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Confined Multiple Enzymatic (Cascade) Reactions within Poly(dopamine)-based Capsosomes

Leticia Hosta‐Rigau、María José York-Durán、Yan Zhang 等 5 位作者2014-06-26ACS Applied Materials & Interfaces

The design of compartmentalized carriers as artificial cells is envisioned to be an efficient tool with potential applications in the biomedical field. The advent of this area has witnessed the assembly of functional, bioinspired systems attempting to tackle challenges in cell mimicry by encapsulating multiple compart…

Nanoparticle-Based Drug DeliveryPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Bio‐plastics and elastomers from polylactic acid/thermoplastic polyurethane blends

Vladislav Jašo、Miroslav Cvetinov、Srđan Rakić 等 4 位作者2014-06-26Journal of Applied Polymer Science

ABSTRACT Blends of two biocompatible polymers: thermoplastic polyester‐urethane (TPU) and polylactic acid (PLA) were studied. The effect of the blending ratio on blend morphology and properties was examined by running a series of blends from 10 to 80 wt % of PLA. Increasing TPU concentration in the blends lowered the…

biodegradable polymer synthesis and propertiesPolymer composites and self-healingCarbon dioxide utilization in catalysis

Emergence of electric polarity in BiTeX (X = Br and I) monolayers and the giant Rashba spin splitting

Yandong Ma、Ying Dai、Wei Wei 等 5 位作者2014-06-26Physical Chemistry Chemical Physics

A number of graphene-like materials have been theoretically predicted and experimentally confirmed so far. Here, based on the first-principles calculations, we predict that stable BiTeX (X = Br and I) monolayers possess intrinsic large polar electric fields along the normal direction to the plane, making them two-dime…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Synthesis and physical properties of Ca1−xRExFeAs2withRE= La–Gd

Alberto Sala、Hiroyuki Yakita、Hiraku Ogino 等 13 位作者2014-06-26Applied Physics Express

The synthesis of a series of layered iron arsenides Ca 1− x RE x FeAs 2 (112) was attempted by heating at 1000 °C under a high pressure of 2 GPa. The 112 phase successfully forms with rare earth ( RE ) = La, Ce, Nd, Sm, Eu, and Gd, while RE -free samples do not contain the 112 phase. While a Ce-doped sample does not s…

Corporate Taxation and AvoidanceIron-based superconductors research

Manganese Oxides Supported on TiO2–Graphene Nanocomposite Catalysts for Selective Catalytic Reduction of NOX with NH3 at Low Temperature

Xining Lu、Cunyi Song、Chein‐Chi Chang 等 6 位作者2014-06-26Industrial & Engineering Chemistry Research

TiO 2 –graphene (TiO 2 –GE) nanocomposites were prepared by the sol–gel method with different mass ratios of graphene (0–2% wt %). With the MnO X active component loaded by means of ultrasonic impregnation, the catalysts exhibited excellent structure and electrical properties, which favored the catalytic reaction. All…

Advancements in Battery MaterialsAdvanced Photocatalysis TechniquesCatalytic Processes in Materials Science

A Single-Component White-Emitting CaSr2Al2O6:Ce3+, Li+, Mn2+ Phosphor via Energy Transfer

Yanyan Li、Yurong Shi、Ge Zhu 等 8 位作者2014-06-26Inorganic Chemistry

A series of single-component Ce(3+), Li(+), Mn(2+) ions codoped color-tunable CaSr2Al2O6 phosphors were synthesized by a high-temperature solid-state reaction, and the photoluminescence properties as well as the energy transfer mechanism from Ce(3+) to Mn(2+) ions have been investigated in detail. The Ce(3+) activated…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsAmmonia Synthesis and Nitrogen Reduction

Thermophysiological comfort properties of different knitted fabrics used in cycling clothes

Esra Taştan Özkan、Binnaz Merıç2014-06-26Textile Research Journal

In this paper, we measured the thermal and moisture management properties of six different types of polyester knitted fabrics that are used in the production of summer cycling clothes. The test samples were selected from the most commonly used fabric structures according to the results of a survey on a cycling team in…

Thermoregulation and physiological responsesTextile materials and evaluationsErgonomics and Musculoskeletal Disorders

Enhanced Activity for CO Oxidation over WO3 Nanolamella Supported Pt Catalyst

Jiajun Wang、Zongyuan Wang、Changjun Liu2014-06-26ACS Applied Materials & Interfaces

WO3 nanolamella supported Pt catalyst has been prepared and applied for CO oxidation in this work. A significantly enhanced activity has been achieved, compared to that of the Pt catalyst supported by the WO3 nanoparticle. The catalyst characterization using X-ray diffraction (XRD), scanning electronic microscopy (SEM…

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and SensorsCatalysis and Oxidation Reactions

Reactivity of Crystalline ZnO Superstructures against Fungi and Bacterial Pathogens: Synthesized Using Nerium oleander Leaf Extract

Thimappa Ramachandrappa Lakshmeesha、M.K. Sateesh、B. Daruka Prasad 等 7 位作者2014-06-26Crystal Growth & Design

For the first time, different morphologies of zinc oxide (ZnO) superstructures are synthesized by a simple and environmental friendly route using Nerium oleander leaf extract as fuel. Powder X-ray diffraction, scanning electron microscopy, UV–visible spectroscopy, and photoluminescence studies are performed to ascerta…

ZnO doping and propertiesCopper-based nanomaterials and applicationsMagnesium Oxide Properties and Applications

Charge spill-out and work function of few-layer graphene on SiC(0 0 0 1)

O. Renault、Aline M. Pascon、H. Rotella 等 10 位作者2014-06-26Journal of Physics D Applied Physics

We report on the charge spill-out and work function of epitaxial few-layer graphene on 6 H-SiC(0 0 0 1). Experiments from high-resolution, energy-filtered x-ray photoelectron emission microscopy (XPEEM) are combined with ab initio density functional theory calculations using a relaxed interface model. The work functio…

Graphene research and applicationsSilicon Carbide Semiconductor TechnologiesBoron and Carbon Nanomaterials Research

On the objective origin of the phase transitions and metastability in many-particle systems

A. G. Godizov、A. Godizov2014-06-26International Journal of Modern Physics B

The modern equilibrium statistical mechanics, intended to link microscopic dynamics to thermodynamic laws for macroscopic quantities, is faced with significant difficulties, as applied to the description of the macroscopic properties of real condensed media within wide thermodynamic ranges, including the vicinities of…

Material Dynamics and PropertiesTheoretical and Computational PhysicsAdvanced Thermodynamics and Statistical Mechanics

Rationally Designed Surfactants for Few-Layered Graphene Exfoliation: Ionic Groups Attached to Electron-Deficient π‑Conjugated Unit through Alkyl Spacers

Lu Zhang、Zijian Zhang、Chaozheng He 等 6 位作者2014-06-26ACS Nano

Mass production of graphene with low cost and high throughput is very important for practical applications of graphene materials. The most promising approach to produce graphene with low defect content at a large scale is exfoliation of graphite in an aqueous solution of surfactants. Herein, we report a molecular desi…

Graphene research and applicationsMolecular Junctions and NanostructuresGraphene and Nanomaterials Applications

Color-Tunable Luminescence of Organoclay-Based Hybrid Materials Showing Potential Applications in White LED and Thermosensors

Tianren Wang、Peng Li、Huanrong Li2014-06-26ACS Applied Materials & Interfaces

Hybrid composites with great potential for white light LED and temperature sensing obtained through a simple, low cost, and environmental benign way is highly desirable and remains a challengeable task. Herein we present luminescent hybrid composites both in the form of powder and transparent film by simply mixing org…

Luminescence Properties of Advanced MaterialsLuminescence and Fluorescent MaterialsLanthanide and Transition Metal Complexes

Growth Modes of Quasicrystals

C. V. Achim、Michael Schmiedeberg、Hartmut Löwen2014-06-26Physical Review Letters

The growth of quasicrystals, i.e., aperiodic structures with long-range order, seeded from the melt is investigated using a dynamical phase field crystal model. Depending on the thermodynamic conditions, two different growth modes are detected, namely defect-free growth of the stable quasicrystal and a mode dominated…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaQuasicrystal Structures and Properties

Heterojunction Hybrid Devices from Vapor Phase Grown MoS2

Chanyoung Yim、Maria O’Brien、Niall McEvoy 等 12 位作者2014-06-26Scientific Reports

We investigate a vertically-stacked hybrid photodiode consisting of a thin n-type molybdenum disulfide (MoS2) layer transferred onto p-type silicon. The fabrication is scalable as the MoS2 is grown by a controlled and tunable vapor phase sulfurization process. The obtained large-scale p-n heterojunction diodes exhibit…

Graphene research and applications2D Materials and ApplicationsNanowire Synthesis and Applications

Framework flexibility and the negative thermal expansion mechanism of copper(I) oxide Cu 2 O

Leila H. N. Rimmer、Martin T. Dove、Björn Winkler 等 6 位作者2014-06-26Physical Review B

The negative thermal expansion (NTE) mechanism in ${\mathrm{Cu}}_{2}\mathrm{O}$ has been characterized via mapping of different ${\mathrm{Cu}}_{2}\mathrm{O}$ structural flexibility models onto phonons obtained using ab initio lattice dynamics. Low-frequency acoustic modes that are responsible for the NTE in this mater…

Advanced Battery Materials and TechnologiesLayered Double Hydroxides Synthesis and ApplicationsThermal Expansion and Ionic Conductivity

Electron localization and possible phase separation in the absence of a charge density wave in single-phase 1T-VS$_2$

A. Gauzzi、A. Sellam、G. Rousse 等 15 位作者2014-06-26arXiv

We report on a systematic study of the structural, magnetic and transport properties of high-purity 1T-VS$_2$ powder samples prepared under high pressure. The results differ notably from those previously obtained by de-intercalating Li from LiVS$_2$. First, no Charge Density Wave (CDW) is found by transmission electro…

Materials ScienceStrongly Correlated Electrons

A theoretical study on the performances of thermoelectric heat engine and refrigerator with two-dimensional electron reservoirs

Xiaoguang Luo、Jizhou He、Kailin Long 等 6 位作者2014-06-26Journal of Applied Physics

Theoretical thermoelectric nanophysics models of low-dimensional electronic heat engine and refrigerator devices, comprising two-dimensional hot and cold reservoirs and an interconnecting filtered electron transport mechanism have been established. The models were used to numerically simulate and evaluate the thermoel…

Advanced Thermoelectric Materials and DevicesMolecular Junctions and NanostructuresAdvanced Thermodynamics and Statistical Mechanics

R-phase transformation in NiTi alloys

X. B. Wang、Bert Verlinden、J. Van Humbeeck2014-06-26Materials Science and Technology

In near equiatomic NiTi alloys, the thermoelastic transformation between austenite and the R-phase shows unique properties, which make the R-phase transformation very promising for applications. In the present paper, the fundamental issues related to the R-phase transformation, especially the effects of different ther…

Shape Memory Alloy TransformationsIntermetallics and Advanced Alloy PropertiesHigh Entropy Alloys Studies