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Facile synthesis 3D flexible core-shell graphene/glass fiber via chemical vapor deposition

Cheng Yang、Yuanyuan Xu、Chao Zhang 等 8 位作者2014-08-13Nanoscale Research Letters

Direct deposition of graphene layers on the flexible glass fiber surface to form the three-dimensional (3D) core-shell structures is offered using a two-heating reactor chemical vapor deposition system. The two-heating reactor is utilized to offer sufficient, well-proportioned floating C atoms and provide a facile way…

Carbon Nanotubes in CompositesGraphene research and applicationsGraphene and Nanomaterials Applications

ASC, a Bioactive Steroidal Saponin from Ophitopogin japonicas, Inhibits Angiogenesis through Interruption of Src Tyrosine Kinase‐dependent Matrix Metalloproteinase Pathway

Ke‐Wu Zeng、Fangjiao Song、Ning Li 等 6 位作者2014-08-13Basic & Clinical Pharmacology & Toxicology

As angiogenesis is an important target for antitumour drugs, the agents that inhibit angiogenesis may help reduce the use of chemotherapy by blocking tumour blood supply. In this study, we investigated a potent angiogenesis inhibitor, ASC, a steroidal saponin compound, which has been purified from Ophitopogin japonicu…

Natural product bioactivities and synthesisPhytochemical Studies and BioactivitiesPhytochemistry and Bioactive Compounds

Rayleigh Instability Driven Nodular Cu2O Nanowires via Carbothermal Reduction of CuO Nanowires

Fei Wu、Yoon Myung、Parag Banerjee2014-08-13Crystal Growth & Design

Nodular cuprous oxide (Cu 2 O) vertical nanowire (NW) arrays with a length of more than 20 μm and diameter of ∼300 nm have been synthesized by the carbothermal reduction of thermally grown cupric oxide (CuO) NWs. The transformation initiates at a low temperature of 350 °C. Two important effects are observed: First, th…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Temperature effect on colloidal PbSe quantum dot-filled liquid-core optical fiber

Hua Wu、Yù Zhang、Long Yan 等 10 位作者2014-08-13Optical Materials Express

The optical property variation induced by temperature change for PbSe quantum dot (QD)-filled hollow core fiber was investigated as a function of particle size, waveguide length, and doping concentration. The temperature coefficients of emission peak and intensity in QD-filled fiber were obviously size-dependent. The…

Photonic and Optical DevicesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Viscous Friction between Crystalline and Amorphous Phase of Dragline Silk

Sandeep P. Patil、Senbo Xiao、Konstantinos Gkagkas 等 5 位作者2014-08-13PLoS ONE

The hierarchical structure of spider dragline silk is composed of two major constituents, the amorphous phase and crystalline units, and its mechanical response has been attributed to these prime constituents. Silk mechanics, however, might also be influenced by the resistance against sliding of these two phases relat…

Adhesion, Friction, and Surface InteractionsSilk-based biomaterials and applicationsBiochemical and Structural Characterization

Modeling Nanoscale Inhomogeneities for Quantitative HAADF STEM Imaging

Richard Aveyard、Riccardo Ferrando、Roy L. Johnston 等 4 位作者2014-08-13Physical Review Letters

High-angle annular dark-field scanning transmission electron microscopy in conjunction with image simulation is an important tool to determine the structure of nanomaterials. We show that molecular dynamics calculations can be combined with multislice image simulations to account for the large effects of surface-enhan…

Advanced Electron Microscopy Techniques and ApplicationsMachine Learning in Materials ScienceElectron and X-Ray Spectroscopy Techniques

In vitrodynamic degradation behavior of new magnesium alloy for orthopedic applications

G. Yang、Yu-Chan Kim、Hyung‐Seop Han 等 6 位作者2014-08-13Journal of Biomedical Materials Research Part B Applied Biomaterials

We report on methodologies for use in the design of a biodegradable Mg alloy appropriate for load-bearing but temporary orthopedic implant applications. Comparative studies of Mg-5Ca and Mg-5Ca-1Zn were conducted to explore the effects of a combination of minor alloying and hot extrusion, on the alloy's mechanical pro…

Magnesium Alloys: Properties and ApplicationsAluminum Alloys Composites PropertiesHydrogen Storage and Materials

Molecular sensing using armchair graphene nanoribbon

M. Reza Rezapour、Arunkumar Chitteth Rajan、Kwang S. Kim2014-08-13Journal of Computational Chemistry

In molecular electronics, the conductance strongly depends on the frontier energy levels and spatial orientations of molecules. Utilizing these features, we investigate the electron transport characteristics of conjugated molecules attached on an armchair graphene nanoribbon. The resulting sharp reduction in the trans…

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures

End-to-End Alignment of Gold Nanorods on Topographically Enhanced, Cylinder Forming Diblock Copolymer Templates and Their Surface Enhanced Raman Scattering Properties

Qianqian Tong、Edward Malachosky、Jonathan G. Raybin 等 5 位作者2014-08-13The Journal of Physical Chemistry C

We present a facile methodology for the end-to-end assembly of gold nanorods of various aspect ratios on corrugated, horizontal, cylinder-forming diblock copolymer templates. Although the depth of corrugation is significantly smaller than the diameter of the nanorods, they exhibit excellent selectivity (>98%) and alig…

Gold and Silver Nanoparticles Synthesis and ApplicationsBlock Copolymer Self-AssemblyPickering emulsions and particle stabilization

Autonomic Healing of Acrylic Bone Cement

A. Sydney Gladman、Asha‐Dee N. Celestine、Nancy R. Sottos 等 4 位作者2014-08-13Advanced Healthcare Materials

Self-healing in orthopedic bone cement is demonstrated with a novel thermoplastic solvent-bonding approach. Low toxicity solvent-filled microcapsules, embedded in a commercial acrylic bone cement matrix, enable recovery of up to 80% of the virgin fracture toughness of the cement at room and body temperature conditions…

Bone Tissue Engineering MaterialsPolymer composites and self-healingSynthetic Organic Chemistry Methods

Magnetic Circular Dichroism of Porphyrin Lanthanide M3+ Complexes

Valery Andrushchenko、Daniele Padula、E. N. Zhivotova 等 5 位作者2014-08-13Chirality

Lanthanide complexes exhibit interesting spectroscopic properties yielding many applications as imaging probes, natural chirality amplifiers, and therapeutic agents. However, many properties are not fully understood yet. Therefore, we applied magnetic circular dichroism (MCD) spectroscopy, which provides enhanced info…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMolecular spectroscopy and chirality

Phosphorus-containing polymers from tetrakis-(hydroxymethyl)phosphonium sulfate iii . A new hydrolysis-resistant tris(allyloxymethyl)phosphine oxide and its thiol-ene reaction under ultraviolet irradiation

Zhi‐Wei Tan、Chengyan Wu、Min Zhang 等 6 位作者2014-08-13RSC Advances

Two kinds of new phosphorus-containing crosslinked polymer materials were prepared via thiol-ene photopolymerization and their properties were studied. In order to prepare these crosslinked polymer materials, multifunctional monomer tris(allyloxymethyl)phosphine oxide (TAOPO) was synthesized from an eco-friendly raw m…

biodegradable polymer synthesis and propertiesSynthetic Organic Chemistry MethodsSynthesis and properties of polymers

Cellulose Nanocrystals Obtained from Cynara Cardunculus and Their Application in the Paper Industry

Valentina Coccia、Franco Cotana、Gianluca Cavalaglio 等 5 位作者2014-08-13Sustainability

Biorefinery aims at designing new virtuous and high-efficiency energy chains, achieving the combined production of biofuels (e.g., bioethanol) and biobased products. This emerging philosophy can represent an important opportunity for the industrial world, exploiting a new kind of nano-smart biomaterials in their produ…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesPolysaccharides and Plant Cell Walls

Verwey transition in single magnetite nanoparticles

Qian Yu、Alireza Mottaghizadeh、H. Wang 等 8 位作者2014-08-13Physical Review B

We present a tunnel spectroscopy study of the electronic spectrum of single magnetite ${\mathrm{Fe}}_{3}{\mathrm{O}}_{4}$ nanoparticles trapped between nanometer-spaced electrodes. The Verwey transition is clearly identified in the current-voltage characteristics where we find that the transition temperature is electr…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesIron oxide chemistry and applications

Solvent-free synthesis, coating and morphogenesis of conductive polymer materials through spontaneous generation of activated monomers

Ryo Muramatsu、Yuya Oaki、Kento Kuwabara 等 5 位作者2014-08-13Chemical Communications

Synthesis, coating, and morphogenesis of conductive polymers were achieved on a variety of substrates through spontaneous generation of activated monomer vapors under ambient pressure and low temperature conditions. The present approach facilitates the generation of complex hierarchical morphologies and the conductive…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsPolymer Surface Interaction Studies

Electrospun P34HB fibres: a scaffold for tissue engineering

Na Fu、Shuwen Deng、Yao Fu 等 10 位作者2014-08-13Cell Proliferation

OBJECTIVES: Amongst the fourth generation of PHAs is bio-plasticpoly3-hydroxybutyrate4-hydroxybutyrate (P34HB); it is thus appropriate to perform novel research on its uses and applications. The main objective of this study was to determine whether electrospun P34HB fibres would accommodate viability, growth and diffe…

Mesenchymal stem cell researchbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Effect of Hydration on Physicochemical Properties of End-Capped PLGA

Susan D’Souza、Rossella Dorati、Patrick P. DeLuca2014-08-13Advances in Biomaterials

The objective of this study was to assess the physicochemical effects of hydrating a hydrophobic end-capped poly(lactide-co-glycolide) (PLGA) polymer in the liquid and vapor state. PLGA RG503 polymer was incubated at 37°C in 0.5% polyvinyl alcohol (PVA) solution and at 90% RH. Samples were withdrawn at predetermined i…

Hydrogels: synthesis, properties, applicationsbiodegradable polymer synthesis and propertiesAdvanced Drug Delivery Systems

A new approach to fabricating magnetic multilayer nanowires by modifying the ac pulse electrodeposition in a single bath

Ahmad Ramazani、Maryam Ghaffari、M. Almasi Kashi 等 5 位作者2014-08-13Journal of Physics D Applied Physics

This work focused on the development of a new single bath technique to fabricate compositionally modulated Co/Cu, CoFe/Cu and Fe/Cu multilayer nanowires in nanoporous alumina templates prepared by the hard and mild anodization methods. The approach was based on ac pulse electrodeposition, employing successive cycles o…

Nanowire Synthesis and ApplicationsSemiconductor materials and interfacesAnodic Oxide Films and Nanostructures

Plasticity of a Colloidal Polycrystal under Cyclic Shear

Elisa Tamborini、Luca Cipelletti、Laurence Ramos2014-08-13Physical Review Letters

We use confocal microscopy and time-resolved light scattering to investigate plasticity in a colloidal polycrystal, following the evolution of the network of grain boundaries as the sample is submitted to thousands of shear deformation cycles. The grain boundary motion is found to be ballistic, with a velocity distrib…

Material Dynamics and PropertiesTheoretical and Computational PhysicsForce Microscopy Techniques and Applications