Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Dynamic simulations of grade transitions are conducted for an industrial fluidized bed polyethylene reactor using a nickel−diimine catalyst. The reactor process model incorporates a kinetic model that predicts polymer properties for nickel−diimine ethylene polymerization. The relationships between reactor process vari…
This Letter reports experimental and numerical results on particle dynamics in an out-of-equilibrium granular medium. We observed two distinct types of grain motion: the well known cage motion, during which a grain is always surrounded by the same neighbors, and low probability "jumps," during which a grain moves sign…
Abstract Ultrasonically initiated miniemulsion polymerization of styrene was conducted in the presence of Fe 3 O 4 nanoparticles. Stable polystyrene (PS)/Fe 3 O 4 nanocomposite emulsions were prepared and magnetic PS/Fe 3 O 4 composite particles were obtained through magnetic separation. The whole procedure comprised…
The physical and biological properties of a water-soluble polymeric contrast agent based on a complex of N-(2-hydroxypropyl)methacrylamide copolymer with gadolinium (HE-24.8) were investigated, and its potential for experimental magnetic resonance (MR) angiography was assessed. Relaxivities of Gd-DTPA-BMA, Gd-DTPA-HSA…
The density anomaly of liquid Ge(0.15)Te(0.85) measured between 633 and 733 K is investigated with ab initio molecular dynamics calculations at four temperatures and at the corresponding experimental densities. For box sizes ranging from 56 to 112 atoms, an 8 k-points sampling of the Brillouin zone is necessary to obt…
Abstract Poly(ethylene glycol) (PEG) and end‐capped poly(ethylene glycol) (poly(ethylene glycol) dimethyl ether (PEGDME)) of number average molecular weight 1000 g mol −1 was melt blended with poly(ethylene terephthalate) (PET) oligomer. NMR, DSC and WAXS techniques characterized the structure and morphology of the bl…
This paper applies the density functional theory to confined liquid crystals comprising ellipsoidal shaped particles interacting through the hard Gaussian overlap (HGO) potential. The restricted orientation model proposed by Rickayzen [Mol. Phys. 95, 393 (1998)] is extended to study the surface anchoring. The excess f…
Abstract A new organic‐soluble aromatic polyimide with biphenyl side‐groups has been synthesized from 4,4′‐oxydiphthalic anhydride and 3,5‐diamino‐benzonic‐4′‐biphenyl ester (DABBE) via a one‐step polymerization in m ‐cresol. A higher molecular weight polyimide has been obtained by the addition of chlorotrimethylsilan…
The first derivative of a new class of perylene bisimide chromophores, N,N'-bis(octyl)-3,9-bis(phenyl)perylene-1,2,7,8-tetracarboxyl bisimide, 1, has been synthesized and its fundamental photophysical and electrochemical properties assessed. The extended, Z-shaped structure was achieved by use of the classic photoenol…
Electrical conductivity measurements were performed on structurally anisotropic thin films deposited using the glancing angle deposition apparatus [K. Robbie and M. J. Brett, J. Vac. Sci. Technol. A 15, 1460 (1997); K. Robbie, J. Sit, and M. J. Brett, J. Vac. Sci. Technol. B 16, 1115 (1998); K. Robbie and M. J. Brett,…
Abstract Poly(ethylene terephthalate) (PET) based blends were obtained by melt blending PET with up to 30 wt% poly(ethylene‐octene) either modified with maleic anhydride (mLLDPE) or not (LLDPE). Both PET/LLDPE and PET/mLLDPE blends were immiscible. The dispersed phase particle size was large in LLDPE blends, but upon…
Abstract Poly(vinyl chloride) (PVC)/organophilic‐montmorillonite (OMMT) nanocomposites were prepared by direct melt intercalation. PVC/compatibilizer ((vinyl acetate) copolymer (VAc))/OMMT nanocomposites were also prepared by melt intercalation by a masterbatch process. The effect of OMMT content on the nanostructures…
Highly ordered arrays of parallel CoS2 nanowires with a diameter of about 50 nm and a length up to about 50μm were synthesized by two electrical fields in an anodized aluminum oxide film. In this letter, fabrication, structure, magnetic properties of highly ordered magnetic cobalt disulfide nanowires arrays were studi…
The 1 : 3 Schiff base condensates of tris(2-aminoethyl)amine (tren) or tris(3-aminopropyl)amine (trpn) with 4-methyl-5-imidazolecarboxaldehyde, H3L1 and H3L2, respectively, were generated in situ and used to prepare complexes with manganese(II) and iron(III). The resultant complexes, [MnH3L1](ClO4)2, [MnH3L1](ClO4)2.E…
The syntheses, structural characterization, and magnetic behavior of five new 2D manganese(II) complexes with empirical formulas [Mn(N(3))(2)(2,6-DiMepyz)(H(2)O)](n)() (1), [Mn(N(3))(2)(Etpyz)(H(2)O)](n)() (2), [Mn(N(3))(2)(H(2)O)(2)](n)()(2,3-DiMepyz)(n)() (3), [Mn(N(3))(2)(Clpyz)(2)](n)() (4), and [Mn(N(3))(2)(Ipyz)…
Abstract Poly(methyl methacrylate) membranes have been prepared using a supercritical fluid‐phase inversion process in which CO 2 acts as the nonsolvent. Series of experiments were performed at various polymer concentrations, temperatures, and pressures using three different solvents, dimethylsulfoxide, acetone, and t…
Abstract In this article, Fe‐montmorillonite (Fe‐MMT) was synthesized by hydrothermal method. For the first time, Fe‐MMT was modified by cetyltrimethyl ammonium bromide (CTAB), and poly(methyl methacrylate)(PMMA)/Fe‐MMT nanocomposites were synthesized by emulsion polymerization. Then poly(methyl methacrylate)(PMMA)/na…
The structure of the technologically important hydrogen storage compound NaBH4 has been investigated under pressures up to 30 GPa by in situ angle dispersive high pressure x-ray diffraction using synchrotron x rays and a diamond anvil cell. Our experimental results show pressure-induced structural transitions of α-NaB…
Amide-linked spiropyran-anthraquinone (SP-AQ) conjugates were shown to mediate ZnTPPS(4-)-photosensitized transmembrane reduction of occluded Co(bpy)3(3+) within unilamellar phosphatidylcholine vesicles by external EDTA. Overall quantum yields for these reactions were dependent upon the isomeric state of the dye; spec…
Abstract Nickel–zinc ferrite monodisperse nanoparticles are synthesized by forced hydrolysis in diethylenglycol. FC and ZFC susceptibility curves suggest that they present superparmagnetic behaviour with a blocking temperature between 63 and 15 K depending on the zinc content. The saturation magnetization of the nanoc…