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Anomalous phase separation behavior in dynamically asymmetric LCST polymer blends

Jafar Khademzadeh Yeganeh、Fatemeh Goharpey、Reza Foudazi2014-01-01RSC Advances

The interplay of thermodynamic forces and self-generated stresses induced in different compositions, and at different quench depths on the phase behavior of dynamically asymmetric PS/PVME blends are studied. The thermodynamic phase diagram is obtained from dynamic temperature sweep experiments. Phase contrast optical…

Polymer crystallization and propertiesPolymer composites and self-healingBlock Copolymer Self-Assembly

The Effect of Copper Addition on the Mechanical and Wear Properties of Grey Cast Iron

Johnson Olumuyiwa Agunsoye、Sefiu Adekunle Bello、Suhaimi Hassan 等 5 位作者2014-01-01Journal of Minerals and Materials Characterization and Engineering

An alloy of cast iron and copper (Fe-Cu) has been developed using a stir cast process. The compositional, microstructural characterization and wear property of the developed Fe-Cu alloy were carried out with the aids of X-ray diffractometer, scanning electron microscope (SEM) and pin on Disc machine. The mechanical pr…

Aluminum Alloys Composites PropertiesTribology and Wear AnalysisMetal Alloys Wear and Properties

Hydrogen Effect on Fatigue Behavior of a Quenched&tempered Steel

L. Vergani、Chiara Colombo、Giorgia Gobbi 等 5 位作者2014-01-01Procedia Engineering

The investigated material is a quenched&tempered steel for hydrogen applications. Understanding of hydrogen embrittlement and its effect on the mechanical characteristics of steel becomes fundamental. It is, in fact, well known that the atomic hydrogen can cause embrittlement and degradation of the mechanical characte…

Corrosion Behavior and InhibitionFatigue and fracture mechanicsHydrogen embrittlement and corrosion behaviors in metals

Fluorescence enhancement detection of uric acid based on water-soluble 3-mercaptopropionic acid-capped core/shell ZnS:Cu/ZnS

Meihua Wang、Weifen Niu、Xin Wu 等 7 位作者2014-01-01RSC Advances

A simple core/shell ZnS:Cu/ZnS QD based fluorescence enhancement system is constructed for detecting uric acid. The method with high sensitivity, selectivity and lower toxicity features was applied for determination of UA in real samples.

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsQuantum Dots Synthesis And Properties

An Optimization-based Atomistic-to-Continuum Coupling Method

Derek Olson、Pavel Bochev、Mitchell Luskin 等 4 位作者2014-01-01SIAM Journal on Numerical Analysis

We present a new optimization-based method for atomistic-to-continuum (AtC) coupling. The main idea is to cast the latter as a constrained optimization problem with virtual Dirichlet controls on the interfaces between the atomistic and continuum subdomains. The optimization objective is to minimize the error between t…

Microstructure and mechanical propertiesForce Microscopy Techniques and ApplicationsComposite Material Mechanics

Visible and near-infrared luminescent mesoporous titania microspheres functionalized with lanthanide complexes: microstructure and luminescence with visible excitation

Lining Sun、Zhijuan Wang、Jin Z. Zhang 等 7 位作者2014-01-01RSC Advances

A new type of monodisperse mesoporous titania microspheres possessing visible (Eu3+, Sm3+) and near-infrared (Sm3+, Yb3+, Nd3+) luminescence were synthesized with covalent linking to Ln(dbm)3bpdc complexes (Ln = Eu, Sm, Yb, Nd, dbm = dibenzoylmethanate, bpdc = 2,2′-bipyridine-4,4′-dicarboxylic acid). These lanthanide…

Luminescence Properties of Advanced MaterialsLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications

Simultaneous and multisite tumor rapid-target bioimaging through in vivo biosynthesis of fluorescent gold nanoclusters

Jian-Ling Wang、Jing Ye、Hui Jiang 等 9 位作者2014-01-01RSC Advances

In vivo simultaneous and multisite tumor rapid-targeting through specifically biosynthesized gold nanoclusters could be readily followed and monitored by real-time fluorescence imaging.

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

The investigation of corrosion behavior of borided AISI 304 austenitic stainless steel with nanoboron powder

Ali Günen、Bülent Kurt、Nuri Orhan 等 4 位作者2014-01-01Protection of Metals and Physical Chemistry of Surfaces

In this study, corrosion behavior and mechanical properties of AISI 304 austenitic stainless steel, which was borided with Nanoboron powder, was investigated. The commercially available steel was subjected to a boriding treatment with a size of 10–50 nm Nanoboron powders, at the temperatures of 1223 K to 1273 K with b…

Metal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metalsMetal Alloys Wear and Properties

Co-precipitation Synthesis, Structural and Luminescent Behavior of Erbium Doped Gadolinium Oxide (Er 3+ :Gd 2 O 3 ) Nanorods

G. Boopathi、S. Gokul Raj、G. Ramesh Kumar 等 4 位作者2014-01-01Procedia Materials Science

Well–defined and nearly monodisperse one–dimensional (1D) Er3+:Gd2O3 were successfully synthesized through co– precipitation technique followed by a subsequent heat treatment process, without using any kind of organic capping regent, fuel, surfactant, membrane, template or catalyst. Ammonium hydroxide alkali solution…

Luminescence Properties of Advanced MaterialsCarbon and Quantum Dots ApplicationsMicrowave Dielectric Ceramics Synthesis

Optimization of electrospinning process of poly(vinyl alcohol) via response surface methodology (RSM) based on the central composite design

Mina Yazdanpanah、Mohammadreza Khanmohammadi、Ruhollah Mehdinavaz Aghdam 等 5 位作者2014-01-01Current Chemistry Letters

Evaluating the capability of electrospinning method as an efficient versatile approach for fabrication of fibers, a central composite design (CCD) model was used to design an experimental program for investigation of effective in production of poly (vinyl alcohol) (PVA) fibers fabricated from aqueous solutions of PVA.…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Experimental Investigation of Micro-sized Aluminium Oxide Reinforced Epoxy Composites for Microelectronic Applications

Alok Agrawal、Alok Satapathy2014-01-01Procedia Materials Science

The present work aims at developing a class of particulate filled polymer composites consisting of epoxy as base matrix reinforced with micro-sized aluminium oxide (Al2O3) particles. A set of composites, with Al2O3 content ranging from 0 to 25 vol% have been fabricated by hand lay-up technique. Density (ρc), effective…

Epoxy Resin Curing ProcessesThermal properties of materialsDielectric materials and actuators

The roles of surface structure, oxygen defects, and hydration in the adsorption of CO 2 on low-index ZnGa 2 O 4 surfaces: a first-principles investigation

Chuanyi Jia、Weiliu Fan、Xiufeng Cheng 等 7 位作者2014-01-01Physical Chemistry Chemical Physics

The effects of the surface atomic and electronic structures, oxygen defects, and hydration on CO2 adsorption on ZnGa2O4(100), (110), and (111) surfaces were studied using density functional theory (DFT) slab calculations. For the perfect (100) surface, the most stable adsorption state involved the Zn-O-Ga bridge site,…

ZnO doping and propertiesCatalytic Processes in Materials ScienceGa2O3 and related materials

Poly(ethylene glycol)-block-poly(4-vinyl pyridine) as a versatile block copolymer to prepare nanoaggregates of superparamagnetic iron oxide nanoparticles

Nuno Rocha、Joana P. Mendes、Luísa Durães 等 8 位作者2014-01-01Journal of Materials Chemistry B

This work reports an efficient method for the preparation of aqueous dispersions of superparamagnetic iron oxide nanoparticles (SPIONs), involving the use of an amphiphilic block copolymer, poly(ethylene glycol)-block-poly(4-vinyl pyridine) (mPEG-b-P4VP). The iron oxide nanoparticles are easily and efficiently dispers…

Nanoparticle-Based Drug DeliveryBlock Copolymer Self-AssemblyCharacterization and Applications of Magnetic Nanoparticles

Nitrogen-doped carbon supports with terminated hydrogen and their effects on active gold species: a density functional study

Junjie Gu、Qian Du、You Han 等 6 位作者2014-01-01Physical Chemistry Chemical Physics

In order to disclose the reason that the N-doped carbon support can enhance the stability of Au-based catalysts for acetylene hydrochlorination, we established a big graphene cluster model of C110H28 to investigate the effect of different nitrogen-doped carbon supports on three kinds of gold species models of Au dimer…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceCarbon and Quantum Dots Applications

Self-organizing microfluidic crystals

William E. Uspal、Patrick S. Doyle2014-01-01Soft Matter

We consider how to design a microfluidic system in which suspended particles spontaneously order into flowing crystals when driven by external pressure. Via theory and numerics, we find that particle-particle hydrodynamic interactions drive self-organization under suitable conditions of particle morphology and geometr…

Material Dynamics and PropertiesMicro and Nano RoboticsPickering emulsions and particle stabilization

Controlled design and construction of multifunctional nanoparticles by molecular self-assembly

Nisaraporn Suthiwangcharoen、R. Nagarajan2014-01-01RSC Advances

Controlled design of nanoparticles (NPs) displaying multiple functionalities is of great interest to many applications such as targeted drug or gene delivery, diagnostic imaging, cancer theranostics, delivery of protein therapeutics, sensing chemical and biomolecular analytes in complex environments, and design of fut…

Nanoparticle-Based Drug DeliveryAdvanced Polymer Synthesis and CharacterizationDendrimers and Hyperbranched Polymers

Two-color emissive probes for click reactions

Marcel Wirtz、Andreas Grüter、Philipp Rebmann 等 7 位作者2014-01-01Chemical Communications

Cu(I)-catalyzed azide-alkyne cyclization (CuAAC) is the paradigmatic click reaction of continuous interest. Especially fluorogenic and FRET probes have become indispensable tools for life sciences. Here, we present a fluorescent alkyne for monitoring CuAAC, which undergoes a bathochromic shift upon reaction. Applicati…

Advanced biosensing and bioanalysis techniquesLuminescence and Fluorescent MaterialsClick Chemistry and Applications

A new 3D framework based on reduced Wells-Dawson arsenotungstates as eight-connected linkages

Wenlong Sun、Shaobin Li、Huiyuan Ma 等 6 位作者2014-01-01RSC Advances

A compound representing the first example of high dimensional and high connected hybrid based on reduced Wells-Dawson arsenotungstates has been synthesized, and its electrocatalytic and photocatalytic properties have been investigated.

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions