Materials Literature
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Mn-based nanoparticles (NPs) have emerged as new class of probes for magnetic resonance imaging due to the impressive contrast ability. However, the reported Mn-based NPs possess low relaxivity and there are no immunotoxicity data regarding Mn-based NPs as contrast agents. Here, we demonstrate the ultrahigh relaxivity…
In the field of regenerative medicine there is a need for scaffolds that support large, critically‐sized tissue formation. Major limitations in reaching this goal are the delivery of oxygen and nutrients throughout the bulk of the engineered tissue as well as host tissue integration and vascularization upon implantati…
A facile and scalable co-segregation method is used to grow hexagonal boron nitride (h-BN) thin films from B- and N-containing metals. By annealing the sandwiched metal substrates in vacuum, sub-monolayer h-BN flakes, monolayer h-BN films, and multilayer h-BN thin films of varying thickness are successfully prepared.…
Abstract The aim of this work was to prepare and characterize nanocomposites containing graphene from intercalated graphite. The graphene was produced by rapid thermal expansion using expandable graphite oxide or obtained commercially. The polymer used was poly(styrene- b -butadiene- b -styrene) (SBS). The SBS was dis…
Experimental studies have demonstrated that nanoparticles can affect the rate of protein self-assembly, possibly interfering with the development of protein misfolding diseases such as Alzheimer's, Parkinson's and prion disease caused by aggregation and fibril formation of amyloid-prone proteins. We employ classical m…
Uniaxial deformations of amorphous poly(lactic acid) (PLA) films were performed at two different temperatures, 70 and 80 °C, at various draw strains. The samples deformed at 70 °C showed a strain-induced mesophase, and the structural ordering and thermal stability increased as the draw strain increased. Further anneal…
Abstract Supercapacitors are attracting intense scientific attention as they can bridge the energy‐power gap between commercial batteries and electrolytic capacitors. High‐surface area activated carbon remains the electrode material of choice for commercial systems due to the inherently lower cost relative to the more…
The aqueous calcium carbonate system is rigorously investigated with respect to ionic activity. Ideal treatment is found to be a good approximation at relevant concentrations. The data further show that bound CaCO3 species cannot be regarded as "inactive" during nucleation but rather appear to play a key role in the p…
Pure polyamide 6 (PA6) and polyamide 6/carbon nanotube (PA6/CNT) composite samples with 0.5 weight percent loading of pristine or functionalized CNTs were made using a solution mixing technique. Modification of nanotube surface as a result of chemical functionalization was confirmed through the presence of lattice def…
This paper describes the first detailed tailored-approach for the preparation of biopolymers comprising chitosan (CTS) grafted onto the backbone of epoxidized natural rubber (CTS-g-ENR). In a typical experiment, appropriate amount of CTS and AlCl 3 6H 2 O was added to a specified amount of ENR50 (ENR with about 50% ep…
In this paper, we are reporting a novel strategy for the preparation of conductive polyaniline-clay nanocomposite in Polyvinylchloride (PVC) matrix by admicellar emulsion polymerization using a low cost renewable resource based surfactant cum dopant. The highly oriented percolated network of polyaniline-clay nanocompo…
Reduced graphene oxide or graphene was dispersed in ultra high molecular weight polyethylene (UHMWPE) using two methods to prepare nanocomposite films. In pre-reduction method, graphite oxide (GO) was exfoliated and dispersed in organic solvents and reduced to graphene before polymer was added, while reduction of grap…
We show that the glass transition of a multitude of mixtures containing hydrogen bonding materials correlates strongly with the effective number of hydroxyl groups per molecule, which are available for intermolecular hydrogen bonding. This correlation is in compliance with the topological constraint theory, wherein th…
We present the statistical method as a direct extension of the mean first-passage time concept to the analysis of molecular dynamics simulation data of a phase transformation. According to the method, the mean first-passage time trajectories for the first $(i=1)$ as well as for the subsequent ($i=2$, $3$, $4$, $\ldots…
The electrostatic potential profile of a spherical soft particle is derived by solving the Poisson-Boltzmann equations on a spherical system both numerically and analytically. The soft particle is assumed to consist of an ion-permeable charged outer layer and a non-permeable charged core with constant charged density.…
Two-dimensional (2D) transition-metal dichalcogenides (TMDs) are gaining increasing attention as an alternative to graphene for their very high potential in optoelectronics applications. Here, we consider two prototypical metallic 2D TMDs, NbSe 2 and TaS 2 . Using a first-principles approach, we investigate the proper…
We have investigated the structural and electronic properties of phosphorescent planar platinum(II) complexes at the interface of Au(111) with submolecular resolution using combined scanning tunneling microscopy and spectroscopy as well as density functional theory. Our analysis shows that molecule-substrate coupling…
In this study, the morphology conversion of bimetallic NiCo2O4 nanostructures on carbon fiber cloth (CFC) was achieved via a simple hydrothermal approach with different precursor salts. As expected, the surface morphology has been successfully driven by varying the precursor. Typical NiCo2O4 nanowall-networks and poro…
The plastic component of the deformation gradient plays a central role in finite kinematic models of plasticity. However, its characterization has been the source of extended debates in the literature and many important issues still remain unresolved. Some examples are the micromechanical understanding of F=FeFp with…
Density functional theory (DFT) has been immensely successful in its ability to predict physical properties, and, in particular, structures of condensed matter systems. Here, however, we show that DFT qualitatively fails to predict the dimerized structural phase for a monatomic Co wire that is self-assembled on a vici…