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A non-aqueous procedure to synthesize amino group bearing nanostructured organic–inorganic hybrid materials

Mandy Göring、Andreas Seifert、Katja Schreiter 等 5 位作者2014-07-07Chemical Communications

Amino-functionalized organic-inorganic hybrid materials with a narrow distributed nanostructure of 2-4 nm in size were obtained by means of a template-free and non-aqueous procedure. Simultaneous twin polymerization of novel amino group containing twin monomers with 2,2'-spirobi[4H-1,3,2-benzodioxasiline] has been app…

biodegradable polymer synthesis and propertiesPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

Results of a New Production of Nuclear-Grade 1.4970 ‘15-15Ti’ Stainless Steel Fuel Cladding Tubes for GEN IV Reactors

Rémi Delville、E. Stergar、Marc Verwerft2014-07-07Volume 1: Plant Operations, Maintenance, Engineering, Modifications, Life Cycle and Balance of Plant; Nuclear Fuel and Materials; Plant Systems, Structures and Components; Codes, Standards, Licensing and Regulatory Issues

Titanium stabilized 1.4970 ‘15-15Ti’ stainless steel cladding is the primary choice for fuel cladding of several current fast spectrum research reactor projects. The choice of cladding material is based on past experiences and the availability of material databases from similar steel grades that have proven their reli…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

Collision Time Measurements in a Sonoluminescing Microplasma with a Large Plasma Parameter

Alexander Bataller、Brian Kappus、Carlos G. Camara 等 4 位作者2014-07-07Physical Review Letters

The plasma which forms inside of a micron-sized sonoluminescing bubble in water for under a nanosecond has been probed with 3 ns long laser pulses. A comparison of the response to 532 and 1064 nm light indicates that the plasma number density is about 2×10(21) cm(-3) and that transport properties are dominated by stro…

Plasma Applications and DiagnosticsFluid Dynamics and Heat TransferUltrasound and Cavitation Phenomena

Quantum transport in chemically functionalized graphene at high magnetic field: defect-induced critical states and breakdown of electron-hole symmetry

Nicolas Leconte、Frank Ortmann、Alessandro Cresti 等 5 位作者2014-07-072D Materials

Quantum transport in chemically functionalized graphene at high magnetic field: defect-induced critical states and breakdown of electron-hole symmetry, Leconte, Nicolas, Ortmann, Frank, Cresti, Alessandro, Charlier, Jean-Christophe, Roche, Stephan

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures

An Integrated Process Analytical Technology (PAT) Approach for Process Dynamics-Related Measurement Error Evaluation and Process Design Space Development of a Pharmaceutical Powder Blending Bed

Huiquan Wu、Maury White、Mansoor A. Khan2014-07-07Organic Process Research & Development

In this work, a model pharmaceutical powder blending system consisting of ibuprofen (drug), MCC, and lactose anhydrous was monitored in real-time via inline near-infrared (NIR) spectroscopy for dual purposes: (1) to examine the effects of formulation variables (drug and MCC contents) and a process variable (impeller r…

Advanced Statistical Process MonitoringCrystallization and Solubility StudiesMineral Processing and Grinding

Fire Performance of Plywood Treated with Ammonium Polyphosphate and 4A Zeolite

Mingzhi Wang、Xiaomeng Wang、Li Li 等 4 位作者2014-07-07BioResources

Plywood samples treated with ammonium polyphosphate (APP) and 4A zeolite were prepared to investigate the effect of zeolite on wood’s burning behavior using a cone calorimeter under a heat flux of 35 kW/m2. Results showed that APP decreased the heat release rate (HRR), total heat release (THR), and mass loss rate (MLR…

Fire dynamics and safety researchFlame retardant materials and properties

Poly(vinyl chloride) Nanocomposites

D. Feldman2014-07-07Journal of Macromolecular Science Part A

Poly(vinyl chloride) is one of the major thermoplastics beside other commodities polymers like polyethylene and polystyrene. However, some of its main characteristics such as plasticity, thermal and photo stability are inferior to other commodity polymers. Adding nano scale inorganic fillers to poly(vinyl chloride) or…

Advanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and PropertiesPolymer Science and PVC

Stabilizing the Microphase Separation of Block Copolymers by Controlled Photo‐crosslinking

Katharina Tietz、Stefanie Finkhäuser、K. Samwer 等 4 位作者2014-07-07Macromolecular Chemistry and Physics

Photo‐crosslinkable material is produced via self‐assembly of poly(methyl methacrylate)‐block‐poly(n‐butyl acrylate) (PMMA‐b‐PBA) block copolymers, in which the MMA block is decorated with coumarin moieties. The block copolymer is synthesized by reversible addition‐fragmentation chain transfer (RAFT) polymerization. A…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assembly

Highly Selective Epoxidation of Cycloaliphatic Alkenes with Aqueous Hydrogen Peroxide Catalyzed by [PO4{WO(O2)2}4]3−/Imidazole

Keigo Kamata、Kosei Sugahara、Ryo Ishimoto 等 7 位作者2014-07-07ChemCatChem

Abstract In the presence of imidazole as an additive, a phosphorus‐containing tetranuclear peroxotungstate, THA3[PO4{WO(O2)2}4] (I, THA=tetra‐n‐hexylammonium), could act as an efficient catalyst for epoxidation of cycloaliphatic alkenes with 30 % aqueous hydrogen peroxide (H2O2). Compound I showed higher catalytic act…

Polyoxometalates: Synthesis and ApplicationsChemical Synthesis and ReactionsVanadium and Halogenation Chemistry

METAL-POOR DWARF GALAXIES IN THE SIGRID GALAXY SAMPLE. II. THE ELECTRON TEMPERATURE-ABUNDANCE CALIBRATION AND THE PARAMETERS THAT AFFECT IT

David C. Nicholls、Michael A. Dopita、Ralph S. Sutherland 等 5 位作者2014-07-07The Astrophysical Journal

In this paper, we use the Mappings photoionization code to explore the physical parameters that impact on the measurement of electron temperature and abundance in H ii regions. In our previous paper, we presented observations and measurements of physical properties from the spectra of 17 H ii regions in 14 isolated dw…

Atomic and Molecular PhysicsElectron and X-Ray Spectroscopy TechniquesScientific Research and Discoveries

Topology breaking of the vortex in multiferroic Y0.67Lu0.33MnO3

Qinghua Zhang、Guotai Tan、Lin Gu 等 8 位作者2014-07-07Applied Physics Letters

Although topological defects, such as domain walls (DWs) or vortices, are naturally protected by topological invariance, yet, we discover an exception that the six-state topology of the vortex with Z2 × Z3 symmetry is broken by a partial edge dislocation (PED) in hexagonal Y0.67Lu0.33MnO3, where the topologies of the…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Graphene Amplification by Continued Growth on Seed Edges

Lin Gan、Xuewu Ou、Qicheng Zhang 等 5 位作者2014-07-07Chemistry of Materials

Large-area single-layer graphenes with high crystallinity are desired for electronic applications. Here we demonstrate a continued growth method to amplify an existing graphene seed, originally grown by chemical vapor deposition, by preferentially inducing nucleation at seed edges. More specifically, this approach inv…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Effects of Complex Flame Retardant on the Thermal Decomposition of Natural Fiber

Na Xiao、Xue Zheng、Shuping Song 等 4 位作者2014-07-07BioResources

Natural fiber is a renewable resource characterized by its low cost and environmental friendliness. However, flame retardant properties are one of the biggest limitations for the preparation of composite materials that need to be improved. In this work, a novel complex flame retardant consisting of aluminum hydroxide…

Natural Fiber Reinforced CompositesLignin and Wood ChemistryFlame retardant materials and properties

Fabrication of mAb G250-SPIO Molecular Magnetic Resonance Imaging Nanoprobe for the Specific Detection of Renal Cell Carcinoma In Vitro

Cailuan Lu、Jinɡjinɡ Li、Kai Xu 等 7 位作者2014-07-07PLoS ONE

Molecular magnetic resonance imaging (mMRI) has been paid more and more attention for early diagnosis of cancer. A sensitive and specific mMRI probe plays the most important role in this technique. In this study, superparamagnetic iron oxide (SPIO) nanoparticles and mAb G250 were conjugated as mMRI probe for the detec…

Nanoparticle-Based Drug DeliveryLanthanide and Transition Metal ComplexesNanocluster Synthesis and Applications

Recent Advances of AIE-Active Conjugated Polymers: Synthesis and Application

Lingyun Wang、Guipo Fang、Derong Cao2014-07-07Journal of Macromolecular Science Part A

Conjugated polymers (CPs) have long been recognized as an important class of materials. The highly conjugated backbone of the CPs will facilitate the rapid exciton migration and result in amplification of fluorescence signals. However, CPs are likely to aggregate and form excimers in solid states, directly leading to…

Molecular Sensors and Ion DetectionOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Higher than 60% internal quantum efficiency of photoluminescence from amorphous silicon oxynitride thin films at wavelength of 470 nm

Pengzhan Zhang、Kunji Chen、Hengping Dong 等 8 位作者2014-07-07Applied Physics Letters

We reported the study on the photoluminescence internal quantum efficiency (PL IQE) and external quantum efficiency (PL EQE) from the amorphous silicon oxynitride (a-SiNO) films, which were fabricated by plasma-enhanced chemical vapor deposition followed by in situ plasma oxidation. We employed the direct measurement…

Semiconductor materials and devicesThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence

Structure and magnetic properties of Co nanowires electrodeposited into the pores of anodic alumina membranes

Iwona Dobosz、W. Gumowska、M. Czapkiewicz2014-07-07Journal of Solid State Electrochemistry

Cobalt nanowires were obtained in the process of electrodeposition into pores of an alumina membrane. Structural research (XRD, TEM) of Co revealed the face-centered cubic structure. However, the existence of the hexagonal structure cannot be excluded due to strong texture. The influences of an external magnetic field…

Magnetic properties of thin filmsElectrodeposition and Electroless CoatingsAnodic Oxide Films and Nanostructures

Tetrairon(III) Single-Molecule Magnet Monolayers on Gold: Insights from ToF-SIMS and Isotopic Labeling

Pasquale Totaro、Lorenzo Poggini、Annaïck Favre 等 8 位作者2014-07-07Langmuir

To work as magnetic components in molecular electronics and spintronics, single-molecule magnets (SMMs) must be reliably interfaced with metals. The organization on gold of a Fe4 SMM carrying two acetyl-protected thiol groups has been studied by exploiting the surface sensitivity of time-of-flight secondary ion mass s…

Magnetism in coordination complexesMolecular Junctions and NanostructuresLanthanide and Transition Metal Complexes

Non-covalent functionalization of single wall carbon nanotubes and graphene by a conjugated polymer

Jilili Jiwuer、Ayjamal Abdurahman、Oğuz Gülseren 等 4 位作者2014-07-07Applied Physics Letters

We report first-principles calculations on the binding of poly[(9,9-bis-(6-bromohexylfluorene-2,7-diyl)-co-(benzene-1,4-diyl)] to a (8,0) single wall carbon nanotube (SWCNT) and to graphene. Considering different relative orientations of the subsystems, we find for the generalized gradient approximation a non-binding…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Molecular Dynamics Studies of PEGylated α-Helical Coiled Coils and Their Self-Assembled Micelles

Sun Young Woo、Hwankyu Lee2014-07-07Langmuir

We performed coarse-grained (CG) molecular dynamics simulations of trimeric α-helical coiled coils grafted with poly(ethylene glycol) (PEG) of different sizes and conjugate positions and the self-assembled micelle of amphiphilic trimers. The CG model for the trimeric coiled coil is verified by comparing the α-helical…

Supramolecular Chemistry and ComplexesSurfactants and Colloidal SystemsSupramolecular Self-Assembly in Materials