsPorphyrin and Phthalocyanine Chemistry

On the investigation of the effect of apparatus configurations on the nucleation mechanisms in a cooling crystallization of sodium chlorate

Craig J. Callahan、Xiongwei Ni2014-08-13The Canadian Journal of Chemical Engineering

Continuous crystallization plays a key role in the drive to deliver consistent crystal properties while minimizing solvent waste and undesired crystals. Plug flow crystallizers such as the continuous oscillatory baffled crystallizer (COBC) have been investigated. Kinetics studies are often carried out in batch OBCs wh…

Crystallization and Solubility StudiesChemical and Physical Properties in Aqueous SolutionsFreezing and Crystallization Processes

Design Considerations for ZnO Transistors Made Using Spatial ALD

Shelby F. Nelson、Carolyn R. Ellinger、Lee Tutt2014-08-13ECS Transactions

We have used spatial atomic layer deposition (SALD) to fabricate metal oxide thin-film devices with unusually simple processes. Selective area deposition allows us to fabricate transistors and circuits additively and with digital design variations when used in combination with an inkjet-printed inhibitor. In a second…

Semiconductor materials and devicesOptical Coatings and GratingsElectronic and Structural Properties of Oxides

Investigation into adsorption and photocatalytic degradation of gaseous benzene in an annular fluidized bed photocatalytic reactor

Qijin Geng、Shankang Tang、Lintong Wang 等 4 位作者2014-08-13Environmental Technology

The adsorption and photocatalytic degradation of gaseous benzene were investigated considering the operating variables and kinetic mechanism using nano-titania agglomerates in an annular fluidized bed photocatalytic reactor (AFBPR) designed. The special adsorption equilibrium constant, adsorption active sites, and app…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCatalytic Processes in Materials Science

Strain Energy and Structural Property of Methyl Substituted Imogolite

Geunyeong Park、Hoik Lee、Sang Uck Lee 等 4 位作者2014-08-13Molecular Crystals and Liquid Crystals

Aluminosilicate mineral, imogolite, with chemical composition [(OH)3Al2O3SiOH] has high monodispersity of diameter originated by the arrangements of inner hydroxyl (OH) groups that induced the strain energy minimum due to hydrogen bond networks. We have successfully synthesized substituted imogolite with methyl groups…

Clay minerals and soil interactionsGrouting, Rheology, and Soil Mechanics

Effects of Doping, Strain and Size on the Electrical Properties of MoS2 Nanoribbons

Sheng Yu、Qiliang Li、Kwesi Eshun2014-08-13ECS Transactions

In this work, we have investigated size, doping and strain effect on the electrical properties of n-type and p-type MoS2 monolayer, one of the most interesting two-dimensional layered materials. We found that the bandgap of the MoS2 will reduce from 1.8 eV to 1.2 eV as the infinite lattice being shrunk into 10×10 nano…

2D Materials and ApplicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Synthesis of Symmetrically Functionalized Oligo(het)arylenes Containing Phenylene, Thiophene, Benzthiophene, Furan, Benzofuran, Pyridine, and/or Pyrimidine Groups

Arne Lützen、Andreas Osadnik2014-08-13Synthesis

Rod-like oligomers consisting of thiophene and phenylene rings have proven to be highly interesting building blocks for the preparation of self-assembled, well-defined nanoaggregates via vapor deposition on solid supports. Changing the molecules’ chain length and substitution pattern allows to tailor the aggregates’ o…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSynthesis and Properties of Aromatic Compounds

Phase-locking of magnetic islands diagnosed by ECE-imaging

B. Tobias、B. A. Grierson、C. M. Muscatello 等 9 位作者2014-08-13Review of Scientific Instruments

Millimeter-wave imaging diagnostics identify phase-locking and the satisfaction of 3-wave coupling selection criteria among multiple magnetic island chains by providing a localized, internal measurement of the 2D power spectral density, S(ω, kpol). In high-confinement tokamak discharges, these interactions impact both…

Magnetic confinement fusion researchDiamond and Carbon-based Materials ResearchMagnetic Field Sensors Techniques

Full-Vectorial Beam-Propagation Methods Based on a Fundamental Scheme—Design of a Short Polarization Converter

Yuta Nito、Jun Shibayama、Junji Yamauchi 等 4 位作者2014-08-13Journal of Lightwave Technology

A fundamental scheme is utilized to reformulate the full-vectorial beam-propagation methods (BPMs). First, the fundamental scheme is introduced into the Fresnel equations which are discretized using the Crank-Nicolson method (FCN-BPM). The present FCN-BPM has the advantage that the total number of arithmetic operation…

Microwave Engineering and WaveguidesElectromagnetic Simulation and Numerical MethodsOptical Coatings and Gratings

Intrinsically tunable bulk acoustic wave resonators based on sol-gel grown PMN-PT films

Andrei Vorobiev、Matjaž Spreitzer、Asja Veber 等 5 位作者2014-08-13Journal of Applied Physics

Intrinsically tunable bulk acoustic wave resonators, based on sol-gel 0.70Pb(Mg1/3Nb2/3)O3-0.30PbTiO3 (PMN-PT) thin films, with high effective electromechanical coupling coefficient of 13% and tunability of the series resonance frequency up to 4.0% are fabricated and characterized. The enhanced electroacoustic propert…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsAcoustic Wave Resonator Technologies

Cracking Analysis of Automobile Rim Flash Butt Welding

Na Yin、Xian Tang Meng、Fei Li 等 5 位作者2014-08-13Advanced materials research

Aiming at the serious crack phenomenon of automobile rim butt welding in a domestic wheel plant, means of analysis such as chemical analysis, tensile test, bending test, macrocosmic and microcosmic examination were used to find out the formation mechanism. Results showed that the chemical compositions and mechanical p…

Metal Alloys Wear and PropertiesMechanical Engineering and Vibrations ResearchEngineering Applied Research

MgSrP3N5O2 – A Novel Oxonitridophosphate

Florian J. Pucher、Wolfgang Schnick2014-08-13Zeitschrift für anorganische und allgemeine Chemie

Abstract MgSrP3N5O2 was synthesized at 6 GPa and 1000 °C starting from Mg3N2, Sr(N3)2, PON, and P3N5 utilizing the multianvil technique. By applying NH4Cl as mineralizer, single crystals were obtained. MgSrP3N5O2 exhibits a novel structure type [P21/c (no. 14), a = 6.9404(8), b = 6.6103(7), c = 13.9317(12) Å, β = 118.…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationInorganic Chemistry and Materials

Development of a Gas-Fed Plasma Source for Pulsed High-Density Plasma/Material Interaction Studies

Michael Pachuilo、F. Stefani、Laxminarayan L. Raja 等 8 位作者2014-08-13IEEE Transactions on Plasma Science

A gas-fed capillary plasma source has been developed to study plasma-surface interactions under pulsed high pressure arc conditions, without the use of an exploding fuse wire or ablative liner. A nonintrusive preionization source has been developed to break down relatively large interelectrode gaps at low charge volta…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchVacuum and Plasma Arcs

The Influence of Carbonyl Nickel Content on Thermophysical Properties of Metal Polymer Materials Based on Aromatic Polyamide Phenylon

А. I. Burya、Yekaterina Yeriomina、Xiang Qian 等 4 位作者2014-08-13Advanced materials research

Introducing carbonyl nickel’s fine particles into a thermo-resistant polyamide phenylone can significantly improve thermo-physical characteristics of the CM and extend the operational temperature range of products made from these materials. Introducing carbonyl nickel in the amount of 5 – 20 mass %, thermo-resistance…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersThermal and Kinetic Analysis

Photo-Alignment Using Benzophenone Sensitized Photodecomposition of the Polyimide

Bo-Na Yang、Dong-Myung Shin2014-08-13Molecular Crystals and Liquid Crystals

For more aggressive photo-decomposition of polyimide, the photoreactions employing triplet mechanism and the double fragmentation reactions were carried out. The polyimide was synthesized with cyclobutane-1, 2, 3, 4-tetracarboxylic dianhydride (CBDA) and 4, 4′-diaminobenzophenone (DABP) by condensation reaction. The b…

Synthesis and properties of polymersSilicone and Siloxane ChemistryPhotopolymerization techniques and applications

Quantum Resistor-Capacitor Circuit with Majorana Fermion Modes in a Chiral Topological Superconductor

Minchul Lee、Mahn‐Soo Choi2014-08-13Physical Review Letters

We investigate the mesoscopic resistor-capacitor circuit consisting of a quantum dot coupled to spatially separated Majorana fermion modes in a chiral topological superconductor. We find substantially enhanced relaxation resistance due to the nature of Majorana fermions, which are their own antiparticles and are compo…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Comment on "Effects of dislocation mechanics on diffusion-induced stresses within a spherical insertion particle electrode" by P. Wei, J. Zhou, X. Pang, H. Liu, K. Deng, G. Wang, Y. Wu and B. Chen, J. Mater. Chem. A., 2014, 2, 1128

Fuqian Yang2014-08-13Journal of Materials Chemistry A

In this work, it is shown that the analysis by Wei et al. [Wei et al., J. Mater. Chem. A, 2014, 2, 1128–1136] is inappropriate for studying the effect of dislocation mechanics on diffusion-induced stresses. Using the theories of dislocation mechanics and plasticity, a set of equations for analyzing the effect of dislo…

Force Microscopy Techniques and ApplicationsSemiconductor materials and interfacesAnodic Oxide Films and Nanostructures

Topological Insulator Bi2Se3 Nanowire Field Effect Transistors

Hao Zhu、Erhai Zhao、Curt A. Richter 等 4 位作者2014-08-13ECS Transactions

Topological insulator is characterized as a new class of materials which have an insulating band gap in the bulk and gapless surface state which is protected by its intrinsic time-reversal symmetry. Here, we report high-performance topological insulator nanowire field effect transistors (FETs) with sharp turn-on, clea…

Graphene research and applicationsDiamond and Carbon-based Materials ResearchTopological Materials and Phenomena

The use of multivariate statistics to resolve multiple contamination signals in the oxygen isotope analysis of biogenic silica

Katy E. Wilson、Melanie J. Leng、Anson W. Mackay2014-08-13Journal of Quaternary Science

ABSTRACT Analysis of the oxygen isotope composition (δ18O) of diatom silica is a commonly used tool for palaeoclimate reconstruction that recent studies have demonstrated may be complicated by the presence of non‐diatom detrital material. Such contamination can mask any true climate‐driven signal, leading to spurious…

Geology and Paleoclimatology ResearchPaleontology and Stratigraphy of FossilsDiatoms and Algae Research

Self Assembled Metamaterials Formed via Plasma Enhanced ALD of Ag Thin Films

S. M. Prokes、O. J. Glembocki2014-08-13ECS Transactions

We have investigated the novel optical behavior of Ag metal deposited via plasma enhanced atomic layer deposition (PEALD). This material exhibits unexpected plasmonic properties and the plasmonic enhancement is dependent on the unique microstructure of the Ag film. Electromagnetic field simulations indicate that this…

Plasmonic and Surface Plasmon ResearchPhotonic and Optical DevicesOptical Coatings and Gratings