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Scalable and Versatile Graphene Functionalized with the Mannich Condensate

Ruijuan Liao、Zhenghai Tang、Tengfei Lin 等 4 位作者2013-03-06ACS Applied Materials & Interfaces

The functionalized graphene (JTPG) is fabricated by chemical conversion of graphene oxide (GO), using tea polyphenols (TP) as the reducer and stabilizer, followed by further derivatization through the Mannich reaction between the pyrogallol groups on TP and Jeffamine M-2070. JTPG exhibits solubility in a broad spectru…

Graphene research and applicationsPolymer Nanocomposite Synthesis and IrradiationGraphene and Nanomaterials Applications

Gold‐Nanoparticle‐Decorated Boron Nitride Nanosheets: Structure and Optical Properties

Sunil Singhal、V. Kumar、Karuppiah Stalin 等 9 位作者2013-03-06Particle & Particle Systems Characterization

Synergetic cooperation of individual components of the nanocomposites (NCs) is responsible for their novel properties that lead to various technological applications. A simple chemical process depicting the deposition of functionalized gold nanoparticles on the surface of boron nitride nanosheets (BNNSs) in solution i…

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Enzyme-Mimetic Catalyst-Modified Nanoporous SiO2–Cellulose Hybrid Composites with High Specific Surface Area for Rapid H2O2 Detection

Yijun Jiang、Wei Wang、Xiutao Li 等 6 位作者2013-03-06ACS Applied Materials & Interfaces

Mesoporous silica-cellulose hybrid composites were prepared by surface sol-gel coating process on nature cellulose substance. The template CTAB (hexadecyl trimethyl ammonium Bromide) in the silica film can be removed by extraction to obtain high specific surface area (80.7 m(2) g(-1)), which is 2 orders of magnitude h…

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsAdvanced Nanomaterials in Catalysis

The Wemple–DiDomenico model as a tool to probe the building blocks conforming a glass

J.M. González-Leal2013-03-06physica status solidi (b)

Abstract magnified image The low‐frequency optical dielectric response of glasses is discussed regarding its sensitivity to the presence of building blocks conforming their structure. The model suggested by Wemple and DiDomenico to describe the dispersion of the refractive index of solids is further developed in terms…

Material Dynamics and PropertiesGlass properties and applicationsPhase-change materials and chalcogenides

Effects of fabrication condition on the network morphology and electro-optical characteristics of polymer-dispersed bistable smectic A liquid crystal device

Yang Lü、Jie Wei、Yang Shi 等 5 位作者2013-03-06Liquid Crystals

In this study, a bistable smectic A (SmA) liquid crystal (LC) device based on polymer-dispersed liquid crystal (PDLC) mode was demonstrated, in which SmA PDLC films were prepared from ultraviolet (UV) irradiation-induced polymerisation of the acrylate monomers in acrylate monomers/ion-doped SmA LCs mixtures. The effec…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPhase-change materials and chalcogenides

Cyclodextrin Insulation Prevents Static Quenching of Conjugated Polymer Fluorescence at the Single Molecule Level

Daniel Thomsson、Rafael Camacho、Yuxi Tian 等 7 位作者2013-03-06Small

Conjugated polymers (CPs) are promising materials for fluorescence imaging application. However, a significant problem in this field is the unexplained abnormally low fluorescence brightness (or number of fluorescence photons detected per one excitation photon) exhibited by most of CP single chains in solid polymer ho…

Organic Electronics and PhotovoltaicsPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Effect of backbone moiety in epoxies on thermal conductivity of epoxy/alumina composite

Thanhkieu Giang、Jaeman Park、Inhee Cho 等 5 位作者2013-03-06Polymer Composites

Abstract We chose two commercial epoxies, bisphenol A diglycidyl ether (DGEBA) and 3,3′,5,5′‐tetramethyl‐4,4′‐biphenol diglycidyl ether (TMBP), and synthesized one liquid crystalline epoxy (LCE), 4′4′‐bis(4‐hydroxybenzylidene)‐diaminophenylene diglycidyl ether (LCE‐DP) to investigate the effect of backbone moiety in e…

Epoxy Resin Curing ProcessesThermal properties of materialsSynthesis and properties of polymers

Prospects for Ferroelectrics: 2012–2022

J. F. Scott2013-03-06ISRN Materials Science

A review is given of more than a dozen subtopics within the general study of ferroelectrics, with emphasis upon controversies, unsolved problems, and prospects for the next decade, including pure science and industrial applications. The review emphasizes work over the past two years, from 2010 to 2012.

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Fluorescent Magnetic Fe3O4/Rare Earth Colloidal Nanoparticles for Dual‐Modality Imaging

Haie Zhu、Yalei Shang、Wenhao Wang 等 11 位作者2013-03-06Small

Fluorescent magnetic colloidal nanoparticles (FMCNPs) are produced by a two-step, seed emulsifier-free emulsion polymerization in the presence of oleic acid and sodium undecylenate-modified Fe3 O4 nanoparticles (NPs). The Fe3 O4 /poly(St-co-GMA) nanoparticles are first synthesized as the seed and Eu(AA)3 Phen is copol…

Nanoparticle-Based Drug DeliveryNanocluster Synthesis and ApplicationsCharacterization and Applications of Magnetic Nanoparticles

Selective Semihydrogenation of Alkynes on Shape‐Controlled Palladium Nanocrystals

Jooyoung Chung、Chanhoi Kim、Hansaem Jeong 等 9 位作者2013-03-06Chemistry - An Asian Journal

A systematic study on the selective semihydrogenation of alkynes to alkenes on shape-controlled palladium (Pd) nanocrystals was performed. Pd nanocrystals with a cubic shape and thus exposed {100} facets were synthesized in an aqueous solution through the reduction of Na2PdCl4 with L-ascorbic acid in the presence of b…

Catalytic Processes in Materials ScienceNanocluster Synthesis and ApplicationsNanomaterials for catalytic reactions

Photoexcitation Dynamics of Coupled Semiconducting Carbon Nanotube Thin Films

Randy D. Mehlenbacher、Meng‐Yin Wu、Maksim Grechko 等 6 位作者2013-03-06Nano Letters

Carbon nanotubes are a promising means of capturing photons for use in solar cell devices. We time-resolved the photoexcitation dynamics of coupled, bandgap-selected, semiconducting carbon nanotubes in thin films tailored for photovoltaics. Using transient absorption spectroscopy and anisotropy measurements, we found…

Carbon Nanotubes in CompositesMechanical and Optical ResonatorsThermal Radiation and Cooling Technologies

Carbon nanotube growth for through silicon via application

Rongrong Xie、C. Zhang、Marleen H. van der Veen 等 8 位作者2013-03-06Nanotechnology

Through silicon via (TSV) technology is key for next generation three-dimensional integrated circuits, and carbon nanotubes (CNT) provide a promising alternative to metal for filling the TSV. Three catalyst preparation methods for achieving CNT growth from the bottom of the TSV are investigated. Compared with sputteri…

Carbon Nanotubes in CompositesGraphene research and applicationsNanowire Synthesis and Applications

Direct Fabrication of Cobalt Oxide Nanoparticles Employing Sucrose as a Combustion Fuel

M.Th. Makhlouf、Bahaa M. Abu‐Zied、Tharwat Hassan Mansoure2013-03-06Journal of Nanoparticles

Combustion method has been used as a fast and facile method to prepare nanocrystalline Co 3 O 4 spinel employing sucrose as a combustion fuel. The products were characterized by thermal analyses (TGA and DTA), X-ray diffraction technique (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microsco…

Chalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applicationsThermal and Kinetic Analysis

Controlling Liquid Spreading Using Microfabricated Undercut Edges

Ville Liimatainen、Veikko Sariola、Quan Zhou2013-03-06Advanced Materials

A purely topographical method for controlling liquid spreading by using easy-to-fabricate undercut edges is reported. By periodic repetition of such edges, it is shown that multiple droplets can be patterned in well-controlled shapes, and highly anisotropic wetting can also be achieved at a large scale. Apparent conta…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferFluid Dynamics and Thin Films

Thermal Transfer in Graphene-Interfaced Materials: Contact Resistance and Interface Engineering

Hanxiong Wang、Jixuan Gong、Yongmao Pei 等 4 位作者2013-03-06ACS Applied Materials & Interfaces

We investigate here heat transfer across interfaces consisting of single- and few-layer graphene sheets between silicon carbides by performing nonequilibrium molecular dynamics simulations. The interfacial thermal conducitivity κI is calculated by considering graphene layers as an interfacial phase. The results indica…

Graphene research and applicationsThermal properties of materialsThermal Radiation and Cooling Technologies

Aligned Carbon Nanotubes for High‐Efficiency Schottky Solar Cells

Jiangtao Di、Zhenzhong Yong、Xinhe Zheng 等 5 位作者2013-03-06Small

The development of low-cost and high-efficiency silicon Schottky solar cells has drawn considerable interest in recent years. A facial approach for the fabrication of carbon nanotube-silicon (CNT-Si) Schottky solar cells by using aligned double-walled CNTs drawn from a CNT array is demonstrated. The aligned CNTs help…

Carbon Nanotubes in CompositesNanowire Synthesis and ApplicationsSemiconductor materials and interfaces

Electronic and optical properties of ZnO quantum dots under hydrostatic pressure

Zaiping Zeng、Christos S. Garoufalis、Sotirios Baskoutas 等 4 位作者2013-03-06Physical Review B

In the present work, we studied the electronic and optical properties of ZnO quantum dots (QDs) subjected to externally applied hydrostatic pressure. Our single-particle calculations are based on the empirical pseudopotential method and the excitonic effects are considered by employing the configuration interaction ap…

ZnO doping and propertiesPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Covalent organic frameworks and their metal nanoparticle composites: Prospects for hydrogen storage

Suresh Babu Kalidindi、Roland A. Fischer2013-03-06physica status solidi (b)

Abstract Covalent organic frameworks (COFs) are microporous crystalline organic frameworks with large specific surface areas. The area of COFs is rapidly developing in the direction of finding potential applications in fields like gas storage, photovoltaics, and catalysis. With respect to hydrogen storage, at first gl…

Metal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas TransportCovalent Organic Framework Applications

Collective Excitation of an Electric Dipole on a Molecular Dimer in an Organic Dimer-Mott Insulator

K. Itoh、H. Itoh、M. Naka 等 9 位作者2013-03-06Physical Review Letters

The terahertz response in $10--100\text{ }\text{ }{\mathrm{cm}}^{\ensuremath{-}1}$ was investigated in an organic dimer-Mott (DM) insulator $\ensuremath{\kappa}\mathrm{\text{\ensuremath{-}}}(\mathrm{ET}{)}_{2}{\mathrm{Cu}}_{2}(\mathrm{CN}{)}_{3}$ that exhibits a relaxorlike dielectric anomaly. An $\ensuremath{\sim}30\…

Perovskite Materials and ApplicationsOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography

Statistical Analysis of Variation in Laboratory Growth of Carbon Nanotube Forests and Recommendations for Improved Consistency

C. Ryan Oliver、Erik S. Polsen、Eric R. Meshot 等 7 位作者2013-03-06ACS Nano

While many promising applications have been demonstrated for vertically aligned carbon nanotube (CNT) forests, lack of consistency in results (e.g., CNT quality, height, and density) continues to hinder knowledge transfer and commercialization. For example, it is well known that CNT growth can be influenced by small c…

Carbon Nanotubes in CompositesAdvanced Thermodynamics and Statistical MechanicsField-Flow Fractionation Techniques