Materials Literature
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The photoisomerization of azobenzene in solution was studied experimentally and by calculations. trans-to-cis and cis-to-trans dynamics are described through broadband transient absorption, fluorescence, and stimulated Raman spectroscopy. Transient absorption was extended to cover not only the nπ* band but also the ππ…
A porous metal-organic framework (MOF), [Ni2(dobdc)(H2O)2]⋅6 H2O (Ni2(dobdc) or Ni-MOF-74; dobdc(4-)=2,5-dioxido-1,4-benzenedicarboxylate) with hexagonal channels was synthesized using a microwave-assisted solvothermal reaction. Soaking Ni2(dobdc) in sulfuric acid solutions at different pH values afforded new proton-c…
A fast and low-cost sol-gel synthesis used to deposit a shell of TiO2 anatase onto an array of vertically aligned ZnO nanowires (NWs) is reported in this paper. The influence of the annealing atmosphere (air or N2) and of the NWs preannealing process, before TiO2 deposition, on both the physicochemical characteristics…
In this paper, the concept of frequency-coordinating virtual impedance is proposed for the autonomous control of a dc microgrid. This concept introduces another degree of freedom in the conventional droop control scheme, to enable both time-scale and power-scale coordination in a distributed microgrid system. As an ex…
This publication is the new edition of the International Basic Safety Standards. The edition is co-sponsored by seven other international organizations — European Commission (EC/Euratom), FAO, ILO, OECD/NEA, PAHO, UNEP and WHO. It replaces the interim edition that was published in November 2011 and the previous editio…
A material containing a phenothiazine (PTZ) electron donor unit and 2,4,6-triphenyl-1,3,5-triazine (TRZ) electron acceptor unit, PTZ-TRZ, which exhibits thermally activated delayed fluorescence (TADF) was developed. Density functional theory calculations revealed the existence of two ground-state conformers with diffe…
Adequate primary explosives such as lead azide mostly contain toxic ingredients, which have to be replaced. A new candidate that shows high potential, potassium 1,1'-dinitramino-5,5'-bistetrazolate (K2DNABT), was synthesized by a sophisticated synthetic procedure based on dimethylcarbonate and glyoxal. It was intensiv…
The promising energy storage properties of new lead-free antiferroelectric HfxZr1-xO2 (x = 0.1–0.4) films with high energy storage density are reported. The energy storage density of the Hf0.3Zr0.7O2 capacitor does not decrease with the increase in temperature up to 175 °C, and it decreases by only ≈4.5% after field c…
Over the last two decades, calix[4]pyrroles have attracted considerable attention as molecular containers. Used in this capacity, they have been exploited as strong and selective receptors and as extractants for both anions and ion pairs. More recently, calix[4]pyrroles have found application as carriers, systems capa…
Coupling ZnO with carbon materials using a suitable integration method to form ZnO-carbon composites has been established as a promising strategy to ameliorate the photocatalytic performance of semiconductor ZnO. In this perspective article, we describe the recent advances and current status of enhancing the photocata…
The ICH quality vision introduced the concept of quality by design (QbD), which requires a greater understanding of the raw material attributes, of process parameters, of their variability and their interactions. Microcrystalline cellulose (MCC) is one of the most important tableting excipients thanks to its outstandi…
Trabajo presentado en la 3rd European Conference on NanoFilms & Al-NanoFunc Final Conference (Microstructural and chemical characterization in the nano-scale), celebrada en sevilla del 7 al 11 de julio de 2014.
Proton conduction behaviors in oxides have theoretically been investigated in a first-principles manner, taking several proton-conducting oxides with various crystal structures as model systems. The local structures around proton sites and the migration mechanisms greatly depend on the types and connections of oxygen…
(Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 (BCZT) -xSm2O3 nanocomposite films with different molar ratio x were successfully de posited on SrRuO3-coated (001) SrTiO3 substrates by pulsed laser deposition. The strain state of nanocomposites is closely related to planar lattice mismatch between film and substrate, and vertical lattic…
Wide band electromagnetic (EM) scattering characteristics of randomly rough surface in the terahertz (THz)frequency range are investigated through the use of finite difference time domain(FDTD) algorithm. Then the scattering characteristics of double negative materials(DNM) randomly rough surface are investigated furt…
We present a new cathode structure that the field emission current can be modified. A triode structure of graphene cathode with nano-scale sharp folds with two plat electrodes at two sides is presented in which an internal electrical field can be applied across the graphene fold, which is serving as field emission tip…
Co-doped ZnO nanoparticles were fabricated by an electrodeposition method. The XPS results show Co ions have doped into the ZnO crystal lattices successfully. The as-grown sample has no ferromagnetism at room temperature. But after an ammine plasma treatment the room temperature ferromagnetism were detected on Co0.04Z…
This paper describes observed changes in the emission from a 100-tip Spindt cathode array operated at peak emission levels that produced Joule heating and temperatures sufficient to cause surface self-diffusion at the tips. This well-known thermal field forming effect can produce blunting or sharpening of the emitter…
In this paper, we present a novel electronically switchable metasurface that provides absorption and reflection modes depending on bias voltages of pin diodes. The metasurface is designed by a periodic split ring resonator loading the pin diode. When the pin diodes turn on, the metasurface is working as the absorber.…
Field emission properties of vertically grown Carbon Nanotubes (CNTs), Nanoflakes (CNFs), and mechanically exfoliated Highly Oriented Pyrolitic Graphite (ex-HOPG) has been investigated using digital Field Emission Microscopy (FEM), Current-Voltage (I–V), and Current-time (I-t) measurements. Prior to the field emission…