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Electrochemistry of Aqueous Colloidal Graphene Oxide on Pt Electrodes

Glen D. O’Neil、Andrew W. Weber、Raluca Buiculescu 等 5 位作者2014-07-14Langmuir

The electrochemical behavior of colloidal solutions of graphene oxide (GO) is described here in detail. The GO reduction is shown to exhibit near-reversible electron transfer on Pt electrodes, based on E1/2 and ΔEp values. The observed peak current is found to depend linearly on the concentration of the GO and the squ…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Focal depth measurement of scanning helium ion microscope

Hongxuan Guo、Hiroshi Itoh、Chunmei Wang 等 5 位作者2014-07-14Applied Physics Letters

When facing the challenges of critical dimension measurement of complicated nanostructures, such as of the three dimension integrated circuit, characterization of the focal depth of microscopes is important. In this Letter, we developed a method for characterizing the focal depth of a scanning helium ion microscope (H…

Advancements in Photolithography TechniquesElectron and X-Ray Spectroscopy TechniquesIntegrated Circuits and Semiconductor Failure Analysis

Mechanistic Insights into Mg2+-Independent Prenylation by CloQ from Classical Molecular Mechanics and Hybrid Quantum Mechanics/Molecular Mechanics Molecular Dynamics Simulations

Craig A. Bayse、Kenneth M. Merz2014-07-14Biochemistry

Understanding the mechanism of prenyltransferases is important to the design of engineered proteins capable of synthesizing derivatives of naturally occurring therapeutic agents. CloQ is a Mg(2+)-independent aromatic prenyltransferase (APTase) that transfers a dimethylallyl group to 4-hydroxyphenylpyruvate in the bios…

Mass Spectrometry Techniques and ApplicationsCrystallography and molecular interactionsEnzyme Structure and Function

Colour Metallography of Cast Aluminium Alloys

Laura García、Christian Dietz、A. Criado 等 4 位作者2014-07-14Practical Metallography

Abstract For better observation of the microstructure of cast aluminium alloys under an optical microscope, the contrast obtained for the different micro constituents was enhanced by making use of a copper phthalocyanine based colorant. The proposed method allows distinguishing structural details which would remain hi…

Aluminum Alloy Microstructure PropertiesElectron and X-Ray Spectroscopy TechniquesAnodic Oxide Films and Nanostructures

Selective solvent annealing induced phase separation and dewetting in PMMA/SAN blend ultrathin films

Shuangshuang Zhang、Yu Zhu、Tongfei Shi 等 6 位作者2014-07-14Journal of Polymer Science Part B Polymer Physics

Phase behaviors induced by solvent annealing in poly(methyl methacrylate) (PMMA) and poly(styrene-ran-acrylonitrile) (SAN) blend ultrathin films have been investigated by atomic force microscopy and grazing incidence small-angle X-ray scattering. Our results indicate that both the phase separation within the blend and…

Rheology and Fluid Dynamics StudiesBlock Copolymer Self-AssemblyFluid Dynamics and Thin Films

Unraveling the Polymorphism of [(p-cymene)Ru(κN-INA)Cl2] through Dispersion-Corrected DFT and NMR GIPAW Calculations

Davide Presti、Alfonso Pedone、Maria Cristina Menziani2014-07-14Inorganic Chemistry

The structural and (13)C/(1)H NMR parameters of the four crystal forms (1α, 1·H2O, 1β, and 1γ) of the solid wheel-and-axle (WAA) metal-organic compound [(p-cymene)Ru(κN-INA)Cl2] have been studied by means of periodic DFT calculations. The quality of the results obtained strongly depends on a correct description of lon…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Interchain relay of antiferromagnetic ordering in 1D Co( ii ) coordination polymers via π–π interactions

Musheer Ahmad、Raja Das、Jerzy Mroziński 等 6 位作者2014-07-14CrystEngComm

Two new Phen-Co(II) complexes bridged by a hydroxyl isophthalate ligand, {[Co(dimphen)(HIA)]·H2O}n (1) and {[Co(phen)(HIA)]·H2O}n (2) (dimphen = 2,9-dimethyl-1,10-phenanthroline, phen = 1,10-phenanthroline, HIA = 5-hydroxyisophthalic acid), have been synthesized by carefully tuning the basicity of the reaction medium.…

Metal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesMagnetism in coordination complexes

Phosphorescent light-emitting diodes using triscarbazole/bis(oxadiazole) hosts: comparison of homopolymer blends and random and block copolymers

Xuyang He、Dengke Cai、Dun‐Yen Kang 等 12 位作者2014-07-14Journal of Materials Chemistry C

Examples of blends of carbazole- and bis(oxadiazole)benzene-based side-chain polymers have recently been reported to be efficient host materials for phosphorescent emitters in organic light-emitting diodes. Here, the properties and performance of a physical blend of polynorbornene homopolymers with triscarbazole and b…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Out-of-plane effects on dynamic pull-out of p -phenylene terephthalamide yarns

Zherui Guo、Jihye Hong、James Q. Zheng 等 4 位作者2014-07-14Textile Research Journal

In this study, the mechanical response of a single yarn pull-out from single layers of Kevlar® and Twaron® fabric under out-of-plane loading at dynamic rates was experimentally investigated, as ballistic applications typically occur at higher velocities and out-of-plane directions compared to previous literature. In o…

Mechanical Behavior of CompositesTextile materials and evaluationsFiber-reinforced polymer composites

Ni-W Electrodeposited Coatings on Low Carbon Steel Substrate: Fatigue Observations

Katarzyna Mróz、Agnieszka Bigos、S. Kucharski 等 5 位作者2014-07-14Journal of Materials Engineering and Performance

The fatigue response of electrodeposited Ni-W on low carbon steel substrate was studied. The considered Ni-W coatings are a promising substitute for toxic hard chromium coatings which, according to EU directives (2000/53/WE, 2011/37/UE), must be eliminated. Specimens of pure substrate and those covered by coating were…

Metal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metalsElectrodeposition and Electroless Coatings

Reconstruction of the Right Atrium and Superior Vena Cava with Extracellular Matrix

Michał Szczeklik、Prity Gupta、Rajiv Amersey 等 4 位作者2014-07-14Journal of Cardiac Surgery

We describe our technique for reconstructing the free right atrial wall and superior vena cava using CorMatrix (CorMatrix Alpharetta, GA, USA) extracellular matrix following resection of a large leiomyosarcoma. doi: 10.1111/jocs.12398 (J Card Surg 2015;30:351–354)

Electrospun Nanofibers in Biomedical ApplicationsCardiac tumors and thrombiTissue Engineering and Regenerative Medicine

Effect of heat-treatment on the dielectric properties of CaMgSi2O6 glass-ceramics with Cr2O3–Fe2O3–TiO2

Young Jun Eoh、Eung Soo Kim2014-07-14Japanese Journal of Applied Physics

The dielectric properties of CaMgSi 2 O 6 glass-ceramics were investigated at microwave frequencies as a function of Cr 2 O 3 –Fe 2 O 3 –TiO 2 (CFT) content and heat-treatment method. The specimens with 0.5 wt % CFT heat-treated at 900 °C for 3 h showed the maximum degree of crystallization and a high quality factor (…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisMicrowave Dielectric Ceramics Synthesis

A Ruthenium‐Based Light‐Harvesting Antenna Bearing an Anthracene Moiety in Dye‐Sensitized Solar Cells

Georgios C. Vougioukalakis、Maria Konstantakou、Eleftherios K. Pefkianakis 等 9 位作者2014-07-14Asian Journal of Organic Chemistry

Abstract A heteroleptic ruthenium sensitizer (DV56) bearing a terpyridine ligand with an appended phenylanthracene moiety was synthesized and extensively characterized. The physicochemical properties of the light‐harvesting antenna were studied in solution and on sensitized TiO2 thin film electrodes using a variety of…

TiO2 Photocatalysis and Solar CellsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Adapting SAFT-γ perturbation theory to site-based molecular dynamics simulation. II. Confined fluids and vapor-liquid interfaces

Ahmadreza F. Ghobadi、J. Richard Elliott2014-07-14The Journal of Chemical Physics

In this work, a new classical density functional theory is developed for group-contribution equations of state (EOS). Details of implementation are demonstrated for the recently-developed SAFT-γ WCA EOS and selective applications are studied for confined fluids and vapor-liquid interfaces. The acronym WCA (Weeks-Chand…

Hydrocarbon exploration and reservoir analysisPhase Equilibria and ThermodynamicsMaterial Dynamics and Properties

Evaluating smoldering behavior of fire-blocking barrier fabrics

Shonali Nazaré、William M. Pitts、Szabolcs Matkó 等 4 位作者2014-07-14Journal of Fire Sciences

This study reports on the smoldering propensity of commercially available barrier fabrics in a small-scale mock-up configuration. Most barrier fabrics are smolder resistant when tested alone over a standard flexible polyurethane foam. However, when covered with a smolder-prone cover fabric, most barrier fabrics failed…

Fire dynamics and safety researchFlame retardant materials and propertiesOccupational Health and Performance

Strong π-π interaction of porphyrins on (6,5) carbon nanotubes with full surface coverage: Ab-initio calculations

Walter Orellana2014-07-14Applied Physics Letters

The stability, electronic, and optical properties of (6,5) single-walled carbon nanotubes (CNTs) functionalized with free-base tetraphenylporphyrin (TPP) molecules through π-stacking interactions are studied by ab-initio calculations. The stability and optical response of the CNT-TPP compounds for increasing CNT-surfa…

Carbon Nanotubes in CompositesPorphyrin and Phthalocyanine ChemistryMolecular Junctions and Nanostructures

Improving the oxidation potential of Sb-doped SnO2 electrode by Zn/Sb co-doping

Aqing Chen、Binbin Li、Bojan Miljkovic 等 6 位作者2014-07-14Applied Physics Letters

Inorganic oxides are recognized as attractive materials for developing anodes for wastewater treatment, potentially offering a cost effective solution for electro-oxidation. A key parameter in measuring the effectiveness of different anode materials is the oxygen over potential. In this paper, we study the role of Zn…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

In Vitro Cytotoxicity and Phototoxicity Assessment of Acylglutamate Surfactants Using a Human Keratinocyte Cell Line

Abhay Kyadarkunte、Milind S. Patole、Varsha Pokharkar2014-07-14Cosmetics

In the current study, human keratinocyte cell line was used as in vitro cell culture model to elucidate the effects of the fatty acid chain length of acylglutamate (amino acid-based surfactant) namely, sodium cocoyl glutamate, sodium lauroyl glutamate, and sodium myristoyl glutamate on their cytotoxicity and the ultra…

Essential Oils and Antimicrobial ActivitySkin Protection and AgingPhotochromic and Fluorescence Chemistry

Shot noise in a quantum dot system coupled with Majorana bound states

Qiao Chen、Ke‐Qiu Chen、Hong-Kang Zhao2014-07-14Journal of Physics Condensed Matter

We investigate the spectral density of shot noise and current for the system of a quantum dot coupled to Majorana bound states (MBS) employing the nonequilibrium Green's function. The Majorana bound states at the end of the wire strongly affect the shot noise. There are two types of coupling in the system: dot-MBS and…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

The Cu2+ Binding Properties of Branched Peptides Based on l -2,3-Diaminopropionic Acid

Łukasz Szyrwiel、Łukasz Szczukowski、József S. Pap 等 6 位作者2014-07-14Inorganic Chemistry

Three new branched peptides, namely, H-Gly-Dap(H-Gly)-Gly-NH2 (3G), H-His-Dap(H-His)-Gly-NH2 (2HG), and H-Gly-Dap(H-Gly)-His-NH2 (2GH), where Dap stands for the 2,3-diaminopropionic acid residue, were synthesized by solid phase procedures. Because of the junction at Dap these peptides have three available pending arms…

Molecular Sensors and Ion DetectionChemical Synthesis and AnalysisSupramolecular Self-Assembly in Materials