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Signature of multiple glassy states in micellar nanoparticle-polymer composites

A. K. Kandar、S. Srivastava、J. K. Basu 等 6 位作者2008-09-11arXiv

We present results of temperature dependent measurements of dynamics of micellar nanoparticle - polymer composites of fixed volume fraction and variable polymer chain grafting density. For nanoparticles with lower grafting density we observe dynamically arrested state at low temperatures corresponding to an attractive…

Materials ScienceSoft Condensed Matter

Hexagonal eutectic solidification patterns operating near a marginal stability point

Mikael Perrut、Silvère Akamatsu、Sabine Bottin-Rousseau 等 4 位作者2008-09-11arXiv

We study the long-time dynamics of hexagonal directional-solidification patterns in bulk samples of a transparent eutectic alloy using an optical method which permits real-time observation of the growth front. A slow dilatation of the patterns due to a slight curvature of the isotherms drives the system into a permane…

Materials Sciencenlin.PS

Surface-controlled dislocation multiplication in metal micropillars

Christopher R. Weinberger、Wei Cai2008-09-11Proceedings of the National Academy of Sciences

Understanding the plasticity and strength of crystalline materials in terms of the dynamics of microscopic defects has been a goal of materials research in the last 70 years. The size-dependent yield stress observed in recent experiments of submicrometer metallic pillars provides a unique opportunity to test our theor…

Microstructure and mechanical propertiesForce Microscopy Techniques and ApplicationsSurface and Thin Film Phenomena

Surface Electron Accumulation and the Charge Neutrality Level inIn2O3

P. D. C. King、T. D. Veal、David J. Payne 等 6 位作者2008-09-11Physical Review Letters

High-resolution x-ray photoemission spectroscopy, infrared reflectivity and Hall effect measurements, combined with surface space-charge calculations, are used to show that electron accumulation occurs at the surface of undoped single-crystalline In2O3. From a combination of measurements performed on undoped and heavi…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Uptake of H2 and CO2 by Graphene

Anupama Ghosh、K. S. Subrahmanyam、Katla Sai Krishna 等 7 位作者2008-09-11OpenAlex

Graphene samples prepared by the exfoliation of graphitic oxide and conversion of nanodiamond exhibit good hydrogen uptake at 1 atm, 77 K, the uptake going up to 1.7 wt %. The hydrogen uptake varies linearly with the surface area, and the extrapolated value of hydrogen uptake by single-layer graphene works out to be j…

Graphene research and applicationsHydrogen Storage and MaterialsBoron and Carbon Nanomaterials Research

A helix scaffold for the assembly of active protein kinases

Alexandr P. Kornev、Susan S. Taylor、Lynn F. Ten Eyck2008-09-11OpenAlex

Structures of set of serine-threonine and tyrosine kinases were investigated by the recently developed bioinformatics tool Local Spatial Patterns (LSP) alignment. We report a set of conserved motifs comprised mostly of hydrophobic residues. These residues are scattered throughout the protein sequence and thus were not…

Protein Structure and DynamicsBioinformatics and Genomic NetworksEnzyme Structure and Function

Noble Metal Nanocrystals: Plasmon Electron Transfer Photochemistry and Single-Molecule Raman Spectroscopy

Louis E. Brus2008-09-11OpenAlex

The excited electronic states of noble metal Au and Ag nanocrystals are very different than those of molecules. Ag and Au nanocrystal optical transitions (plasmons) in the visible can be so intense that they significantly modify the local electromagnetic field. Also, coherent elastic Rayleigh light scattering is stron…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Superconductivity at 22 K in Co-DopedBaFe2As2Crystals

Athena S. Sefat、Rongying Jin、Michael A. McGuire 等 6 位作者2008-09-11OpenAlex

Here we report bulk superconductivity in ${\mathrm{BaFe}}_{1.8}{\mathrm{Co}}_{0.2}{\mathrm{As}}_{2}$ single crystals below ${T}_{c}=22\text{ }\text{ }\mathrm{K}$, as demonstrated by resistivity, magnetic susceptibility, and specific heat data. Hall data indicate that the dominant carriers are electrons, as expected fr…

Corporate Taxation and AvoidanceIron-based superconductors researchIntellectual Capital and Performance Analysis

<title>Nanostructure of glasses: experimental evidence</title>

L. V. Maksimov、A. V. Anan’ev、V. N. Bogdanov 等 6 位作者2008-09-10Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Inorganic glass is material having nanoscaled physical and chemical inhomogeneities ad initio because glass inherits thermodynamic fluctuations of concentration, density and anisotropy of a glass forming melt. Combining light scattering and high temperature acoustics data allows to use the effect of internal immersion…

Glass properties and applicationsMineralogy and Gemology StudiesOptical and Acousto-Optic Technologies

Microstructure and Electrochemical Characterization of Sm 0.5 Sr 0.5 CoO 3 Films as SOFC Cathode Prepared by the Electrostatic‐Assisted Ultrasonic Spray Pyrolysis Method

Chun‐Liang Chang、Bing‐Hwai Hwang2008-09-10International Journal of Applied Ceramic Technology

Sm 0.5 Sr 0.5 CoO 3 cathode films for solid oxide fuel cells were deposited on Ce 0.9 Gd 0.1 O 1.95 disks using the electrostatic‐assisted spray pyrolysis method. While an increase of deposition temperature resulted in enhanced evaporation and diminished wetting of aerosol droplets on substrates and led to more porous…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Step‐like melting mechanisms of isothermally crystallized isotactic polypropylene

Francisco J. Medellín‐Rodríguez、Manuel Mata‐Padilla、S. Sánchez‐Valdés 等 5 位作者2008-09-10Journal of Polymer Science Part B Polymer Physics

Abstract The complex melting behavior of isotactic polypropylene, after isothermal crystallization, was studied within the context of step‐like melting mechanisms which were previously proposed for high temperature polymers. The morphological characteristics of the melting process were also studied as a function of mo…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Influence of polarity on the preferential intercalation behavior of clay in immiscible polypropylene/polystyrene blend

Yanqiu Zhu、Yuzhen Xu、Lifang Tong 等 5 位作者2008-09-10Journal of Applied Polymer Science

Abstract The immiscible polypropylene (PP)/polystyrene (PS) blend was prepared via melt compounding and the preferential intercalation behavior of clay was investigated by wide angle X‐ray diffraction (XRD) and transmission electron microscope (TEM). It was found that the clay platelets initially located in the PS pha…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Modeling of the propylene polymerization catalyzed by single‐/multi‐active site catalyst: A Monte Carlo study

Zheng‐Hong Luo、Wei Wang、Pei‐Lin Su2008-09-10Journal of Applied Polymer Science

Abstract In the present study, a model is established to describe the propylene polymerization kinetics catalyzed by the typical catalysts with single‐/multi‐active site type in a liquid phase stirred‐tank reactor using the Monte Carlo simulation method, regardless of the mass and heat diffusion effects within the pol…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

Load Flow in Plain Woven Composites

Deepak Kumar Goyal、John Whitcomb2008-09-10Journal of Composite Materials

The increase in computational power has made performing virtual experiments of various textile architectures using detailed three-dimensional finite element analyses practical. Interpretation of the results remains a challenge. The wealth of raw numerical information provided by the typical finite element analysis pro…

Mechanical Behavior of CompositesComposite Material MechanicsTextile materials and evaluations

Discovery of Polarization Flop Transition and Simultaneous Measurements of Magnetic Ordering and Dielectric Properties of TmMn2O5

Mamoru Fukunaga、Keisuke Nishihata、Hiroyuki Kimura 等 5 位作者2008-09-10Journal of the Physical Society of Japan

We have performed simultaneous measurements of magnetic neutron diffraction, ferroelectric D – E hysteresis loops and permittivity along the b - and a -axes of multiferroic TmMn 2 O 5 down to 2.5 K. It was confirmed that the permittivity peak coincides with an increase in both the polarization along the b -axis and a…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Influence of Roughness Surfaces on Third-Order Nonlinear-Optical Properties of Erbium-Doped Zinc Oxide Thin Films

M. Alaoui Lamrani、Mohamed El Jouad、M. Addou 等 12 位作者2008-09-10Spectroscopy Letters

Zinc oxide (ZnO) and erbium-doped zinc oxide (ZnO:Er) thin films were deposited on heated glass substrates using the spray pyrolysis technique. Third-order nonlinear-optical properties of the thin films have been investigated using the third harmonic generation (THG) at wavelength of 1064 nm in picosecond regime. The…

ZnO doping and propertiesNonlinear Optical Materials StudiesCopper-based nanomaterials and applications

Electrical Conductivity of Polypyrrole–Polymethylmethacrylate Composites Determined by Impedance Spectroscopy

M. E. Achour、A. Droussi、S. Zoulef 等 7 位作者2008-09-10Spectroscopy Letters

Thermal properties of polypyrrole–polymethylmethacrylate (PPy–PMMA) composites are analyzed by differential scanning calorimetry (DSC). A decrease in the glass transition temperature Tg with the PPy concentration content reveals the increase of segmental motion. The ac conductivity of these composites is studied in fr…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Can the hybrid meta GGA and DFT‐D methods describe the stacking interactions in conjugated polymers?

A. Dkhissi、Jean Marie Ducéré、Ralf Blossey 等 4 位作者2008-09-10Journal of Computational Chemistry

Newly developed hybrid meta density functionals and density functionals augmented by a classical London dispersion term have been systematically applied for the description of stacking energy and intermolecular distance of thiophene dimer and substituted thiophene dimer. The performance of the various approaches is co…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsOrganic and Molecular Conductors Research

Investigation on nonisothermal crystallization kinetics of the high‐flow nylon 6 by differential scanning calorimetry

Fan Zhang、Li Zhou、Yuanqin Xiong 等 4 位作者2008-09-10Journal of Polymer Science Part B Polymer Physics

Abstract The crystallization kinetics of the high‐flow nylon 6 containing polyamidoamine (PAMAM) dendrimers units in nylon 6 matrix was investigated by differential scanning calorimetry. The Ozawa and Mo equations were used to describe the crystallization kinetics under nonisothermal condition. The values of Avrami ex…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Quenching of the Quantum Hall Effect in Multilayered Epitaxial Graphene: The Role of Undoped Planes

Pierre Darancet、Nicolas Wipf、Claire Berger 等 5 位作者2008-09-10Physical Review Letters

We propose a mechanism for the quenching of the Shubnikov-de Haas oscillations and the quantum Hall effect observed in epitaxial graphene. Experimental data show that the scattering time of the conduction electron is magnetic field dependent and of the order of the cyclotron orbit period, i.e., it can be much smaller…

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures