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Structural characterization, thermal properties, and density functional theory studies of PMMA‐maghemite hybrid material

Marcus V. J. Rocha、Hudson Wallace Pereira de Carvalho、Víctor Hugo Vitorino Sarmento 等 5 位作者2014-07-23Polymer Composites

Maghemite (γ‐Fe2O3)‐poly(methyl methacrylate) (PMMA) nanocomposites were prepared by grafting 3‐(trimethoxy‐silyl) propyl methacrylate on the surface of maghemite nanoparticles, this process being followed by methyl methacrylate radical polymerization. Three different hybrids with 0.1, 0.5, and 2.5 wt% of maghemite na…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Science and PVC

Flow Cytometric Analysis of the Physical and Protein-Binding Characteristics of Solid Drug Nanoparticle Suspensions

Neill J. Liptrott、Marco Giardiello、Joseph W Hunter 等 8 位作者2014-07-23Nanomedicine

AIM: Oral and intramuscular sustained-release antiretroviral solid drug nanoparticles (SDNs) are in development but there is limited understanding of whether nanoparticles or dissolved drug predominate systemically. MATERIALS & METHODS: A flow cytometric method was developed to analyze SDNs in biological fluids such a…

Nanoparticle-Based Drug DeliveryAdvanced Drug Delivery SystemsProtein purification and stability

Octahedral distortion induced magnetic anomalies in LaMn0.5Co0.5O3 single crystals

Kaustuv Manna、Venkata Srinu Bhadram、Suja Elizabeth 等 5 位作者2014-07-23Journal of Applied Physics

Single crystals of LaMn0.5Co0.5O3 belonging to the ferromagnetic-insulator and distorted perovskite class were grown using a four-mirror optical float zone furnace. The as-grown crystal crystallizes into an orthorhombic Pbnm structure. The spatially resolved 2D Raman scan reveals a strain-induced distribution of trans…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Crosslinking Liposomes/Cells Using Cholesteryl Group-Modified Tilapia Gelatin

Tsunemasa Taguchi、Yoshiaki Endo2014-07-23International Journal of Molecular Sciences

Cholesteryl group-modified tilapia gelatins (Chol-T-Gltns) with various Chol contents from 3 to 69 mol % per amino group of Gltn were prepared for the assembly of liposomes and cells. Liposomes were physically crosslinked by anchoring Chol groups of Chol-T-Gltns into lipid membranes. The resulting liposome gels were e…

Nanoparticle-Based Drug DeliveryLipid Membrane Structure and BehaviorSupramolecular Self-Assembly in Materials

Polystyrene Templated Porous Titania Wells for Quantum Dot Heterojunction Solar Cells

Cheng Cheng、Michael M. Lee、Nakita K. Noel 等 8 位作者2014-07-23ACS Applied Materials & Interfaces

Polystyrene spheres are used to template TiO2 with a single layer of 300 nm wells which are infilled with PbS quantum dots to form a heterojunction solar cell. The porous well device has an efficiency of 5.7% while the simple planar junction is limited to 3.2%. Using a combination of optical absorption and photocurren…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Preparation and characterization of zinc oxide and nanoclay reinforced crosslinked starch/jute green nanocomposites

Murshid Iman、Ajay Kumar Manhar、Manabendra Mandal 等 4 位作者2014-07-23RSC Advances

In the present work, ZnO nanoparticles (ZNP) and ZNP in combination with nanoclays are reported as reinforcing agents for the preparation of ‘Green’ nanocomposites based on glutaraldehyde (GA) crosslinked starch/jute fabric. A solution-induced intercalation method has been used for the successful fabrication of the na…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Influence of montmorillonite on electrical treeing and breakdown characteristics of low-density polyethylene

Ruijin Liao、Xiao Li、Ge Bai 等 5 位作者2014-07-23Journal of Reinforced Plastics and Composites

Electrical treeing is an electrical aging phenomenon that severely threatens the operation safety of power equipment, in which polymer is used as primary insulation material. A type of low-density polyethylene-montmorillonite (LDPE/MMT) nanocomposite was prepared using melt method to study the impact of MMT nanopartic…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

Tribological behaviours of Ti 3 SiC 2 under current carrying conditions

Qiqiao Xiao、Shaoqing Wu2014-07-23Advances in Applied Ceramics Structural Functional and Bioceramics

High purity Ti3SiC2 samples were prepared by infiltration sintering method. The tribological behaviours of high pure bulk Ti3SiC2 dry sliding against a GCr15 bearing steel disc were experimentally investigated on a pin on disc type tester under different sliding speeds from 5 to 50 m s−1, different electric currents f…

Metal and Thin Film MechanicsAluminum Alloys Composites PropertiesMXene and MAX Phase Materials

Effect of layer thickness on the thermal release from Be–D co-deposited layers

M.J. Baldwin、R.P. Doerner2014-07-23Nuclear Fusion

The results of previous work (Baldwin et al 2013 J. Nucl. Mater. 438 S967–70 and Baldwin et al 2014 Nucl. Fusion 54 073005 ) are extended to explore the influence of layer thickness on the thermal D 2 release from co-deposited Be–(0.05)D layers produced at ∼323 K. Bake desorption of layers of thickness 0.2–0.7 µ m are…

Magnetic confinement fusion researchFusion materials and technologiesNuclear Materials and Properties

Through‐Space Conjugated Molecular Wire Comprising Three π‐Electron Systems

Yasuhiro Morisaki、Naoya Kawakami、Shotaro Shibata 等 4 位作者2014-07-23Chemistry - An Asian Journal

A [2.2]paracyclophane-based through-space conjugated oligomer comprising three π-electron systems was designed and synthesized. The arrangement of three π-conjugated systems in an appropriate order according to the energy band gap resulted in efficient unidirectional photoexcited energy transfer by the Förster mechani…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic Compounds

On the theory of metal nanoparticles based on quantum mechanical calculation

Elias Saion、Elham Gharibshahi2014-07-23Malaysian Journal of Fundamental and Applied Sciences

Metal nanoparticles have attracted considerable attention owing to their unusual physical and chemical properties from those of their molecular and bulkcounterparts and are fundamental to surface science applications such as catalysts, optics, photonics, sensors, and spectroscopy. Traditionally, the opticalabsorption…

Gold and Silver Nanoparticles Synthesis and Applications

Metalation of Polyamine Dendrimers with Ethynylcobalticenium for the Construction of Mono‐ and Heterobimetallic Polycationic Metallodendrimers

Yanlan Wang、Amalia Rapakousiou、Jaimé Ruiz 等 4 位作者2014-07-23Chemistry - A European Journal

The introduction of robust redox groups at the periphery of common amine-terminated dendrimers is of interest in the design of dendritic nanobatteries, sensors, and redox catalysts. Here we are applying the recently discovered uncatalyzed hydroamination of ethynylcobalticenium, a mild "green" reaction that quantitativ…

RNA Interference and Gene DeliveryDendrimers and Hyperbranched PolymersFerrocene Chemistry and Applications

Mechanical reinforcement and shape memory effect of graphite nanoplatelet–reinforced epoxy composites

Limin Zhao、Xue Feng、Xujun Mi 等 6 位作者2014-07-23Journal of Intelligent Material Systems and Structures

The homogeneous dispersion of fine graphite nanoplatelets throughout the epoxy matrix with different mass fraction is prepared. Influence of graphite nanoplatelets of varied mass fraction in the mechanical reinforcement and shape memory effect of graphite nanoplatelets/epoxy composite is investigated. The morphology a…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingEpoxy Resin Curing Processes

Surface temperature: A key parameter to control the propanethiol plasma polymer chemistry

Damien Thiry、Francisco J. Aparicio、Priya Laha 等 5 位作者2014-07-23Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

In this work, the influence of the substrate temperature (Ts) on the chemical composition of propanethiol plasma polymers was investigated for a given set of plasma conditions. In a first study, a decrease in the atomic sulfur content (at. %S) with the deposition time (td) was observed. This behavior is explained by t…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchTribology and Wear Analysis

Impact of the various spin- and orbital-ordering processes on the multiferroic properties of orthovanadate DyVO3

Qiang Zhang、Kiran Singh、Ch. Simon 等 6 位作者2014-07-23Physical Review B

The orthovanadate ${\mathrm{DyVO}}_{3}$ crystal, known to exhibit multiple structural, spin-, and orbital-ordering transitions, is presently investigated on the basis of magnetization, heat capacity, resistivity, dielectric, and polarization measurements. Our main result is experimental evidence for the existence of m…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Synthesis and microwave absorption properties of Ni–Zn–Mn spinel ferrites

Y. Liu、X. Liu、X. Wang2014-07-23Advances in Applied Ceramics Structural Functional and Bioceramics

A series of Ni0·5−xZn0·3−xMn0·2+2xFe2O4 ferrites was successfully prepared by the sol–gel autocombustion method. The structure and electromagnetic properties of the powders were characterised by X-ray diffraction, SEM and vector network analysis. The pure powders were formed by heating at 1200°C for 3 h in air, and gr…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materials

Effects of silica nanoparticles on electro-optical properties of polymer-stabilized liquid crystals

Che-Ju Hsu、Chih-Chin Kuo、Chia-Ding Hsieh 等 4 位作者2014-07-23Optics Express

We control the pretilt angle of liquid crystals (LCs) by simultaneously doping silica nanoparticles (SNs) and reactive monomers into the LC cell. Application of AC high voltage (ACHV) to the cell compels the lifting force and the facilitation of polar groups to move the SNs and monomers toward the substrate surface. P…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsPlant Reproductive Biology

Large Self-Biased Magnetoelectric Properties in Heterostructure of Graded-Magnetostrictive Layers and a Rosen-Type Piezoelectric Transformer

Caijiang Lu、Ping Li、Yumei Wen 等 4 位作者2014-07-23IEEE Sensors Journal

This paper develops a magnetoelectric (ME) heterostructure FeCuNbSiB/Ni/Rosen-type piezoelectric transformer (RPT)/Ni/FeCuNbSiB consisting of a RPT Pb(Zr1-xTix)O3with its drive-end sandwiched between two graded-magnetostrictive layers of FeCuNbSiB/Ni. The graded-magnetostrictive layer FeCuNbSiB/Ni is made up of Fe-bas…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMagnetic Properties and Applications

Electrons in deterministic quasicrystalline potentials and hidden conserved quantities

Pavel Kalugin、A Katz2014-07-23Journal of Physics A Mathematical and Theoretical

We propose an ansatz for the wave function of a non-interacting quantum particle in a deterministic quasicrystalline potential. It is applicable to both continuous and discrete models and includes Sutherland's hierarchical wave function as a special case. The ansatz is parameterized by a first cohomology class of the…

Topological Materials and PhenomenaQuantum Mechanics and Non-Hermitian PhysicsQuasicrystal Structures and Properties

Infrared-active optical phonons and magnetic excitations in the hexagonal manganites RMnO3 ( R=Ho , Er, Tm, Yb, and Lu)

R. Basistyy、T. N. Stanislavchuk、A. A. Sirenko 等 9 位作者2014-07-23Physical Review B

Optical properties of hexagonal multiferroic oxides $R\mathrm{Mn}{\mathrm{O}}_{3}$, where $R=\mathrm{Ho}$, Er, Tm, Yb, and Lu, have been studied in the far-infrared spectral range between 100 and 2000 cm${}^{\ensuremath{-}1}$ and temperatures between 1.5 and 300 K by means of several experimental techniques: Mueller m…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials