Materials Literature
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Abstract Licht im Speicher : Der Einbau eines vernetzbaren photochromen Dithienylperfluorcyclopentens (DTE) in organische Leuchtdioden (OLEDs) ermöglicht die Individualisierung der Emissionsfläche, z. B. für die Anwendung in Anzeigeelementen. Das Arbeitsprinzip beruht auf dem Schalten der Injektionsbarriere für Löcher…
The relation between properties of strontium aluminate phosphor and Al/Sr ratio was investigated.A series of strontium aluminate phosphors with different Al/Sr ratios from 1.0 to 12.0 were synthesized by solid-state method.The samples were characterized by X-ray diffraction and photoluminescence spectra.The results re…
We found that the tunnel magnetoresistance ratio of fully epitaxial Co2MnGe/MgO/Co50Fe50 magnetic tunnel junctions (MTJs) increased discontinuously and significantly from 92% at room temperature (RT) (244% at 4.2 K) for Ta of 475 °C to 160% at RT (376% at 4.2 K) for Ta of 500 °C, where Ta is the temperature at which t…
The authors have investigated changes in the electronic structures of digitally controlled La0.6Sr0.4MnO3 (LSMO) layers sandwiched between SrTiO3 as a function of LSMO layer thickness in terms of hard x-ray photoemission spectroscopy (HX-PES). The HX-PES spectra show the evolution of Mn 3d derived states near the Ferm…
The materials under consideration are binary aluminium-copper alloys (10 at% to 90.3 at%Cu) produced by HF melting and RF magnetron sputtering. The resulting micro structures have been observed by standard metallographic techniques, X-ray powder diffraction, scanning electron microscopy and transmission electron micro…
In this letter, we report a method for a tunable magnetic field sensor based on the magnetoelastic coupling properties of a magnetoelastic/piezoelectric laminated composite structure. The magnetically and elastically tunable, flexural resonant mode in the bimorph FeNi36% (invar)/polyvinylidene fluoride clamped bilayer…
This report focuses on the comparison of the effects of two different halogen dopants (bromine and iodine) on the Raman spectra of “double-walled carbon nanotube (DWNT) buckypaper”. By changing the laser excitation energy, it is possible to study the effects of the dopants on different DWNTs. We observed that the Rama…
The tribological characteristics of nanotube-based nanoelectromechanical systems (NEMS) exemplified by a gigahertz oscillator are studied. Various factors that influence the tribological properties of nanotube-based NEMS are quantitatively analyzed with the use of molecular dynamics calculations of the quality factor…
Iron man or weakling? Ligand-field strengths are conveniently expressed by the empirical spectrochemical series. Although cyanide has been deeply entrenched as a strong-field ligand, a couple of recent examples cast doubt toward the position of this ligand, namely the high-spin (S = 2) states of [Cr(II)(CN)(5)](3-) an…
The effects on the luminescent properties of coating CdSe quantum dots with silica are presented. Coating increased the quantum yields from ∼10%–20% to ∼80% at a maximum. The changes in quantum yields and photoluminescence peak at wavelength were discussed in terms of the effects of surface charge. By neutralizing sur…
A highly sensitive pH capacitive sensor has been designed by confined growth of vertically aligned nanowire arrays on interdigited microelectrodes. The active surface of the device has been functionalized with an electrochemical pH transducer (polyaniline). We easily tune the device features by combining lithographic…
In this study, a hybrid system of gold nanoparticles and multiwalled carbon nanotubes (MWNTs) with a switching function was successfully realized through photocontrolled host−guest interaction based on α-cyclodextrin (α-CD) and azobenzene derivatives. First, the azobenzene derivative was covalently bonded onto the sur…
High-resolution curvature measurements have been performed in situ during aluminum thin film anodizing in sulfuric acid. A well-defined transition in the rate of internal stress-induced curvature change is shown to allow for the accurate, real-time detection of porosity initiation. The validity of this in situ diagnos…
Abstract. Variations in the chemical composition of fossil biogenic carbonates, and in particular of mollusc shells, have been used in a range of palaeoenvironmental reconstructions. It is of primary importance, therefore, to detect and understand the diagenetic processes that may modify the original chemical signatur…
Recently, the effect of π-bonding electrons conjugating to a gold surface has been predicated by first principles. In this paper, we observe surface plasmon resonance splitting due to the covalence and π-bonding electrons conjugated effect. When surfactantless Au NPs are linked on the glass substrate by sulfur, the SP…
Hydrotalcite-like, α-cobalt hydroxides intercalated with either chloride or anthraquinone-2-sulfonate (AQS2) were crystallized on self-assembled monolayers of 11-mercaptoundecanoic acid on gold as well as poly(acrylic acid) functionalized silicon substrates. These novel functional hybrid films were prepared by the dir…
CdSe/ZnS core/shell nanocrystals (NCs) are integrated into para-sexiphenyl (p-6P) based hybrid light emitting diodes, to obtain green and red emission in addition to blue emission originated from p-6P. For the active region of the devices, ultrathin layers of p-6P and NCs are deposited by hot wall epitaxy and spin cas…
A hexagonal mesoporous silica (HMS) and its postfunctionalized counterparts with propyl (P-HMS) and aminopropyl (AMP-HMS) were prepared and characterized by elemental analysis, N2 adsorption, powder x-ray diffraction, Fourier-transform infrared, and surface charge measurements. Batch experiments were further performed…
Carbon nanotubes loaded with peptides, proteins and drugs can translocate across the cell membrane. This big advantage has attracted increasing attention to design a novel delivery system using nanotubes. Polyoxometalate (POM) is a promising antitumor drug and it shows a very strong interaction with carbon nanotube su…
The dielectric relaxation behavior of the fluorite structured nanocrystalline Ce0.8Gd0.1Pr0.1O2−δ compound was studied in the temperature range of 200–550 °C. Two different types of relaxation processes were observed corresponding to (1) defect pairs such as (PrCe′–VO)• and (GdCe′–VO)• and (2) the trimers such as (PrC…