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Simultaneous Steady-state and Dynamic 13C NMR Can Differentiate Alternative Routes of Pyruvate Metabolism in Living Cancer Cells

Chendong Yang、Crystal Harrison、Eunsook S. Jin 等 8 位作者2014-01-11Journal of Biological Chemistry

Metabolic reprogramming facilitates cancer cell growth, so quantitative metabolic flux measurements could produce useful biomarkers. However, current methods to analyze flux in vivo provide either a steady-state overview of relative activities (infusion of (13)C and analysis of extracted metabolites) or a dynamic view…

Enzyme Structure and FunctionAdvanced NMR Techniques and ApplicationsElectron Spin Resonance Studies

Mesenchymal Stem Cells: Roles and Relationships in Vascularization

Anthony J. Melchiorri、Bao‐Ngoc B. Nguyen、John P. Fisher2014-01-11Tissue Engineering Part B Reviews

One of the primary challenges in translating tissue engineering to clinical applicability is adequate, functional vascularization of tissue constructs. Vascularization is necessary for the long-term viability of implanted tissue expanded and differentiated in vitro. Such tissues may be derived from various cell source…

Mesenchymal stem cell researchElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Mimicking Isovolumic Contraction with Combined Electromechanical Stimulation Improves the Development of Engineered Cardiac Constructs

Kathy Ye Morgan、Lauren D. Black2014-01-11Tissue Engineering Part A

Electrical and mechanical stimulation have both been used extensively to improve the function of cardiac engineered tissue as each of these stimuli is present in the physical environment during normal development in vivo. However, to date, there has been no direct comparison between electrical and mechanical stimulati…

Electrospun Nanofibers in Biomedical Applications3D Printing in Biomedical ResearchTissue Engineering and Regenerative Medicine

Controlled synthesis of α- and γ-Fe2O3 nanoparticles via thermolysis of PVA gels and studies on α-Fe2O3 catalyzed styrene epoxidation

Ruhul Amin Bepari、Palash Bharali、Birinchi K. Das2014-01-11Journal of Saudi Chemical Society

Fe2O3 nanoparticles with diameters in the 7–18 nm range have been synthesized via thermolysis of polyvinyl alcohol (PVA) gels prepared under alkaline pH by adding Fe3+ ions into warm aqueous solutions of PVA. While calcinations at 400 °C, 500 °C and 600 °C give γ-Fe2O3 as the pure product, α-Fe2O3 is obtained by heati…

Nanoparticle-Based Drug DeliveryMinerals Flotation and Separation TechniquesIron oxide chemistry and applications

Fe3O4/γ-Fe2O3 Nanoparticle Multilayers Deposited by the Langmuir–Blodgett Technique for Gas Sensors Application

S. Capone、Maria Grazia Manera、A. Taurino 等 9 位作者2014-01-11Langmuir

Fe3O4/γ-Fe2O3 nanoparticles (NPs) based thin films were used as active layers in solid state resistive chemical sensors. NPs were synthesized by high temperature solution phase reaction. Sensing NP monolayers (ML) were deposited by Langmuir-Blodgett (LB) techniques onto chemoresistive transduction platforms. The sensi…

Gold and Silver Nanoparticles Synthesis and ApplicationsGas Sensing Nanomaterials and SensorsCharacterization and Applications of Magnetic Nanoparticles

Molecular structure and vibrational spectra of N‐acetylglycine oligomers and polyglycine I using DFT approach

Saba Bee、Neetu Choudhary、Archana Gupta 等 4 位作者2014-01-11Biopolymers

We have determined the geometric, vibrational, and electronic properties of N-acetylglycine oligomers by performing density functional theory quantum chemical calculations. The normal mode analysis was performed and the potential energy distribution was calculated among the internal coordinates. The optically active v…

Advanced Chemical Physics StudiesCrystallography and molecular interactionsNonlinear Optical Materials Research

Pulse Electric Current–Aided Reactive Sintering of High‐Purity Zr 3 Al 3 C 5

Jie Zhou、Fagui Qiu、Lu Shen 等 7 位作者2014-01-11Journal of the American Ceramic Society

Herein, we report on the in situ reactive synthesis and simultaneous densification of a high‐purity ternary Zr 3 Al 3 C 5 phase via pulse electric current sintering ( PECS ) of Zr / Al /graphite powder mixtures with a molar ratio of 3:3.2:4.8. The phases and microstructure evolution in the 580°C–1800°C temperature ran…

Advanced ceramic materials synthesisMXene and MAX Phase MaterialsAdvanced materials and composites

Raman Responses in Mechanically Activated BaTiO 3

Vera P. Pavlović、Vera P. Pavlovic、Maria Vesna Nikolić 等 10 位作者2014-01-11Journal of the American Ceramic Society

The structure and lattice dynamics of mechanically activated BaTiO 3 was investigated in this study. Phonon behavior and crystal structure stability of the obtained nanocrystalline BaTiO 3 were discussed from the view point of crystallite size effects and microstrains induced by mechanical activation. A systematic stu…

Ferroelectric and Piezoelectric MaterialsForce Microscopy Techniques and ApplicationsElectronic and Structural Properties of Oxides

Synthesis, electrochemical, and optical properties of low band gap homo- and copolymers based on squaraine dyes

Sebastian F. Völker、Theresa Dellermann、Harald Ceymann 等 5 位作者2014-01-11Journal of Polymer Science Part A Polymer Chemistry

A broad series of monomeric and polymeric squaraines was synthesized to investigate the impact of electron-donating bridges, such as unsaturated triarylamine, carbazole, and saturated piperazine groups, on the spectroscopic and redox properties. These bridges were attached to both standard trans-indolenine squaraines…

Organic Electronics and PhotovoltaicsLuminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic Compounds

Promoting effect of cerium on the characteristic and catalytic activity of Al, Zr, and Al–Zr pillared clay

Saida Mnasri-Ghnimi、N. Frini-Srasra2014-01-11Applied Clay Science

A series of pillared interlayered clays (PILCs) including Al-, Zr- and Al–Zr-PILC have been prepared and characterized by X-ray diffraction, elemental analyses, N2 adsorption, cationic exchange capacity and IR measurements after n-butylamine adsorption. Cerium introduced in the Zr4 + and/or Al3 + intercalated solution…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and Applications

Spectroscopic Studies of Nanopowder and Nanoceramics La 2 Hf 2 O 7 : Pr Scintillator

Joanna Trojan–Piegza、S. Gierlotka、Eugeniusz Zych 等 4 位作者2014-01-11Journal of the American Ceramic Society

Sintered nanoceramics of Pr ‐doped lanthanum hafnate, La 2 Hf 2 O 7 : Pr , were prepared by means of a high‐pressure sintering technique using nanopowders made by Pechini method. Structure, morphology, and spectroscopic properties of the ceramics compared to the starting powder are presented and discussed. Emission an…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesNuclear materials and radiation effects

Future Opportunities in Cancer Nanotechnology—NCI Strategic Workshop Report

Piotr Grodzinski、Dorothy Farrell2014-01-11Cancer Research

There has been significant progress in utilizing nanotechnology in several areas of cancer care, including in vitro diagnostics, imaging, and therapy. The National Cancer Institute, which currently supports an array of research activities in cancer nanotechnology, convened a strategic workshop to explore the most prom…

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesGraphene and Nanomaterials Applications

A Novel Approach to Improve Properties of BiFeO 3 Nanomultiferroics

G. S. Arya、R.K. Kotnala、N. S. Negi2014-01-11Journal of the American Ceramic Society

In this study we report the synthesis of Bi 1− x In x Fe 1− y Ti y O 3 (0 ≤ x ≤ 0.1, 0 ≤ y ≤ 0.05) nanoparticles by a simple cost effective solution combustion method. Pure BFO samples shows distorted rhombohedral perovskite structure with space group R 3 c which is also supported by Fourier transform infrared spectra…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Controlled Surface Chemistry of Diamond/β-SiC Composite Films for Preferential Protein Adsorption

Tao Wang、Stephan Handschuh‐Wang、Yang Yang 等 9 位作者2014-01-11Langmuir

Diamond and SiC both process extraordinary biocompatible, electronic, and chemical properties. A combination of diamond and SiC may lead to highly stable materials, e.g., for implants or biosensors with excellent sensing properties. Here we report on the controllable surface chemistry of diamond/β-SiC composite films…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Fine-tuning control on CNT diameter distribution, length and density using thermal CVD growth at atmospheric pressure: an in-depth analysis on the role of flow rate and flow duration of acetylene (C2H2) gas

Nishant Tripathi、Prabhash Mishra、Harsh Harsh 等 4 位作者2014-01-11Applied Nanoscience

An optimization control has been demonstrated to obtain carbon nanotubes having specific diameter distribution, length, homogeneity, and yield during its growth by thermal chemical vapor deposition technique under atmospheric pressure. Carbon nanotubes (CNTs) were grown on silicon wafer where a predeposition of iron c…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Morphology Control between Twisted Ribbon, Helical Ribbon, and Nanotube Self-Assemblies with His-Containing Helical Peptides in Response to pH Change

Akihiro Uesaka、Motoki Ueda、A. Makino 等 6 位作者2014-01-11Langmuir

pH-Responsive molecular assemblies with a variation in morphology ranging from a twisted ribbon, a helical ribbon, to a nanotube were prepared from a novel A3B-type amphiphilic peptide having three hydrophilic poly(sarcosine) (A block) chains, a hydrophobic helical dodecapeptide (B block), and two histidine (His) resi…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Translocator Protein Ligand–PLGA Conjugated Nanoparticles for 5-Fluorouracil Delivery to Glioma Cancer Cells

Valentino Laquintana、Nunzio Denora、Antonio Lopalco 等 8 位作者2014-01-11Molecular Pharmaceutics

Translocator protein 18 kDa (TSPO) is a promising target for molecular imaging and for targeted drug delivery to tumors overexpressing TSPO. In our previous work, new macromolecular conjugates with a high affinity and selectivity for TSPO were prepared by conjugating the biodegradable poly(d,l-lactic-co-glycolic acid)…

Nanoparticle-Based Drug DeliveryRadiopharmaceutical Chemistry and ApplicationsGraphene and Nanomaterials Applications

Functional-Friction Networks: New Insights on the Laboratory Earthquakes

H. O. Ghaffari、B. D. Thompson、R. P. Young2014-01-11arXiv

We report some new applications of functional complex networks on acoustic emission waveforms from frictional interfaces. Our results show that laboratory faults undergo a sequence of generic phases as well as strengthening, weakening or fast-slip and slow-slip leading to healing. Also, using functional networks, we e…

Materials Sciencephysics.geo-ph

Helium Ion Microscopy

Gregor Hlawacek、Vasilisa Veligura、Raoul van Gastel 等 4 位作者2014-01-11arXiv

Helium Ion Microcopy (HIM) based on Gas Field Ion Sources (GFIS) represents a new ultra high resolution microscopy and nano-fabrication technique. It is an enabling technology that not only provides imagery of conducting as well as uncoated insulating nano-structures but also allows to create these features. The latte…

Mesoscale and Nanoscale PhysicsMaterials Science

Dynamics of skyrmions in chiral magnets: dynamic phase transitions and equation of motion

Shi-Zeng Lin、Charles Reichhardt、Cristian D. Batista 等 4 位作者2014-01-11arXiv

We study the dynamics of skyrmions in a metallic chiral magnet. First we show that skyrmions can be created dynamically by destabilizing the ferromagnetic background state through a spin polarized current. We then treat skyrmions as rigid particles and derive the corresponding equation of motion. The dynamics of skyrm…

Materials ScienceStrongly Correlated Electronsnlin.PS