Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
In the present paper, nickel cobalt ferrite (Co0.5Zn0.5Fe2O4) nanoparticles were synthesized using a template-assisted hydrothermal method. Carboxymethyl cellulose was used as the templating agent for controlling the morphology of the Co0.5Zn0.5Fe2O4nanoparticles. The synthesized nanoparticles were characterized using…
We demonstrate a template-free synthetic approach for the preparation of a highly conductive Cu/Cu(2)O nanocomposite electrode by a chemical reduction process. Cu(2)O octahedra were prepared through chemical dehydrogenation of as-synthesized Cu(OH)(2) nanowire precursors. To provide a sufficiently electron-conducting…
We have studied the mechanism of the initial stages of nitrogen-doped single-walled carbon nanotube growth illustrated for the case of a floating catalyst chemical vapor deposition system, which uses carbon monoxide (CO) and ammonia (NH(3)) as precursors and iron as a catalyst. We performed first-principles electronic…
Dynamic characterization of materials is a complex process that usually requires expensive experimental tests. One of the most used experimental techniques for dynamic characterization of materials is the Split Hopkinson Pressure Bar test (SHPB). This technique allows to identify the stress-strain relationship of mate…
Size selective inclusion of organic molecules into pillared carbons accompanied by large interlayer expansions was observed for the first time. In order to achieve this, the distance between two adjacent pillars should be between 0.36 and 0.40 nm and they should align in the same direction.
Polyaniline (PANI) nanotubes have been synthesized employing chemical polymerization with acetic acid as dopant. The synthesized PANI nanotubes were characterized by Scanning electron microscope (SEM), Transmission electron microscope (TEM), Uv-visible spectroscopy and Fourier transform infrared spectroscopy (FTIR). T…
In this work, we perform a study of spin transport in bilayer graphene using semiclassical Monte Carlo simulation. Both the D’yakonov–Perel’ (DP) and Elliot–Yafet (EY) mechanisms for spin relaxation are considered. A vertical field of varying magnitude is applied across the bilayer and the dependence of the spin relax…
Onaka has recently (2010) discussed the application of the Hencky equivalent strain to the description of large strains in simple shear in the Journal of the Japan Institute of Metals. We find this analysis in error and introduce below what we consider as the appropriate approach to this problem. We also explain why t…
We describe an enneanuclear Fe(III) complex with an unusual boat-shaped core topology and an S=11/2 ground state, assembled using the ligands tricine {N-(2-hydroxy-1,1-bis(hydroxymethyl)ethyl)glycine, H(4)L} and 2-phenoxybenzoate.
In this paper, we have built up the organic-inorganic hybrid co-crystal (1) by using the derivative of ethylenediammonium cations (N,N,N′,N′-tetra-p-methoxybenzyl-ethylenediamine, L1) and [CuCl4]2− anions. The reaction was carried out by mixing MeOH solution of CuCl2·2H2O and HCl/MeOH solution of L1 at room temperatur…
The nano ceramic Ba0.5Sr0.5Co0.2Fe0.8O3 (BSCF) powders have been synthesized by Sol-Gel process using nitrate based chemicals for SOFC applications since these powders are considered to be more promising cathode materials for SOFC. Glycine was used as a chelant agent and ethylene glycol as a dispersant. The powders we…
NIR-dye encoded gold nanoparticles (GNP) are rapidly emerging as contrast agents in many bio-imaging/sensing applications. The coding process is usually carried out without control or a clear understanding of the metal-liquid interface properties which, in contrast, are critical in determining the type and extension o…
In this paper, mesoporous organosilicas functionalised with aminopropyl groups have been successfully used for peptide oligomerisation. For this purpose, three mesoporous silica SBA-15 type containing different amounts of aminopropyl groups were prepared by direct synthesis and using 3-tert-butyloxycarbonylamino propy…
Stealth macromolecular platforms bearing alkyne groups and poly(ethylene oxide) brushes were synthesized by reversible addition fragmentation chain transfer (RAFT) polymerization. The anchoring of Gd3+-chelates bearing an azide group was then carried out by the Huisgen 1,3-dipolar cycloaddition (“click”) reaction in m…
Shear thickening fluids (STFs) have been studied extensively, and an enormous number of patents have been generated due to their potential for commercial applications. STFs draw continued attention as they are considered possible candidate materials for liquid body armour and sporting protective clothing because of th…
Here, we report the synthesis and characterization of high-quality hierarchical ZnS nanobelt/ZnO nanorod heterostructures by a simple two-step vapor-phase transport method. On the basis of TEM results, ZnO nanorods epitaxially grew on the side surfaces of ZnS nanobelt along ±[001] directions, resulting in the hierarch…
Ruthenium (Ru) and ruthenium nitride (RuN) thin films have been investigated as candidates for barrier layers in copper (Cu) damascene processes. In order to study the thermal stability of the Ru and RuN films, the as-deposited films were annealed by rapid thermal annealing (RTA), and the film resistance was real-time…
First principles calculations have played a useful role in screening mixtures of complex metal hydrides to find systems suitable for H(2) storage applications. Standard methods for this task efficiently identify the lowest energy reaction mechanisms among all possible reactions involving collections of materials for w…
A new self-complementary supramolecule based on U-DPy possesses an extremely high association constant, far exceeding those of existing systems (Kdimer > 107 M−1). In addition, its sextuple hydrogen bonding interaction and π-packing can be further promoted through annealing, resulting in a flat ribbon structure.
The first monomeric anhydrous scandium tris(8-quinolinolate) complex 1 with the 2-amino-8-quinolinolate ligands and the Sc(2)Q(6) dinuclear complex 2 with the unsubstituted 8-quinolinolate ligands have been synthesized and characterized by X-ray analysis and DFT calculations. The intramolecular hydrogen bonds appear t…