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A new type of ordered mesoporous carbon/polyaniline composites prepared by a two-step nanocasting method for high performance supercapacitor applications

Zhongshen Zhang、Gang Wang、Yang Li 等 9 位作者2014-08-13Journal of Materials Chemistry A

A new type of ordered mesoporous carbon/polyaniline (OMCx/PANI) composite with a hexagonally ordered mesostructure was prepared by a two-step nanocasting method using SBA-15 as a template. This method could protect the pore structure of OMCx from being blocked by PANI, and the in situ polymerization of aniline inside…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationConducting polymers and applications

Energy Method in the Calculation Stability of Compressed Polymer Rods Considering Creep

Vladimir I Andreew、Антон Чепурненко、Batyr Yazyev2014-08-13Advanced materials research

The problem of stability of the polymer rod in creeping was solved by energy method in the form of Timoshenko and Ritz. Possible displacements of the points were given in the form of a trigonometric series with undetermined coefficients. Results obtained numerically using complex Matlab under different constraint equa…

Structural mechanics and materialsMaterial Properties and Failure MechanismsPolymer Science and Applications

Binding of nucleobases with graphene and carbon nanotube: a review of computational studies

Morteza Chehel Amirani、Tian Tang2014-08-13Journal of Biomolecular Structure and Dynamics

Functionalized carbon nanotubes (CNTs) constitute a new class of nanostructured materials that have vast applications in CNT purification and separation, biosensing, drug delivery, etc. Hybrids formed from the functionalization of CNT with biological molecules have shown interesting properties and have attracted great…

Carbon Nanotubes in CompositesGraphene research and applicationsAdvanced biosensing and bioanalysis techniques

High tensile strength fiber of poly[(R)‐3‐hydroxybutyrate‐co‐(R)‐3‐hydroxyhexanoate] processed by two‐step drawing with intermediate annealing

Taizo Kabe、Chizuru Hongo、Toshihisa Tanaka 等 6 位作者2014-08-13Journal of Applied Polymer Science

ABSTRACT High tensile strength fibers of poly[(R)‐3‐hydroxybutyrate‐co‐(R)‐3‐hydroxyhexanoate] [P(3HB‐co‐3HH)], a type of microbial polyesters, were processed by one‐step and two‐step cold‐drawn method with intermediate annealing. Thermal degradation behaviors were characterized by differential scanning calorimeter an…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsMicroplastics and Plastic Pollution

Nanoslitting of phase-separated block copolymers by solvent swelling for membranes with ultrahigh flux and sharp selectivity

Leiming Guo、Yong Wang2014-08-13Chemical Communications

Long and narrow slit-shaped pores are predicted to have enhanced permeation and selectivity. We report, for the first time, the efficient production of membranes containing densely packed slitted pores with a pore width of <15 nm from block copolymers (BCPs). Such membranes exhibit sharp selectivity and ultrahigh wate…

Membrane Separation and Gas TransportBlock Copolymer Self-AssemblyNanopore and Nanochannel Transport Studies

DNA-Mediated Fast Synthesis of Shape-Selective ZnO Nanostructures and Their Potential Applications in Catalysis and Dye-Sensitized Solar Cells

Subrata Kundu、U. Nithiyanantham2014-08-13Industrial & Engineering Chemistry Research

Shape-selective ZnO nanoparticles (NPs) with various morphologies have been synthesized within 2 min of microwave heating by the reaction of Zn(NO 3 ) 2 ·2H 2 O with NaOH in the presence of DNA. The size and shape of the materials can be tuned by controlling the molar ratio of Zn(II) salt to DNA and by altering the ot…

Advanced Photocatalysis TechniquesZnO doping and propertiesCopper-based nanomaterials and applications

Capillary‐Assisted Fabrication of Biconcave Polymeric Microlenses from Microfluidic Ternary Emulsion Droplets

Takasi Nisisako、Takuya ANDO、Takeshi Hatsuzawa2014-08-13Small

In this study, a simple capillary-based approach for producing biconcave polymeric microlenses with uniform size and shape from ternary emulsion droplets is presented. Monodisperse ternary emulsion droplets (0.6-4.0 nL) are produced which contain a photocurable segment of an acrylate monomer and two non-curable segmen…

Ocular Surface and Contact LensPickering emulsions and particle stabilizationElectrowetting and Microfluidic Technologies

Intracellularly Degradable Hydrogen‐Bonded Polymer Capsules

Kristian Kempe、Sher Leen Ng、Sylvia T. Gunawan 等 5 位作者2014-08-13Advanced Functional Materials

The assembly of low‐fouling polymer capsules with redox‐responsive behavior and intracellular degradability is reported. Thiol‐containing poly(2‐ethyl‐2‐oxazoline) (PEtOxMASH) brushes are synthesized by atom transfer radical polymerization (ATRP) of oligo(2‐ethyl‐2‐oxazoline)methacrylate and glycidyl methacrylate (GMA…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPolymer Surface Interaction Studies

Functionalized Nanoscale Micelles with Brain Targeting Ability and Intercellular Microenvironment Biosensitivity for Anti‐Intracranial Infection Applications

Kun Shao、Yu Zhang、Ning Ding 等 12 位作者2014-08-13Advanced Healthcare Materials

Due to complication factors such as blood-brain barrier (BBB), integrating high efficiency of brain target ability with specific cargo releasing into one nanocarrier seems more important. A brain targeting nanoscale system is developed using dehydroascorbic acid (DHA) as targeting moiety. DHA has high affinity with GL…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsAdenosine and Purinergic Signaling

Formation of new electric double percolation via carbon black induced co-continuous like morphology

Hao Xiu、Yan Zhou、Jia Dai 等 7 位作者2014-08-13RSC Advances

A new electric double percolation was realized via carbon black self-networking induced co-continuous like morphology (composed of disconnected PU clusters and bands) in polylactide/poly(ether)urethane (PLA/PU) blends. As a result, a simultaneous improvement in electrical conductivity and impact toughness of the blend…

Supercapacitor Materials and FabricationConducting polymers and applicationsbiodegradable polymer synthesis and properties

First-principles study of 180∘ domain walls in BaTiO3 : Mixed Bloch-Néel-Ising character

Menglei Li、Yijia Gu、Yi Wang 等 5 位作者2014-08-13Physical Review B

The ${180}^{\ensuremath{\circ}}$ ferroelectric domain walls (FDWs) have long been regarded as purely Ising type in ferroelectrics, but recent theoretical works suggested that they can also have N\'eel- and/or Bloch-like rotations. Using a combination of first-principles calculations with phase-field simulations, we st…

Ferroelectric and Piezoelectric MaterialsPerovskite Materials and ApplicationsAcoustic Wave Resonator Technologies

An ultrastable {Ag 55 Mo 6 } nanocluster with a Ag-centered multishell structure

Kun Zhou、Yun Geng、Li‐Kai Yan 等 9 位作者2014-08-13Chemical Communications

An ultrastable [Ag55(MoO4)6](43+) ({Ag55Mo6} for short) nanocluster with a Ag-centered multishell structure in compound [Ag55(MoO4)6(C≡C(t)Bu)24(CH3COO)18](OAc)·2H2O (1) has been obtained. The ultrastability of 1 was demonstrated by Mulliken population analysis. In addition, the potential wide gap semiconductor proper…

Metal-Organic Frameworks: Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Structural Characterization of a Gcn5-Related N-Acetyltransferase from Staphylococcus aureus

Parul Srivastava、Yogesh Khandokar、Crystall M. D. Swarbrick 等 8 位作者2014-08-13PLoS ONE

The Gcn5-related N-acetyltransferases (GNATs) are ubiquitously expressed in nature and perform a diverse range of cellular functions through the acetylation of small molecules and protein substrates. Using activated acetyl coenzyme A as a common acetyl donor, GNATs catalyse the transfer of an acetyl group to acceptor…

Enzyme Structure and FunctionPolyamine Metabolism and ApplicationsPeptidase Inhibition and Analysis

Thermoelectric Properties of Undoped High Purity Higher Manganese Silicides Grown by Chemical Vapor Transport

Steven N. Girard、Xi Chen、Fei Meng 等 7 位作者2014-08-13Chemistry of Materials

Semiconducting higher manganese silicides (HMS), with a nominal composition of MnSi 1.73, are particularly promising thermoelectric materials because of their elemental abundance, nontoxicity, and reported ZT of around 0.4 at 800 K for undoped samples. However, embedded MnSi impurities naturally form during the melt g…

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsSemiconductor materials and interfaces

Facet-Dependent Surface Plasmon Resonance Properties of Au-Cu2O Core-Shell Nanocubes, Octahedra, and Rhombic Dodecahedra

Shih‐Chen Hsu、Shuya Liu、Hsiang-Ju Wang 等 4 位作者2014-08-13Small

Au-Cu2 O core-shell nanocubes, octahedra, and rhombic dodecahedra display facet-dependent optical properties. Furthermore, different-sized Au-Cu2 O octahedra with 58, 65, 68, and 73 nm octahedral gold cores clearly show a transition from the shell thickness-independent gold surface plasmon resonance band for octahedra…

ZnO doping and propertiesGold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applications

Luminescent and Transparent Nanopaper Based on Rare-Earth Up-Converting Nanoparticle Grafted Nanofibrillated Cellulose Derived from Garlic Skin

Jingpeng Zhao、Zuwu Wei、Xin Feng 等 8 位作者2014-08-13ACS Applied Materials & Interfaces

Highly flexible, transparent, and luminescent nanofibrillated cellulose (NFC) nanopaper with heterogeneous network, functionalized by rare-earth up-converting luminescent nanoparticles (UCNPs), was rapidly synthesized by using a moderate pressure extrusion paper-making process. NFC was successfully prepared from garli…

Advanced Cellulose Research StudiesCarbon and Quantum Dots ApplicationsDyeing and Modifying Textile Fibers

Masticatory biomechanics in the rabbit: a multi-body dynamics analysis

Peter J. Watson、Flora Gröning、Neil Curtis 等 7 位作者2014-08-13Journal of The Royal Society Interface

Multi-body dynamics is a powerful engineering tool which is becoming increasingly popular for the simulation and analysis of skull biomechanics. This paper presents the first application of multi-body dynamics to analyse the biomechanics of the rabbit skull. A model has been constructed through the combination of manu…

Muscle Physiology and Disorders3D Printing in Biomedical ResearchSilk-based biomaterials and applications

Regenerated cellulose fibers as impact modifier in long jute fiber reinforced polypropylene composites: Effect on mechanical properties, morphology, and fiber breakage

Nalini Ranganathan、Kristiina Oksman、Sanjay K. Nayak 等 4 位作者2014-08-13Journal of Applied Polymer Science

ABSTRACT Polypropylene/jute fiber (PP‐J) composites with various concentrations of viscose fibers (VF) as impact modifiers and maleated polypropylene (MAPP) as a compatibilizer have been studied. The composite materials were manufactured using direct long fiber thermoplastic (D‐LFT) extrusion and compression molding.…

Polymer crystallization and propertiesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

Analysis of characteristics of vanadate conversion coating on the surface of magnesium alloy

Liyuan Niu、Shiuan-Ho Chang、Xian Tong 等 5 位作者2014-08-13Journal of Alloys and Compounds

The vanadate conversion coating (VCC) was formed on the surface of magnesium (Mg) alloy in vanadium phosphate solution, as well as the cathode electrophoresis and bake-curing treatments of the conversion coating proceeded. According to the addition of vanadate in the solution, the conversion coating is refined crystal…

Corrosion Behavior and InhibitionMagnesium Alloys: Properties and ApplicationsMagnesium Oxide Properties and Applications

Atomic-scale investigation of point defects and hydrogen-solute atmospheres on the edge dislocation mobility in alpha iron

M. A. Bhatia、Sébastien Groh、K.N. Solanki2014-08-13Journal of Applied Physics

In this study, we present atomistic mechanisms of 1/2 [111](11¯0) edge dislocation interactions with point defects (hydrogen and vacancies) and hydrogen solute atmospheres in body centered cubic (bcc) iron. In metals such as iron, increases in hydrogen concentration can increase dislocation mobility and/or cleavage-ty…

Fusion materials and technologiesHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties