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Statistically quantified measurement of an Alzheimer's marker by surface‐enhanced Raman scattering

Ričardas Buividas、Nerijus Dzingelevičius、Reda Kubiliūtė 等 7 位作者2014-08-13Journal of Biophotonics

Fibrillar forms of the Amyloid‐β (Aβ) protein have been implicated in the early stages of Alzheimer's disease (AD), however there are no standardised assays for soluble Aβ oligomer biomarkers that provide the best indication of the disease progression [1,2]. As a step towards a fast and label‐free method for testing d…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy Techniques in Biomedical and Chemical ResearchBee Products Chemical Analysis

Abraham model correlations for solute transfer into tributyl phosphate from both water and the gas phase

Michela Brumfield、Akash Wadawadigi、Napasorn Kuprasertkul 等 6 位作者2014-08-13Physics and Chemistry of Liquids

Solubilities are reported for acenaphthene, fluoranthene, benzil, 9-fluorenone, trans-stilbene, phenothiazine, 2-methylbenzoic acid, 3-methylbenzoic acid, 4-chlorobenzoic acid, 3-nitrobenzoic acid, 4-nitrobenzoic acid, 3,4-dichlorobenzoic acid, 3,5-dinitrobenzoic acid, 2-chloro-5-nitrobenzoic acid, and 4-chloro-3-nitr…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesChemical Thermodynamics and Molecular Structure

Unprecedented dinuclear Robson type macrocyclic complexes having two + iii metal ions in two compartments and the role of the diimino moiety on the stability of metal ion oxidation states

Leena Mandal、Sasankasekhar Mohanta2014-08-13Dalton Transactions

The work in this investigation deals with the syntheses, characterization, crystal structures and catechol oxidase activity of four diphenoxo-bridged Co(III)Co(III) compounds of composition [Co(III)Co(III)L(Me-pn)(N3)4]·6H2O (), [Co(III)Co(III)L(Me-pn)(N3)4]·4H2O (), [Co(III)Co(III)L(Et-pn)(N3)4]·3.5H2O () and [Co(III…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

On the formation of the porous structure in nanostructured a-Si coatings deposited by dc magnetron sputtering at oblique angles

Vanda Godinho、Pavel Moskovkin、Rafael Álvarez 等 10 位作者2014-08-13Nanotechnology

The formation of the porous structure in dc magnetron sputtered amorphous silicon thin films at low temperatures is studied when using helium and/or argon as the processing gas. In each case, a-Si thin films were simultaneously grown at two different locations in the reactor which led to the assembly of different poro…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceIon-surface interactions and analysis

Red/blue spectral shifts of laser-induced fluorescence emission due to different nanoparticle suspensions in various dye solutions

Ali Bavali、Parviz Parvin、Seyedeh Zahra Mortazavi 等 5 位作者2014-08-13Applied Optics

Red/blue shifts of laser-induced fluorescence (LIF) are investigated using several guest dielectric nanoscatterers, such as TiO2, ZnO, Al2O3, and SiO2, in the host Rd6G, RdB, Coumarin 4, and Coumarin 7 ethanolic solutions. A couple of inflection points are identified varying nanoparticle (NP) density into dye solution…

Gold and Silver Nanoparticles Synthesis and ApplicationsPhotochemistry and Electron Transfer StudiesRandom lasers and scattering media

Thermal Stability of an Interface-Stabilized Skyrmion Lattice

A. Sonntag、Jan Hermenau、S. Krause 等 4 位作者2014-08-13Physical Review Letters

The thermal stability of the magnetic nano-skyrmion lattice in the monolayer Fe/Ir(111) is investigated using temperature dependent spin-polarized scanning tunneling microscopy. Our experiments show that the skyrmion lattice disappears at a temperature of T_{c}=27.8 K, indicating a loss of long-range magnetic order. A…

Magnetic properties of thin filmsTheoretical and Computational PhysicsNanoporous metals and alloys

Effects of palladium on the optical and hydrogen sensing characteristics of Pd-doped ZnO nanoparticles

Anh-Thu Thi、Hong Thai Giang、Thu Phuong Tran Thi 等 5 位作者2014-08-13Beilstein Journal of Nanotechnology

The effect of palladium doping of zinc oxide nanoparticles on the photoluminescence (PL) properties and hydrogen sensing characteristics of gas sensors is investigated. The PL intensity shows that the carrier dynamics coincides with the buildup of the Pd-related green emission. The comparison between the deep level em…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Enhanced CO2 capture in Fe3O4-graphene nanocomposite by physicochemical adsorption

Ashok Kumar Mishra、Sundara Ramaprabhu2014-08-13Journal of Applied Physics

Cost effective and efficient methods for CO2 capture are the need of the hour to render the clean environment in the era of rising energy demand. Here, we report the physicochemical adsorption of carbon dioxide (CO2) in iron oxide decorated graphene nanocomposite at elevated pressures and temperatures. Nanocomposite w…

Graphene research and applicationsCarbon Dioxide Capture TechnologiesMembrane Separation and Gas Transport

Continuous and Scalable Fabrication of Bioinspired Dry Adhesives via a Roll-to-Roll Process with Modulated Ultraviolet-Curable Resin

Hoon Yi、Insol Hwang、Jeong Hyeon Lee 等 11 位作者2014-08-13ACS Applied Materials & Interfaces

A simple yet scalable strategy for fabricating dry adhesives with mushroom-shaped micropillars is achieved by a combination of the roll-to-roll process and modulated UV-curable elastic poly(urethane acrylate) (e-PUA) resin. The e-PUA combines the major benefits of commercial PUA and poly(dimethylsiloxane) (PDMS). It n…

Surface Modification and SuperhydrophobicityAdhesion, Friction, and Surface InteractionsNanofabrication and Lithography Techniques

Dielectric and Terahertz Spectroscopy of Polarizable and Nonpolarizable Water Models: A Comparative Study

Marcello Sega、Christian Schröder2014-08-13The Journal of Physical Chemistry A

Using extensive classical molecular dynamics simulations, we compute the dielectric and far-infrared spectra of nine popular water models, including polarizable and nonpolarizable ones. We analyze the dielectric spectra using a two-relaxation model that allows one to extract the characteristic time of both the main di…

Advanced Chemical Physics StudiesSpectroscopy and Quantum Chemical StudiesSolid-state spectroscopy and crystallography

Oxidative Dehydrogenation of Ethane on Dynamically Rearranging Supported Chloride Catalysts

Christian Gärtner、A.C. van Veen、Johannes A. Lercher2014-08-13Journal of the American Chemical Society

Ethane is oxidatively dehydrogenated with a selectivity up to 95% on catalysts comprising a mixed molten alkali chloride supported on a mildly redox-active Dy2O3-doped MgO. The reactive oxyanionic OCl(-) species acting as active sites are catalytically formed by oxidation of Cl(-) at the MgO surface. Under reaction co…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisCatalysis and Oxidation Reactions

Spectroscopy and dynamics of unoccupied electronic states of the topological insulators Sb2Te3 and Sb2Te2S

J. Reimann、J. Güdde、Kenta Kuroda 等 5 位作者2014-08-13Physical Review B

Time- and angle-resolved two-photon photoemission (2PPE) was used to study the electronic structure and ultrafast electron dynamics of the $p$-doped topological insulator ${\mathrm{Sb}}_{2}{\mathrm{Te}}_{3}$ and its derivative ${\mathrm{Sb}}_{2}{\mathrm{Te}}_{2}\mathrm{S}$. Our 2PPE experiments directly reveal that th…

Graphene research and applications2D Materials and ApplicationsTopological Materials and Phenomena

New Magnesium-ion Conductive Electrolyte Solution Based on Triglyme for Reversible Magnesium Metal Deposition and Dissolution at Ambient Temperature

Tomokazu Fukutsuka、Keisuke Asaka、Akane Inoo 等 8 位作者2014-08-13Chemistry Letters

Abstract New electrolyte solutions for rechargeable magnesium metal batteries were studied. The electrolyte solution composed of triethylene glycol dimethyl ether (triglyme) and butyl methyl triglyme as solvents and magnesium(II) bis(trifluoromethanesulfonyl)amide as a magnesium salt. The reversible deposition and dis…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Double Perovskite Heterostructures: Magnetism, Chern Bands, and Chern Insulators

Ashley M. Cook、Arun Paramekanti2014-08-13Physical Review Letters

Experiments demonstrating the controlled growth of oxide heterostructures have raised the prospect of realizing topologically nontrivial states of correlated electrons in low dimensions. Here, we study heterostructures consisting of {111} bilayers of double perovskites separated by inert band insulators. In bulk, thes…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

A Comprehensive Reference Transcriptome Resource for the Common House Spider Parasteatoda tepidariorum

Nico Posnien、Victor Zeng、Evelyn E. Schwager 等 10 位作者2014-08-13PLoS ONE

Parasteatoda tepidariorum is an increasingly popular model for the study of spider development and the evolution of development more broadly. However, fully understanding the regulation and evolution of P. tepidariorum development in comparison to other animals requires a genomic perspective. Although research on P. t…

Genomics and Phylogenetic StudiesSilk-based biomaterials and applicationsSpider Taxonomy and Behavior Studies

Novel g-C 3 N 4 /BiIO 4 heterojunction photocatalysts: synthesis, characterization and enhanced visible-light-responsive photocatalytic activity

Na Tian、Hongwei Huang、Ying He 等 5 位作者2014-08-13RSC Advances

The g-C3N4/BiIO4 composite photocatalysts were successfully synthesized using a simple-mixed-calcinations method, and their photocatalytic activities for degradation of rhodamine B (RhB) under visible-light (λ > 420 nm) were investigated for the first time. The crystal structure and optical property of the as-synthesi…

Advanced Photocatalysis TechniquesPerovskite Materials and ApplicationsCovalent Organic Framework Applications

A short peptide from frog skin accelerates diabetic wound healing

Han Liu、Zilei Duan、Jing Tang 等 6 位作者2014-08-13FEBS Journal

Delayed wound healing will result in the development of chronic wounds in some diseases, such as diabetes. Amphibian skins possess excellent wound-healing ability and represent a resource for prospective wound-healing promoting compounds. A potential wound-healing promoting peptide (CW49; amino acid sequence APFRMGICT…

Wound Healing and TreatmentsAntimicrobial Peptides and ActivitiesSilk-based biomaterials and applications

Electronic Structure and Photoelectrochemical Properties of an Ir-Doped SrTiO 3 Photocatalyst

Seiji Kawasaki、Ryota Takahashi、Kazuto Akagi 等 10 位作者2014-08-13The Journal of Physical Chemistry C

The effect of iridium valence in Ir:SrTiO 3 on the electronic structure and the photocatalytic activity in a water splitting reaction was studied. Epitaxial thin film photoelectrodes were grown with controlled Ir valence and used to measure the electrochemical efficiency of Ir:SrTiO 3 . The positions of the in-gap Ir…

Advanced Photocatalysis TechniquesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Boron- and Phosphorus-Hyperdoped Silicon Nanocrystals

Shu Zhou、Xiaodong Pi、Zhenyi Ni 等 8 位作者2014-08-13Particle & Particle Systems Characterization

Hyperdoping silicon nanocrystals (Si NCs) to a concentration exceeding the solubility limit of a dopant may enable their novel applications. Here, the successful hyperdoping of Si NCs with boron (B) and phosphorus (P) is demonstrated, which are the most important dopants for Si. Despite the hyperdoping, the diamond st…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchSilicon Nanostructures and Photoluminescence

Label-Free Cysteamine-Capped Silver Nanoparticle-Based Colorimetric Assay for Hg(II) Detection in Water with Subnanomolar Exactitude

Yudhajit Bhattacharjee、A. Chakraborty2014-08-13ACS Sustainable Chemistry & Engineering

Precisely probing heavy metal pollutants in water warrants novel methods and materials. To this end, functionalization of nanoparticles using biologically important substances through a green route is a novel aspect in the design of an optical sensor. In this article we report a green preparative strategy for the synt…

Molecular Sensors and Ion DetectionNanocluster Synthesis and ApplicationsBiomedical Research and Pathophysiology