Materials Literature
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Abstract A novel ABB′ monomer, an isomeric mixture of 4‐[4‐(2,4‐diaminophenoxy)phenoxy]phthalic acid 2‐methyl ester, was successfully prepared. The direct polycondensation of the ABB′ monomer was carried out to form polyamic acid monomethyl ester as a precursor with an inherent viscosity of 0.30 dL/g and a number‐aver…
We present the results of structural studies of poly(benzylphenyl ether) dendrimers (PBPE dendrimers) using classical molecular dynamics simulations. Specifically, we focus on four generations of PBPE dendrimer at 298 K. Our objectives are to calculate donor/acceptor distances and Förster energy-transfer rates as a fu…
Experimental data are presented for the scattering of cold electrons by ${\text{SF}}_{6}$ and ${\mathrm{C}}_{6}{\mathrm{F}}_{6}$, down to energies of a few meV, with an energy resolution varying between 0.95 and $1.5\phantom{\rule{0.3em}{0ex}}\text{meV}$ (full width at half maximum) in the electron beam. The measured…
The depletion potential between two hard spheres in a solvent of thin hard disclike platelets is investigated by using either the Derjaguin approximation or density functional theory. Particular attention is paid to the density dependence of the depletion potential. A second-order virial approximation is applied, whic…
Novel methods for enhancing the epoxide selectivity in the alkene epoxidation over [Ti,Al]-Beta have been developed. When as-synthesized [Ti,Al]-Beta was treated with aqueous ammonium nitrate solution and successively calcined at low temperature, a dramatic enhancement of epoxide selectivity was attained in the liquid…
We study capillary condensation between two spherical particles dispersed in the isotropic phase of a nematic liquid crystal. Within the Landau-de Gennes theory, we calculate interaction energies due to the formation of capillary bridges that reproduce experimental observations. Close to the critical point of the tran…
We previously proposed that the stereochemistry gate loops (SGLs) constituting the substrate binding pocket of D-hydantoinase, a (beta/alpha)(8)-barrel enzyme, might be major structural determinants of the substrate specificity [Cheon, Y. H., et al. (2002) Biochemistry 41, 9410-9417]. To construct a mutant D-hydantoin…
Amineterminated, ethylenediamine core polyamidoamine starburst dendrimers of generation 2 (G2), generation 4 (G4) and generation 6 (G6) have been successfully surface-modified via an amide coupling reaction with 4-ethyl, 4'-(3-propionic) bipyridinium cation and the electrochemical behavior of the resulting dendrimers…
Splayed polarization orientation has been confirmed in the anticlinic ferroelectric phase of a bent-core liquid crystal containing chiral end chains, P-8 -OPIMB6(*), by optical second-harmonic generation (SHG). The in-plane anisotropy of the SHG signal exhibits an unusual six-peak pattern under the rotation of paralle…
Abstract Polypropylene (PP) was prepared by metallocene catalysts so as to have a stereoblock structure, with isotactic sequences long enough to give crystallites functioning as crosslinks, but small enough in number to have the atactic chains predominate in a surrounding elastomeric matrix. The resulting thermoplasti…
The TM1459 gene of Thermotoga maritima encodes a conserved hypothetical protein with a molecular weight of 12,977 Da (residues 1–114) and a calculated isoelectric point of 5.6. Currently, no functional annotation has been made for this protein, made fold recognition methods such as Fold and Function Assignment System…
Abstract The graft copolymerization of reactive pregelled starch (PGS) with methacrylonitrile (MAN) was performed and the reaction conditions were optimized using potassium monopersulfate (PMPS) in the presence of ferrous ion redox pair as initiator. Emphasis was directed towards increasing the graft formation and dec…
Pegylated polystyrene particles (PS-PEG) were prepared as a model system for artificial cells, by modification of carboxyl polystyrene particles (PS-COOH) with homo- and hetero-bifunctional polyethylene glycols (PEG, MW 1500, 3400, and 5000) containing an amino end group for immobilization and an amino, hydroxyl, or m…
Abstract Styrene–ethylene/butylene–styrene triblock copolymer (SEBS)–clay hybrids were prepared by melt blending SEBS and organoclay using an internal mixer. Maleic anhydride modified SEBS (SEBS–MA) was used as a compatibilizer. X‐ray diffraction and transmission electron microscopy revealed that silicate layers of th…
We explore quantitatively the effect of pH on the osmotically induced swelling of polyelectrolyte multilayer microcapsules filled with solutions of a strong polyanion. The shells of the microcapsules are composed of strong polyanions and weak polycations via a layer-by-layer electrostatic self-assembly. The equilibriu…
The reorganization and melting of single crystals of linear polyethylene with lozenge and truncated-lozenge habits has been studied in situ during slow continuous heating using atomic force microscopy. The morphological insights obtained are backed up by complementary experiments using transmission electron microscopy…
The success of recent static printing experiments at Lawrence Berkeley National Laboratory’s Advanced Light Source (ALS) using the EUV LLC Engineering Test Stand (ETS) Set-2 optic has demonstrated the utility of synchrotron-based EUV exposure stations. Although not viable light sources for commercial lithography, sync…
Low-temperature electronic absorption and emission data are reported for Tm 3+ at the octahedral site in crystals of Cs 2 NaTmCl 6 . Thirty-seven crystal field levels (total degeneracy 88) of the f 12 configuration (total degeneracy 91) have been assigned, and in several cases the levels are split due to electron−phon…
Abstract The effectiveness of an antioxidant‐impregnated film to retard autoxidation of a packaged model product containing linoleic acid, via an evaporation/sorption mechanism, was evaluated as a function of storage time and temperature. The rate of loss of antioxidant from the package film structure was described by…
This article presents the synthesis of gold nanoparticles in a single-phase supercritical fluid carbon dioxide solvent. The gold nanoparticles were formed by the reduction of triphenylphosphine gold(I) perfluorooctanoate with dimethylamineborane. Transmission electron microscopy, X-ray photoelectron spectroscopy, and…