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Complete coverage of reduced graphene oxide on silicon dioxide substrates

Jingfeng Huang、Melanie Larisika、Hu Chen 等 7 位作者2014-07-31Chinese Physics B

Reduced graphene oxide (RGO) has the advantage of an aqueous and industrial-scale production route. No other approaches can rival the RGO field effect transistor platform in terms of cost (

Advancements in Battery MaterialsGraphene research and applicationsGraphene and Nanomaterials Applications

Elucidating the crystal structure of the antimalarial drug (±)-mefloquine hydrochloride: a tetragonal hydrated species

Vânia M. do Prado、Rafael Cardoso Seiceira、Altivo Pitaluga 等 7 位作者2014-07-31Journal of Applied Crystallography

Albeit widely studied, the structure of the antimalarial drug (±)-mefloquine hydrochloride is still a controversial issue. A combination of X-ray powder diffraction, theoretical calculations and Fourier transform–infrared spectroscopy is used to unambiguously determine the crystal structure of the molecule in its acti…

Crystallography and molecular interactionsCrystallization and Solubility StudiesX-ray Diffraction in Crystallography

Thermal effect of Ge 2 Sb 2 Te 5 in phase change memory device

Juntao Li、Bo Liu、Zhitang Song 等 10 位作者2014-07-31Chinese Physics B

In the fabrication of phase change random access memory (PRAM) devices, high temperature thermal processes are inevitable. We investigate the thermal stability of Ge 2 Sb 2 Te 5 (GST) which is a prototypical phase change material. After high temperature process, voids of phase change material exist at the interface be…

Liquid Crystal Research AdvancementsChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Dispersion Characteristics of AlN-Y2O3Powder Mixture by Various Dispersants in Non-aqueous Solvents

Shin Kim、Sang-Woo Bang、Injoon Hwang 等 5 位作者2014-07-31Journal of the Korean Ceramic Society

The dispersion characteristics of AlN-4.5 wt% Y 2 O 3 powder mixture by various dispersants were investigated in ethanol and methyethly-ketone (MEK) solvents. In general, the cationic polymer dispersants demonstrated superior dispersion of the powder as compared to the non-ionic ester-type dispersants or anionic phosp…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Valley selection rule in a Y-shaped zigzag graphene nanoribbon junction

Lin Zhang、Jun Wang2014-07-31Chinese Physics B

The valley valve effect was predicted in a straight zigzag graphene nanoribbon (ZGR) p/n junction. In this work, we address a possible valley selection rule in a Y-shaped ZGR junction. By modeling the system as a three-terminal device and calculating the conductance spectrum, we found that the valley valve effect coul…

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures

A Cuprate Spin Ladder Linked by a Pyridyl Ligand

Xiao Zhang、Sadafumi Nishihara、Y. Nakano 等 5 位作者2014-07-31Chemistry Letters

Abstract We succeeded in synthesizing a novel cuprate compound, [Cu2(CO3)2(bpp)2.5]·5.5H2O (1) (bpp: 1,3-bis(4-pyridyl)propane). Its structural determination reveals that 1 has a ladder-like configuration formed by the alternate stacking of two Cu2+ ions and a CO32− ion, each of which is linked by a bpp molecule. The…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesOrganic and Molecular Conductors Research

Strain-induced low-frequency relaxation in colloidal DGEBA/SiO2 suspensions

Rick Dannert、Roland Sanctuary、Matthieu Thomassey 等 6 位作者2014-07-31Rheologica Acta

Diglycidyl ether of bisphenol A (DGEBA) is widely exploited as an epoxy resin in adhesives and coatings. In this paper, it is used as an oligomer matrix for silica-filled nanocomposites. Rheological measurements show that the pure matrix obeys power-law relaxation dynamics in the vicinity of the dynamic glass transiti…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

Spectroscopic Studies on Valine-Functionalized Single-Walled Carbon Nanotubes

M. Deborah、Ajay Jawahar、T. Mathavan 等 5 位作者2014-07-31Fullerenes Nanotubes and Carbon Nanostructures

The oxidized single-walled carbon nanotubes (SWCNTs) and valine-functionalized SWCNTs were prepared and characterized by using X-ray diffraction (XRD), ultraviolet-visible (UV-Vis), Fourier transform infrared (FT-IR), electron paramagnetic resonance (EPR), scanning electron microscopy (SEM), and energy dispersive X-ra…

Carbon Nanotubes in CompositesGraphene research and applicationsConducting polymers and applications

HAADF imaging of the omega (ω) phase in a gum metal-related alloy

R.P. Sankaran、Colin Ophus、Burak Ozdol 等 6 位作者2014-07-31The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

Nanosized precipitates have been observed in a Nb-lean gum metal-related alloy, Ti–20.0Nb–0.6Ta–1.7Zr–1.1O at.% (Ti–31.9Nb–2.0Ta–2.7Zr–0.3O wt.%) using probe-corrected high-resolution scanning transmission electron microscopy with a high-angle annular dark-field detector (HAADF). This characterization yields three dis…

Hydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and PropertiesTitanium Alloys Microstructure and Properties

Norbornene Oxidation by Chiral Complexes Encapsulated in NaY Zeolite

Iwona Kuźniarska‐Biernacka、Píer Parpot、César Oliveira 等 7 位作者2014-07-31The Journal of Physical Chemistry C

The preparation of chiral metal complexes in NaY zeolite is reported. The guests, chiral metal complexes, were entrapped in the supercages of NaY zeolite (host) by a two-step process in the liquid phase: (i) inclusion of the selected transition metal (rhodium(III) and manganese(II)) by ion-exchange in the porous struc…

Mesoporous Materials and CatalysisRadioactive element chemistry and processingCovalent Organic Framework Applications

Preparation of novolac-type phenol-based activated carbon with a hierarchical pore structure and its electric double-layer capacitor performance

Dayoung Lee、Jin-Young Jung、Mi-Seon Park 等 4 位作者2014-07-31Carbon letters

A hierarchical pore structured novolac-type phenol based-activated carbon with micropores and mesopores was fabricated. Physical activation using a sacrificial silicon dioxide ( $SiO_2$ ) template and chemical activation using potassium hydroxide (KOH) were employed to prepare these materials. The morphology of the we…

Carbon Nanotubes in CompositesSupercapacitor Materials and FabricationConducting polymers and applications

Triplet states of oxygen vacancy defects in α -quartz: Center $\bf{\text{E}^{\prime\prime}_{9}}$

R. I. Mashkovtsev、Yuanming Pan2014-07-31Europhysics Letters (EPL)

The paramagnetic center in triplet state occurring in electron-irradiated, synthetic ?-quartz has been investigated by using electron paramagnetic resonance (EPR) spectroscopy. The primary spin Hamiltonian parameter matrices g, D and A (hyperfine interactions for five 29Si nuclei) have now been determined. The princip…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid-state spectroscopy and crystallography

Toughness, dynamic mechanical property, and morphology of polyvinylchloride/acrylonitrile‐styrene‐butyl acrylate blends

Liang Ren、Yu Li、Mingyao Zhang 等 5 位作者2014-07-31Journal of Vinyl and Additive Technology

Acrylonitrile‐styrene‐butyl acrylate (ASA) graft copolymers with different acrylonitrile (AN) contents, the core‐shell ratio, and tert‐dodecyl mercaptan (TDDM) amounts were synthesized by seed emulsion polymerization. Polyvinylchloride (PVC)/ASA blends were prepared by melt blending ASA graft copolymers with PVC resin…

Polymer crystallization and propertiesRecycling and Waste Management TechniquesPolymer Science and PVC

Secondary plasmon resonance in graphene nanostructures

Yang Li、Hong Zhang、Dawei Yan 等 5 位作者2014-07-31Frontiers of Physics

The plasmon characteristics of two graphene nanostructures are studied using time-dependent density functional theory (TDDFT). The absorption spectrum has two main bands, which result from π and σ + π plasmon resonances. At low energies, the Fourier transform of the induced charge density maps exhibits anomalous behav…

Graphene research and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon Research

Contact angle hysteresis and pinning at periodic defects in statics

Stanimir Iliev、Nina Pesheva、Vadim S. Nikolayev2014-07-31Physical Review E

This article deals with the theoretical prediction of the wetting hysteresis on nonideal solid surfaces in terms of the surface heterogeneity parameters. The spatially periodical chemical heterogeneity is considered. We propose precise definitions for both the advancing and the receding contact angles for the Wilhelmy…

Surface Modification and SuperhydrophobicityAdhesion, Friction, and Surface Interactionsnanoparticles nucleation surface interactions

Specular graphene transport barrier

Daniel Gunlycke、C. T. White2014-07-31Physical Review B

We present a flexible model for a generic straight transport barrier in graphene in the specular limit. The specular limit applies for scattering of carriers sufficiently close to the Fermi level in three quarters of the transport barriers. Using the Lippmann-Schwinger equation, we obtain the wave function, from which…

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures

Significance and interaction of bonding parameters with bonding ratio in press bonding of TC4 alloy

Hong Li、Miaoquan Li、Weixin Yu 等 4 位作者2014-07-31Rare Metals

Abstract The variation of bonding ratio in the press bonding of TC4 alloy at temperatures from 850 to 900 °C, pressures from 10 to 30 MPa, and time from 5 to 15 min was investigated. The bonding ratio increases with the increase of temperature, time and pressure. The maximum bonding ratio, i.e. 98 %, can be obtained a…

Titanium Alloys Microstructure and PropertiesInjection Molding Process and PropertiesEngineering Technology and Methodologies

Semiconductor activated terahertz metamaterials

Hou‐Tong Chen2014-07-31Frontiers of Optoelectronics

Metamaterials have been developed as a new class of artificial effective media realizing many exotic phenomena and unique properties not normally found in nature. Metamaterials enable functionality through structure design, facilitating applications by addressing the severe material issues in the terahertz frequency r…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchTerahertz technology and applications

Adsorption energetics of azobenzenes on noble metal surfaces

Michael Schulze、Christopher Bronner、Petra Tegeder2014-07-31Journal of Physics Condensed Matter

Temperature-programmed desorption measurements have been applied to investigate the binding energies of four systems, namely the photochromic molecular compounds azobenzene and tetra-tert-butyl-azobenzene (TBA) adsorbed on the Au(1 1 1) and Ag(1 1 1) surfaces, respectively. The binding energy is a measure of the inter…

Quantum Dots Synthesis And PropertiesMolecular Junctions and NanostructuresPhotochromic and Fluorescence Chemistry

Electromagnetic wave absorbing properties and hyperfine interactions of Fe—Cu—Nb—Si—B nanocomposites

Mangui Han、Wei Guo、Yanhui Wu 等 5 位作者2014-07-31Chinese Physics B

The Fe—Cu—Nb—Si—B alloy nanocomposite containing two ferromagnetic phases (amorphous phase and nanophase phase) is obtained by properly annealing the as-prepared alloys. High resolution transmission electron microscopy (HR-TEM) images show the coexistence of these two phases. It is found that Fe—Si nanograins are surr…

Metallic Glasses and Amorphous AlloysElectromagnetic wave absorption materialsAdvanced Antenna and Metasurface Technologies