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Radiolysis of Tributyl Phosphate by Particles of High Linear Energy Transfer

Jeremy D. Pearson、Mikael Nilsson2014-07-03Solvent Extraction and Ion Exchange

Tributyl Phosphate (TBP), used in chemical separation processes for used nuclear fuel, is susceptible to radiolysis causing losses in process performance. We have studied its degradation by exposing dry 1M TBP/n-dodecane solutions to gamma radiation from a cesium-137 source and in a mix of low and high linear energy t…

Radioactive element chemistry and processingNuclear Materials and PropertiesChemical Synthesis and Characterization

Estimating optimal time for fast chromatographic separations

Christopher J. Welch、Erik L. Regalado2014-07-03Journal of Separation Science

The term t(min cc) provides a ready estimate of the shortest time that can be obtained by "column cutting" for baseline resolution of two components showing excess chromatographic resolution. While actual column cutting is impractical, the t(min cc) value is shown to be closely related to the minimum separation time o…

Microfluidic and Capillary Electrophoresis ApplicationsAnalytical Chemistry and ChromatographyCrystallization and Solubility Studies

Granulometric characterization of airborne particulate release during spray application of nanoparticle-doped coatings

Daniel Göhler、Michael Stintz2014-07-03Journal of Nanoparticle Research

Airborne particle release during the spray application of coatings was analyzed in the nanometre and micrometre size range. In order to represent realistic conditions of domestic and handcraft use, the spray application was performed using two types of commercial propellant spray cans and a manual gravity spray gun. F…

Flame retardant materials and propertiesAerosol Filtration and Electrostatic PrecipitationParticle Dynamics in Fluid Flows

Descriptors for the Prediction of Partition Coefficients of 8-Hydroxyquinoline and its Derivatives

Michael H. Abraham、William E. Acree2014-07-03Separation Science and Technology

Literature data on water-solvent partition coefficients have been used to obtain Abraham descriptors for 8-hydroxyquinoline and a large number of its derivatives. From these descriptors and known equations for water-solvent partitions, it is possible to predict partition coefficients for 40 derivatives of 8-hydroxyqui…

Computational Drug Discovery MethodsAnalytical Chemistry and ChromatographyCrystallization and Solubility Studies

Lead Optimization of P5U and Urantide: Discovery of Novel Potent Ligands at the Urotensin-II Receptor

Alfonso Carotenuto、Luigia Auriemma、Francesco Merlino 等 13 位作者2014-07-03Journal of Medicinal Chemistry

We have optimized 1 (P5U) and urantide, two important ligands at the h-UT receptor, designing several analogues by the exchange of the Tyr9 residue with different unnatural aromatic amino acids. This study allowed us to discover novel ligands with improved activity. In particular, the replacement of the Tyr9 residue b…

Thermal Expansion and Ionic ConductivityCardiovascular Disease and AdiposityCardiovascular, Neuropeptides, and Oxidative Stress Research

Water-, oil-, and soil-repellent treatment of textiles, artificial leather, and leather

Meryem Türk、Andrea Ehrmann、Boris Mahltig2014-07-03Journal of the Textile Institute

Several products are on the market to realize water-, oil-, and soil-repellent properties on textiles or textile-related materials. To make an adequate and fast rating of repellent properties of finished textiles, different drop tests according to AATCC and ISO standards are commonly used. For evaluation of the repell…

Fire dynamics and safety researchTextile materials and evaluationsPlant Surface Properties and Treatments

High pressure synthesis and properties studies on spherical bulk ϵ-Fe3N

Wenwen Yin、Li Lei、Xiaodong Jiang 等 8 位作者2014-07-03High Pressure Research

Spherical iron nitride (ϵ-Fe3N) of 4 mm in diameter was synthesized by a high pressure solid-state metathesis reaction between alkaline or alkaline-earth metal ferrite (NaFeO2, MgFe2O4, and Ca2Fe2O5) and boron nitride. The Fe/N atomic ratio of the obtained crystals is close to 3:1 by means of energy-dispersive X-ray a…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

Borane-Protected Cyanides as Surrogates of H-Bonded Cyanides in [FeFe]-Hydrogenase Active Site Models

Brian C. Manor、Mark R. Ringenberg、Thomas B. Rauchfuss2014-07-03Inorganic Chemistry

Triarylborane Lewis acids bind [Fe2(pdt)(CO)4(CN)2](2-) [1](2-) (pdt(2-) = 1,3-propanedithiolate) and [Fe2(adt)(CO)4(CN)2](2-) [3](2-) (adt(2-) = 1,3-azadithiolate, HN(CH2S(-))2) to give the 2:1 adducts [Fe2(xdt)(CO)4(CNBAr3)2](2-). Attempts to prepare the 1:1 adducts [1(BAr3)](2-) (Ar = Ph, C6F5) were unsuccessful, b…

Hydrogen Storage and MaterialsMetalloenzymes and iron-sulfur proteinsInorganic Chemistry and Materials

Bidirectional regulation between TMEFF2 and STAT3 may contribute to H elicobacter pylori‐associated gastric carcinogenesis

Tiantian Sun、Jia‐Yin Tang、Wan Du 等 9 位作者2014-07-03International Journal of Cancer

The transmembrane protein with epidermal growth factor and two follistatin motifs 2 (TMEFF2) is a single-pass transmembrane protein, and it is downregulated in human gastric cancer and levels correlate with tumor progression and time of survival. However, the mechanism of its dysregulation in gastric cancer is little…

Helicobacter pylori-related gastroenterology studiesGenetic factors in colorectal cancerPhytochemistry and Bioactive Compounds

A statistical theory of cosolvent-induced coil-globule transitions in dilute polymer solution

Yu. A. Budkov、A. L. Kolesnikov、N. Georgi 等 4 位作者2014-07-03The Journal of Chemical Physics

We present a statistical model of a dilute polymer solution in good solvent in the presence of low-molecular weight cosolvent. We investigate the conformational changes of the polymer induced by a change of the cosolvent concentration and the type of interaction between the cosolvent and the polymer. We describe the p…

Material Dynamics and PropertiesAdvanced Physical and Chemical Molecular InteractionsElectrostatics and Colloid Interactions

Simultaneous Determination of Catechol, Hydroquinone, and Resorcinol on CTAB Functionalized Graphene Oxide/Multiwalled Carbon Nanotube Modified Electrode

Yu Jun Yang、Weikun Li2014-07-03Fullerenes Nanotubes and Carbon Nanostructures

Hexadecyl trimethyl ammonium bromide (CTAB) functionalized graphene oxide (CTAB-GO) was synthesized. The composite of CTAB-GO and multi-wall carbon nanotubes (MWNT) was used to modify glassy carbon electrode (GCE). The modified electrode showed excellent electrochemical catalytic activities towards the oxidation of ca…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Exploring Ultrafast Electronic Processes of Quasi-Type II Nanocrystals by Two-Dimensional Electronic Spectroscopy

Yoichi Kobayashi、Chi-Hung Chuang、Clemens Burda 等 4 位作者2014-07-03The Journal of Physical Chemistry C

Colloidal CdTe/CdSe heteronanostructures are model systems for quasi-type II nanocrystals (NCs) and have been examined extensively. However, the complex spectra in these heteronanostructures often make it difficult to reveal details of their optical properties by conventional techniques such as transient absorption sp…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsSpectroscopy and Quantum Chemical Studies

Structural stability of WS 2 under high pressure

Nirup Bandaru、Ravhi S. Kumar、Jason Baker 等 7 位作者2014-07-03International Journal of Modern Physics B

Structural behavior of bulk WS 2 under high pressure was investigated using synchrotron X-ray diffraction and diamond anvil cell up to 52 GPa along with high temperature X-ray diffraction and high pressure Raman spectroscopy analysis. The high pressure results obtained from X-ray diffraction and Raman analysis did not…

High-pressure geophysics and materialsBoron and Carbon Nanomaterials ResearchOrganic and Molecular Conductors Research

Defect self-doped TiO 2 for visible light activity and direct noble metal anchoring

Zengxia Pei、Luyao Ding、Wenhui Feng 等 5 位作者2014-07-03Physical Chemistry Chemical Physics

A facile approach was developed for preparing defective, self-doped TiO2, which shows remarkable visible light activity in the photocatalytic degradation of RhB and hydrogen liberation from water. Moreover, noble metal was directly deposited onto the TiO2 surface via an in situ redox reaction between surficial Ti(3+)…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCatalytic Processes in Materials Science

Strontium pyrophosphate modified by phosphoric acid for the dehydration of lactic acid to acrylic acid

Congming Tang、Jiansheng Peng、Xinli Li 等 8 位作者2014-07-03RSC Advances

The dehydration of lactic acid to acrylic acid over strontium catalysts was investigated. Strontium catalysts were prepared by a precipitation method. The catalysts were calcined at 500 °C for 6 hours in an air atmosphere and characterized by SEM for morphological features, by XRD for crystal phases, by FTIR for struc…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesCatalysis for Biomass Conversion

State-of-the-art of advanced gas metal arc welding processes: Dissimilar metal welding

Belinga Mvola、Paul Kah、Jukka Martikainen 等 4 位作者2014-07-03Proceedings of the Institution of Mechanical Engineers Part B Journal of Engineering Manufacture

The manufacturing industry has for many years shown interest in opportunities offered by the welding of dissimilar metals, for example, in transportation to reduce vehicles weight and in power plants, to fit heterogeneous working conditions. Early gas metal arc welding (GMAW) processes had limited control of heat inpu…

Advanced Welding Techniques AnalysisHydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual Stresses

Dynamical gate-tunable supercurrents in topological Josephson junctions

C. Kurter、A. D. K. Finck、Pouyan Ghaemi 等 5 位作者2014-07-03Physical Review B

Josephson junctions made of closely spaced conventional superconductors on the surface of three-dimensional topological insulators have been proposed to host Andreev bound states (ABSs), which can include Majorana fermions. Here, we present an extensive study of the supercurrent carried by low-energy ABSs in $\mathrm{…

Topological Materials and PhenomenaAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Identification of Metabolic Pathways Essential for Fitness of Salmonella Typhimurium In Vivo

Lotte Jelsbak、Hassan Hartman、Casper Schroll 等 11 位作者2014-07-03PLoS ONE

Bacterial infections remain a threat to human and animal health worldwide, and there is an urgent need to find novel targets for intervention. In the current study we used a computer model of the metabolic network of Salmonella enterica serovar Typhimurium and identified pairs of reactions (cut sets) predicted to be r…

Bacterial Genetics and BiotechnologyMicrobial Metabolic Engineering and BioproductionEnzyme Structure and Function

Gamma irradiation synthesis and characterization of AgNP/gelatin/PVA hydrogels for antibacterial wound dressings

Nuchanan Leawhiran、Prasit Pavasant、Kumpanart Soontornvipart 等 4 位作者2014-07-03Journal of Applied Polymer Science

ABSTRACT An antibacterial hydrogel wound dressing was successfully synthesized by the gamma irradiation method. A gelatin solution was mixed with a poly(vinyl alcohol) (PVA) solution of similar concentrations at different weight ratios of 100 : 0, 80 : 20, and 60 : 40 w/w, and irradiated at 30, 40, or 50 kGy. The test…

Electrospun Nanofibers in Biomedical ApplicationsWound Healing and TreatmentsAntimicrobial agents and applications

Physicochemical Properties of Three Ionic Liquids Containing a Tetracyanoborate Anion and Their Lithium Salt Mixtures

Nédher Sánchez-Ramírez、Vitor L. Martins、Rômulo A. Ando 等 7 位作者2014-07-03The Journal of Physical Chemistry B

Given their relevant physicochemical properties, ionic liquids (ILs) are attracting great attention as electrolytes for use in different electrochemical devices, such as capacitors, sensors, and lithium ion batteries. In addition to the advantages of using ILs containing lithium cations as electrolytes in lithium ion…

Advanced Battery Materials and TechnologiesIonic liquids properties and applicationsConducting polymers and applications