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Synthesis and Properties of Step-Growth Polyamide Aerogels Cross-linked with Triacid Chlorides

Jarrod Williams、Mary Ann B. Meador、Linda McCorkle 等 5 位作者2014-07-04Chemistry of Materials

We report the first synthesis of step-growth aromatic polyamide (PA) aerogels made using amine end-capped polyamide oligomers cross-linked with 1,3,5-benzenetricarbonyl trichloride (BTC). Isophthaloyl chloride (IPC) or terephthaloyl chloride (TPC) were combined with m -phenylenediamine (mPDA) in N -methylpyrrolidinone…

Carbon dioxide utilization in catalysisAerogels and thermal insulationSilicone and Siloxane Chemistry

Imaging and steering an optical wireless nanoantenna link

Daniel Drégely、Klas Lindfors、Markus Lippitz 等 6 位作者2014-07-04Nature Communications

Optical nanoantennas tailor the transmission and reception of optical signals. Owing to their capacity to control the direction and angular distribution of optical radiation over a broad spectral range, nanoantennas are promising components for optical communication in nanocircuits. Here we measure wireless optical po…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchOrbital Angular Momentum in Optics

Surfactant Effects on the Structural and Magnetic Properties of Iron Oxide Nanoparticles

Maria Filippousi、M. Angelakeris、M. Katsikini 等 8 位作者2014-07-04The Journal of Physical Chemistry C

Iron oxide nanoparticles were prepared using the simplest and most efficient chemical route, the coprecipitation, in the absence and the presence of three different and widely used surfactants. The purpose of this study is to investigate the possible influence of the different surfactants on the structure and therefor…

Nanoparticle-Based Drug DeliveryIron oxide chemistry and applicationsCharacterization and Applications of Magnetic Nanoparticles

Enhanced Crystallinity in Organic–Inorganic Lead Halide Perovskites on Mesoporous TiO2 via Disorder–Order Phase Transition

Byung‐wook Park、Bertrand Philippe、Torbjörn Gustafsson 等 7 位作者2014-07-04Chemistry of Materials

Organic–inorganic halide perovskite (OIHP) compounds are very interesting materials for device application in, for example, solar cells, electro-optics, and electronic circuits. In this report, we investigated OIHPs reported as CH 3 NH 3 PbI 3– x Cl x (MAPbI 3– x Cl x ) and CH 3 NH 3 PbI 3 (MAPbI 3 ) prepared from sol…

Perovskite Materials and ApplicationsConducting polymers and applicationsSolid-state spectroscopy and crystallography

Availability of the Basal Planes of Graphene Oxide Determines Whether It Is Antibacterial

Liwei Hui、Ji‐Gang Piao、Jeffrey T. Auletta 等 8 位作者2014-07-04ACS Applied Materials & Interfaces

There are significant controversies on the antibacterial properties of graphene oxide (GO): GO was reported to be bactericidal in saline, whereas its activity in nutrient broth was controversial. To unveil the mechanisms underlying these contradictions, we performed antibacterial assays under comparable conditions. In…

Nanoparticles: synthesis and applicationsCarbon and Quantum Dots ApplicationsGraphene and Nanomaterials Applications

Bioactive Coatings for Orthopaedic Implants—Recent Trends in Development of Implant Coatings

Bill Zhang、Damian E. Myers、Gordon G. Wallace 等 5 位作者2014-07-04International Journal of Molecular Sciences

Joint replacement is a major orthopaedic procedure used to treat joint osteoarthritis. Aseptic loosening and infection are the two most significant causes of prosthetic implant failure. The ideal implant should be able to promote osteointegration, deter bacterial adhesion and minimize prosthetic infection. Recent deve…

Bone Tissue Engineering MaterialsOrthopaedic implants and arthroplastyPolymer Surface Interaction Studies

YASARA View—molecular graphics for all devices—from smartphones to workstations

Elmar Krieger、Gert Vriend2014-07-04Bioinformatics

SUMMARY: Today's graphics processing units (GPUs) compose the scene from individual triangles. As about 320 triangles are needed to approximate a single sphere-an atom-in a convincing way, visualizing larger proteins with atomic details requires tens of millions of triangles, far too many for smooth interactive frame…

Protein Structure and DynamicsEnzyme Structure and FunctionScientific Computing and Data Management

Nanomaterials for Hydrogen Storage

Hong Min Kan、Miao Sun、Ning Zhang 等 5 位作者2014-07-04Applied Mechanics and Materials

The nanocrystalline materials for hydrogen storage offer a breakthrough in prospects for practical applications. Their excellent properties are from the combined engineering of many factors: alloy composition, surface properties, microstructure, grain size and others. Nanoengineering can speed up the kinetics, lower t…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsAmmonia Synthesis and Nitrogen Reduction

Modulated SmA b phases formed by anchor shaped liquid crystalline molecules

Karina Geese、Marko Prehm、Carsten Tschierske2014-07-04Chemical Communications

Bent-core molecules with a linear alkyl chain in the bay position (anchor shaped molecules) form new liquid crystalline phases combining periodicities with different coherence lengths in distinct directions; in these LC phases the molecules are organized on average orthogonal in modulated layers (ribbons or patches) w…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsAdvanced Materials and Mechanics

Silicon Carbonitride Hollow Nanospheres from a Block‐Copolymer Precursor

Xueping Yang、Yaohan Chen、Yejie Cao 等 4 位作者2014-07-04Journal of the American Ceramic Society

Nonoxide S i CN hollow nanospheres were prepared from a block‐copolymer comprising of a precursor block and a sacrificial block. The copolymer was first synthesized and then self‐assembled into core‐shell structured micelles with the sacrificial block forming the core and the precursor block forming the shell. The mic…

Advanced ceramic materials synthesisCatalytic Processes in Materials ScienceMesoporous Materials and Catalysis

Nd:YVO4laser ablation of graphene films on glass and poly(ethylene terephthalate) substrates

Jeong Min Lee、Jung Hun Lee、Jae‐Hee Han 等 8 位作者2014-07-04Japanese Journal of Applied Physics

Nd:YVO4 laser ablation of graphene films on glass and poly(ethylene terephthalate) substrates, Lee, Jeong Min, Lee, Jung-Hun, Han, Jae-Hee, Yoo, Ji-Beom, Lee, Jong-Ho, Cho, Seongjae, Kwon, Sang Jik, Cho, Eou Sik

Graphene research and applicationsDiamond and Carbon-based Materials ResearchLaser-Ablation Synthesis of Nanoparticles

Semi-empirical calculations of radiative rates for parity-forbidden transitions within the 4f2configuration of Ba-like ions La+, Ce2+, Pr3+and Nd4+and 4f12configuration of Dy-like Yb4+

Hui Li、Xiao-Yu Kuang、Yau Yuen Yeung2014-07-04Journal of Physics B Atomic Molecular and Optical Physics

The experimental free ion 4f12 energy levels for Yb4+ have been fitted to the standard f-shell free ion Hamiltonian, which includes the major electrostatic and spin–orbit terms as well as various minor contributions like two-body, spin–spin, spin–other-orbit and electrostatically correlated spin–orbit interactions. Th…

Atomic and Molecular PhysicsLanthanide and Transition Metal ComplexesQuantum optics and atomic interactions

Metallic Strip Gratings in the Sub-Subwavelength Regime

Adriana Savin、Rozina Steigmann、Alina Bruma2014-07-04Sensors

Metallic strip gratings (MSG) have different applications, ranging from printed circuits to filters in microwave domains. When they are under the influence of an electromagnetic field, evanescent and/or abnormal modes appear in the region between the traces, their utilization leading to the development of new electrom…

Plasmonic and Surface Plasmon ResearchPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Effects of poly(butylene succinate) and ultrafine wollastonite on the physical properties of plasticized poly(vinyl chloride)

Saowaroj Chuayjuljit、Chutisa Siraprapoj、Anyaporn Boonmahitthisud2014-07-04Journal of Vinyl and Additive Technology

In this study, diisononyl phthalate (DINP), a conventional plasticizer of poly(vinyl chloride) (PVC), was partially replaced by a polymeric plasticizer, poly(butylene succinate) (PBS), in order to reduce the leaching out of low‐molecular‐weight plasticizer from the plasticized PVC. Samples were prepared by melt mixing…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesPolymer Science and PVC

A new inverse problem for the determination of textile fabrics thickness

Yinghong Xu、Dinghua Xu、Lipu Zhang 等 4 位作者2014-07-04Inverse Problems in Science and Engineering

This paper deals with a new inverse problem of estimating textile fabrics thickness based on a one-dimensional steady-state heat and moisture transfer model. First, we give an existence and uniqueness theorem for the solution to the heat and moisture transfer problem in the Banach space. Then we present an inverse pro…

Dyeing and Modifying Textile FibersTextile materials and evaluationsColor Science and Applications

Shape memory alloy actuated structural control with discrete time sliding mode control using multirate output feedback

K Dhanalakshmi、M. Umapathy、D. Ezhilarasi2014-07-04Journal of Vibration and Control

This paper presents the design and experimental evaluation of discrete time sliding mode controller using multirate output feedback to minimize structural vibration of a cantilever beam using shape memory alloy wires as control actuators and piezoceramics as sensor and disturbance actuator. Linear dynamic models of th…

Shape Memory Alloy TransformationsAeroelasticity and Vibration ControlStructural Engineering and Vibration Analysis

Review: Mixed-valent metallodendrimers: design and functions

Didier Astruc、Amalia Rapakousiou、Yanlan Wang 等 7 位作者2014-07-04Journal of Coordination Chemistry

Various types of mixed-valent metallodendrimers and star-shaped macromolecules containing ferrocenyl, biferrocenyl, or other redox-robust iron groups with rigid or flexible tethers of short and long lengths mostly studied in the authors’ laboratory including the class type in terms of Robin-Day classification and thei…

Conducting polymers and applicationsLuminescence and Fluorescent MaterialsDendrimers and Hyperbranched Polymers

In Situ Gamma Radiation‐Induced Attenuation in Sapphire Optical Fibers Heated to 1000°C

Christian Petrie、Brandon Wilson、Thomas E. Blue2014-07-04Journal of the American Ceramic Society

The purpose of this work was to determine the suitability of using instrumentation utilizing sapphire optical fibers in a high‐temperature gamma radiation environment. In this work, the broadband (500–2200 nm, or 0.56–2.48 eV) optical attenuation of commercially available sapphire optical fibers was monitored in situ…

Glass properties and applicationsPhotorefractive and Nonlinear OpticsOptical Systems and Laser Technology

Controlling the Er content of porous silicon using the doping current intensity

Guido Mula、Lucy Loddo、Elisa Pinna 等 8 位作者2014-07-04Nanoscale Research Letters

The results of an investigation on the Er doping of porous silicon are presented. Electrochemical impedance spectroscopy, optical reflectivity, and spatially resolved energy dispersive spectroscopy (EDS) coupled to scanning electron microscopy measurements were used to investigate on the transient during the first sta…

Semiconductor materials and devicesSilicon and Solar Cell TechnologiesSilicon Nanostructures and Photoluminescence

Microstructure and electrical properties of ultra high temperature (1–x)CaBi2Nb2O9–xNa0·5Bi2·5Nb2O9 ceramics

Xin Tian、Shaobo Qu、B. Wang 等 4 位作者2014-07-04Materials Research Innovations

Bismuth layer structured ferroelectric ceramics of (1–x)CaBi2Nb2O9–xNa0·5Bi2·5Nb2O9 [(1–x)CBNO–xNBNO, 0≤x≤1·0] ceramics were obtained by conventional solid state reaction method. The effects of Na0·5Bi2·5Nb2O9 (NBNO) addition on the microstructure and electrical properties of ceramics have been studied. X-ray diffract…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis