Materials Literature
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A general methodology has been devised and implemented into the solid-state ab initio quantum-mechanical Crystal program for studying the evolution under geophysical pressure of the elastic anisotropy of crystalline materials. This scheme, which fully exploits both translational and point symmetry of the crystal, is d…
The electronic and ionic transports in 32–56 nm thick anodic aluminum oxide films are investigated before and after a 1-h anneal at 200–400 °C in argon. Results are correlated to their defect density as measured by the Mott-Schottky technique. Solid state measurements show that electronic conduction upon annealing is…
Phosphatidylcholine (PC) is a rare membrane lipid in bacteria, but is crucial for virulence of the plant pathogen Agrobacterium tumefaciens and various other pathogens. Agrobacterium tumefaciens uses two independent PC biosynthesis pathways. One is dependent on the integral membrane protein PC synthase (Pcs), which ca…
Curcumin is a naturally occurring compound that has been shown to have anti-oxidant, anti-inflammatory, and anti-carcinogenic activities. However, its pharmaceutical potential has been limited due to its low solubility in water. The use of amphiphilic nanocarriers is an attractive and simple method to solubilize curcu…
For many years, cisplatin has been used to treat many types of cancer, including urogenital, skin and lung cancers. Unfortunately, treatment with this drug causes serious side effects, such as severe toxicity; including nephrotoxicity, neurotoxicity, gastrointestinal toxicity, peripheral neuropathy, ototoxicity, asthe…
Fabry-Pérot (FP) modes of a dielectric cavity with a planar distribution of metal nanoparticles at one end have been studied numerically. An unusual enhancement in the strength of FP modes is observed close to the strong localized surface plasmon resonance of the metal nanoparticles. Experimental evidence for the nume…
Polarized Raman scattering measurements on $\mathrm{Ir}{\mathrm{Te}}_{2}$ single crystals carried out over the 15--640 K temperature range, and across the structural phase transition, reveal different insights regarding the crystal symmetry. In the high temperature regime three Raman active modes are observed at all o…
Replacing liquid-state electrolytes with solid-state electrolytes has been proven to be an effective way to improve the durability of dye-sensitized solar cells (DSSCs). We report herein the synthesis of amorphous ionic conductors based on polyhedral oligomeric silsesquioxane (POSS) with low glass transition temperatu…
We investigate the dependence on the applied field of the frequency/wavevector dispersion relations of collective spin waves in arrays of dots, close to a magnetic transition. In particular, we focus on the low frequency “soft” modes in three different cases: end modes in the transition between two different saturated…
Small changes to the reaction conditions differentiate between two metal–organic frameworks (MOFs), {[Ce 2 (H 2 O)(bpdc) 3 (dmf) 2 ]·2(dmf)} n ( 1 ) and {[Ce 4 (H 2 O) 5 (bpdc) 6 (dmf)]· x (dmf)} n ( 2 ), that were solvothermally synthesized from cerium(III) nitrate hexahydrate and 2,2′-bipyridine-5,5′-dicarboxylic ac…
Quantum dot-decorated wide band gap semiconductors, such as TiO2, ZnO, SnO2, etc., which have electron mobilities of less than 200 cm2 V−1 S−1 have been well studied as the photoelectrodes for photovoltaics and photoelectrochemical water splitting. Herein, we report CdSe quantum dot decorated-silicon nanowires (SiNWs)…
We use pump–probe thermal transport measurements and high speed imaging to study the residence time and heat transfer of small (360 μm diameter) water droplets that bounce from hydrophobic surfaces whose temperature exceeds the boiling point. The structure of the hydrophobic surface is a 10 nm thick fluorocarbon coati…
An analytical solution is constructed for the homogenized (i.e., macroscopic) dielectric response of particulate composites comprising a random distribution of particles bonded to a matrix material through interphases of finite size that contain space charges. By accounting for interphasial charges, the solution is ab…
Calcium impregnation is used as a pretreatment in the processing of papaya in syrup. The effect of process temperature (30 and 45°C), calcium source (calcium gluconate and calcium lactate), calcium concentration (0.5 and 1.5% w/w), and pH (4.2 and 6) were studied. The mineral source affected significantly the calcium…
A mechanism of ageing and breakdown of thin insulating polymer films in an electric field is described. Ageing and breakdown are attributed to the field ionization of macromolecules which is regarded as a self-accelerating process that takes place during the entire electric lifetime and results in an abrupt current in…
An experimental procedure for qualifying material properties from cyclically worked parts was investigated in support of aging gas turbine engines and digital twin initiatives. For aging components, remanufacturing or repair efforts are necessary to sustain the life cycles of engines; and for digital twin, the virtual…
Over the last decade, numerous removal methods using solid-supported magnetic nanocomposites have been employed in order to remove arsenic from aqueous solution. In this report, removal of arsenic from aqueous solution by an organo silica, namely, magnetic mobile crystalline material-41 (MCM-41) functionalized by chlo…
Peptidergic neurons are a group of neuronal cells that synthesize and secrete peptides to regulate a variety of biological processes. To identify genes controlling the development and function of peptidergic neurons, we conducted a screen of 545 splice-trap lines and identified 28 loci that drove expression in peptide…
We report a simple optical technique to measure time-resolved nanoscale surface profile of an evaporating sessile fluid droplet. By analyzing the high contrast Newton-ring like dynamical fringes formed by interfering Fresnel reflections, we demonstrated λ/100 ≈ 5 nm sensitivity in surface height (at 0.01–160 nm/s rate…
Water, ethylene glycol and engine oil are commonly used in heat exchanger applications. However, these fluids possess low thermal conductivity. The technology advancement in nanotechnology has enabled nano size particles to be included in a base fluid. This new generation of fluids is known as nanofluids. Producing a…