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Using Shape Anisotropy to Toughen Disordered Nanoparticle Assemblies

Lei Zhang、Gang Feng、Zorana Zeravcic 等 6 位作者2013-08-26ACS Nano

Assemblies of disordered nanoparticles constitute an important class of materials that have numerous applications in energy conversion and storage, electronics, photonics, and sensing. One major roadblock that limits the widespread utilization of disordered nanoparticle assemblies (DNAs) is their poor damage tolerance…

Material Dynamics and PropertiesMetallic Glasses and Amorphous AlloysIon-surface interactions and analysis

Bombarding Cancer: Biolistic Delivery of therapeutics using Porous Si Carriers

Neta Zilony、Adi Tzur-Balter、Ester Segal 等 4 位作者2013-08-26Scientific Reports

A new paradigm for an effective delivery of therapeutics into cancer cells is presented. Degradable porous silicon carriers, which are tailored to carry and release a model anti-cancer drug, are biolistically bombarded into in-vitro cancerous targets. We demonstrate the ability to launch these highly porous microparti…

Advanced biosensing and bioanalysis techniquesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Thermal stability and ablation properties study of aluminum silicate ceramic fiber and acicular wollastonite filled silicone rubber composite

Lin Yu、Shengtai Zhou、Huawei Zou 等 4 位作者2013-08-26Journal of Applied Polymer Science

ABSTRACT The thermal stability and ablation properties of silicone rubber filled with silica (SiO 2 ), aluminum silicate ceramic fiber (ASF), and acicular wollastonite (AW) were studied in this article. The morphology, composition, and ablation properties of the composite were analyzed after oxyacetylene torch tests.…

Polymer Nanocomposites and PropertiesTribology and Wear AnalysisSilicone and Siloxane Chemistry

Waveguide-Enhanced Surface Plasmons for Ultrasensitive SERS Detection

Yuejiao Gu、Shuping Xu、Haibo Li 等 7 位作者2013-08-26The Journal of Physical Chemistry Letters

We design an ultrasensitive surface-enhanced Raman scattering (SERS) substrate based on waveguide-enhanced surface plasmons (SPs). An optical waveguide was exploited to concentrate and restrict the electromagnetic (EM) energy of the incident light, and Ag nanoparticles that were assembled on the waveguide surface were…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon Research

Controllable hydrogen release via aluminum powder corrosion in calcium hydroxide solutions

Shingo Kanehira、S. Kanamori、Kohji Nagashima 等 7 位作者2013-08-26Journal of Asian Ceramic Societies

Mechanism of aluminum powder corrosion in calcium hydroxide solutions was investigated via various analyses of residues after its hydrolysis reaction and pH change of the solutions to control the release of hydrogen gas. It was revealed that the reaction with a release of hydrogen gas consisted of katoite formation an…

Advanced ceramic materials synthesisCorrosion Behavior and InhibitionMagnesium Oxide Properties and Applications

Detection of Antiferromagnetic Ordering in Heavily DopedLaFeAsO1−xHxPnictide Superconductors Using Nuclear-Magnetic-Resonance Techniques

Naoki Fujiwara、S. Tsutsumi、Soshi Iimura 等 7 位作者2013-08-26Physical Review Letters

We studied double superconducting (SC) domes in LaFeAsO(1-x)H(x) by using 75As and 1H nuclear-magnetic-resonance techniques and unexpectedly discovered that a new antiferromagnetic (AF) phase follows the double SC domes on further H doping, forming a symmetric alignment of AF and SC phases in the electronic phase diag…

Corporate Taxation and AvoidanceIron-based superconductors research

Electrospun Poly(L-lactide)/Poly(ε-caprolactone) Blend Nanofibrous Scaffold: Characterization and Biocompatibility with Human Adipose-Derived Stem Cells

Liang Chen、Yi Bai、Guiying Liao 等 8 位作者2013-08-26PLoS ONE

The essence of tissue engineering is the fabrication of autologous cells or induced stem cells in naturally derived or synthetic scaffolds to form specific tissues. Polymer is thought as an appealing source of cell-seeded scaffold owing to the diversity of its physicochemical property and can be electrospun into nano-…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Autophagy‐Sensitized Cytotoxicity of Quantum Dots in PC12 Cells

Xiaoming Li、Nan Chen、Yuanyuan Su 等 10 位作者2013-08-26Advanced Healthcare Materials

Both CdTe and CdTe/CdS/ZnS quantum dots induce similar levels of autophagy in PC12 and HEK293 cells, while the former exhibits higher toxicity. Low levels of cadmium ions are not sufficient to induce either autophagy or cytotoxicity by themselves. Interestingly, the combination of cadmium ions and CdTe/CdS/ZnS mimics…

Nanoparticles: synthesis and applicationsAdvanced biosensing and bioanalysis techniquesCarbon and Quantum Dots Applications

Silaffins of Diatoms: From Applied Biotechnology to Biomedicine

I. E. Pamirsky、Kirill S. Golokhvast2013-08-26Marine Drugs

Silaffins are involved in the formation of the cell walls of diatoms. It is known that silaffins can precipitate silica in vitro, forming nano- and micro-particles in the shape of spheres and plates containing many pores. It is important to note that the deposition of silica and the particle morphology in the presence…

Calcium Carbonate Crystallization and InhibitionProtist diversity and phylogenyDiatoms and Algae Research

Phonons in two-dimensional soft colloidal crystals

Ke Chen、Tim Still、Samuel S. Schoenholz 等 8 位作者2013-08-26Physical Review E

The vibrational modes of pristine and polycrystalline monolayer colloidal crystals composed of thermosensitive microgel particles are measured using video microscopy and covariance matrix analysis. At low frequencies, the Debye relation for two-dimensional harmonic crystals is observed in both crystal types; at higher…

Material Dynamics and PropertiesForce Microscopy Techniques and ApplicationsSpectroscopy and Quantum Chemical Studies

Nanostructured Hollow Tubes Based on Chitosan and Alginate Multilayers

Joana M. Silva、Ana Rita C. Duarte、Catarina A. Custódio 等 9 位作者2013-08-26Advanced Healthcare Materials

The design and production of structures with nanometer-sized polymer films based on layer-by-layer (LbL) are of particular interest for tissue engineering since they allow the precise control of physical and biochemical cues of implantable devices. In this work, a method is developed for the preparation of nanostructu…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Three New Mixed-Alkali- and Alkaline-Earth-Metal Borates: From 1D Chain to 2D Layer to 3D Framework

Han‐Qing Wu、Ping Ju、Huan He 等 5 位作者2013-08-26Inorganic Chemistry

Three new mixed-metal borates, K4Ba2[B14O20(OH)10]·3H2O (1), LiSr2[B10O16(OH)3] (2), and LiBa[B9O15] (3), have been made under hydro(solvo)thermal conditions and characterized by means of IR, UV-vis-near-IR, thermogravimetric analysis, powder X-ray diffraction, and single-crystal X-ray diffraction, respectively. 1 is…

Metal-Organic Frameworks: Synthesis and ApplicationsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Pulverized polyurethane foam particles reinforced rigid polyurethane foam and phenolic foam

Chao Yang、Zhe‐Hui Zhuang、Zhen‐Guo Yang2013-08-26Journal of Applied Polymer Science

ABSTRACT Polyurethane consumption has been increasing in recent years, raising concerns about how to deal with the polymer waste. Post‐consumer rigid polyurethane foams or polyurethane foam scraps (PPU) ground into particles were utilized to strengthen mechanical properties of rigid polyurethane foam (PUF) and phenoli…

Polymer composites and self-healingFlame retardant materials and propertiesPolymer Foaming and Composites

Molecular-like Ag clusters sensitized near-infrared down-conversion luminescence in oxyfluoride glasses for broadband spectral modification

Hang Lin、Daqin Chen、Yunlong Yu 等 5 位作者2013-08-26Applied Physics Letters

Molecular-like Ag clusters sized at 1–4 nm have been stabilized in Pb/Cd-free oxyfluoride glasses, showing broadband excitation/emission characteristics and unique wavelength-dependent luminescent performance with a maximal quantum yield of 26.9%. It was experimentally demonstrated that an energy transfer route of Ag…

Luminescence Properties of Advanced MaterialsLanthanide and Transition Metal ComplexesNanocluster Synthesis and Applications

Marinite Li2M(SO4)2 (M = Co, Fe, Mn) and Li1Fe(SO4)2: Model Compounds for Super-Super-Exchange Magnetic Interactions

Marine Reynaud、Gwenaëlle Rousse、Jean‐Noël Chotard 等 5 位作者2013-08-26Inorganic Chemistry

New materials initially designed for battery electrodes are often of interest for magnetic study, because their chemical compositions include 3d transition metals. We report here on the magnetic properties of marinite phases Li2M(SO4)2 (M = Fe, Co, Mn) and Li1Fe(SO4)2, which all order antiferromagnetically at low temp…

Magnetic and transport properties of perovskites and related materialsCrystal Structures and PropertiesAdvanced Condensed Matter Physics

Tuning the redox activity of encapsulated metal clusters via the metallic and semiconducting character of carbon nanotubes

Fan Zhang、Xiulian Pan、Yongfeng Hu 等 13 位作者2013-08-26Proceedings of the National Academy of Sciences

We demonstrate that reactions confined within single-walled carbon nanotube (SWCNT) channels are modulated by the metallic and semiconducting character of the hosts. In situ Raman and X-ray absorption near-edge structure spectroscopies provide complementary information about the electronic state of carbon nanotubes an…

Advancements in Battery MaterialsCarbon Nanotubes in CompositesGraphene research and applications

Morphological Control of Helical Structures of an ABC-Type Triblock Terpolymer by Distribution Control of a Blending Homopolymer in a Block Copolymer Microdomain

Takeshi Higuchi、Hidekazu Sugimori、Xi Jiang 等 9 位作者2013-08-26Macromolecules

The control of microphase-separated structures in a poly(styrene- block -butadiene- block -methyl methacrylate) (SBM) was investigated in three dimensions by transmission electron microtomography. Neat SBM self-assembled into a double-helical structure of polybutadiene (PB) domains around hexagonally packed core polys…

Advanced Polymer Synthesis and CharacterizationBlock Copolymer Self-AssemblyMachine Learning in Materials Science

CuO/Graphene Nanohybrids: Preparation and Enhancement on Thermal Stability and Smoke Suppression of Polypropylene

Yongqian Shi、Xiaodong Qian、Keqing Zhou 等 10 位作者2013-08-26Industrial & Engineering Chemistry Research

Cu/graphene nanohybrids were successfully prepared using a simultaneous chemical reduction method. Successful oxidation of Cu nanoparticles was carried out by the melt blending during preparation of the nanocomposites. Cu nanoparticles were well dispersed on graphene with a diameter of 3–7 nm. XRD and TGA results reve…

Graphene research and applicationsNatural Fiber Reinforced CompositesFlame retardant materials and properties

3d-4f spin interaction induced giant magnetocaloric effect in zircon-type DyCrO4 and HoCrO4 compounds

A. Midya、N. Khan、Dilip Bhoi 等 4 位作者2013-08-26Applied Physics Letters

We have investigated the influence of 3d-4f spin interaction on magnetic and magnetocaloric properties of DyCrO4 and HoCrO4 compounds by magnetization and heat capacity measurements. Both the compounds exhibit complicated magnetic properties and huge magnetic entropy change around the ferromagnetic transition due to t…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Device Performance of Heterojunction Tunneling Field-Effect Transistors Based on Transition Metal Dichalcogenide Monolayer

Kai‐Tak Lam、Xi Cao、Jing Guo2013-08-26IEEE Electron Device Letters

The ballistic device performances of monolayer transition metal dichalcogenide (MX2) tunneling field-effect transistors (TFETs) and the drive current enhancement via heterojunction are investigated in this letter via the nonequilibrium Green's function formulism. The ultrathin 2-D body and the direct and designable ba…

2D Materials and ApplicationsAdvancements in Semiconductor Devices and Circuit DesignFerroelectric and Negative Capacitance Devices