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Experimental discussion on the mechanisms behind the fire spalling of concrete

Jean‐Christophe Mindeguia、Hélène Carré、Pierre Pimienta 等 4 位作者2014-06-16Fire and Materials

Summary The behaviour of six concretes at high temperature (600 °C) and in particular the risk of fire spalling is studied. Tests are performed with two sizes of samples: small samples (300 × 300 × 120 mm3) and small slabs (700 × 600 × 150 mm3). Different storage conditions (pre‐drying at 80 °C, air and water storing)…

Fire dynamics and safety researchFire effects on concrete materialsEngineering and Material Science Research

A hydrogen peroxide electrochemical sensor based on silver nanoparticles decorated three-dimensional graphene

Beibei Zhan、Changbing Liu、Huaxia Shi 等 7 位作者2014-06-16Applied Physics Letters

A facile strategy has been developed to synthesize sliver nanoparticles (Ag NPs) decorated three-dimensional graphene (3DG) through hydrothermal process. The AgNPs-3DG composites are directly fabricated into a free standing sensing electrode for electrochemical detection of hydrogen peroxide (H2O2) in phosphate buffer…

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsAdvanced Nanomaterials in Catalysis

Nanoparticle-Delivered Quercetin for Cancer Therapy

Ke Men、Xingmei Duan、Xia Wei 等 8 位作者2014-06-16Anti-Cancer Agents in Medicinal Chemistry

Quercetin, a natural protective bioflavonoid, possesses diverse pharmacologic effects, such as antioxidant, anti-inflammatory, anti-proliferative, and anti-angiogenic activities. Recently, quercetin's effect in cancer prevention and treatment was recognized. However, the poor water solubility and low-bioavailability o…

Nanoparticle-Based Drug DeliveryCurcumin's Biomedical ApplicationsTannin, Tannase and Anticancer Activities

A Unified Picture of Adsorption on Transition Metals through Different Atoms

M. M. Montemore、J. Will Medlin2014-06-16Journal of the American Chemical Society

A key issue in catalyst design is understanding how adsorption energies of surface intermediates vary across both different surfaces and various types of adsorbing atoms. In this work, we examine trends in adsorption energies of a wide variety of adsorbates that attach to transition metal surfaces through different at…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceMolecular Junctions and Nanostructures

High modulus steels: new requirement of automotive market. How to take up challenge?

Frédéric Bonnet、V. Daeschler、G. Petitgand2014-06-16Canadian Metallurgical Quarterly

Since the last decade, lightening of automotive structure was mainly achieved by gauge reduction using ultrahigh strength steels such as dual phase and transformation induced plasticity grades. However, gauge reduction can significantly reduce the stiffness. Limits are today reached for some applications such as chass…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesMetal Alloys Wear and Properties

Recent developments in gold( i ) coordination chemistry: luminescence properties and bioimaging opportunities

Emily E. Langdon‐Jones、Simon J. A. Pope2014-06-16Chemical Communications

The fascinating biological activity of gold coordination compounds has led to the development of a wide range of complexes. The precise biological action of such species is often poorly understood and the ability to map gold distribution in cellular environments is key. This article discusses the recent progress in lu…

Metal complexes synthesis and propertiesMagnetism in coordination complexesNanocluster Synthesis and Applications

Temperature dependent spin transport properties of platinum inferred from spin Hall magnetoresistance measurements

Sibylle Meyer、Matthias Althammer、Stephan Geprägs 等 6 位作者2014-06-16Applied Physics Letters

We study the temperature dependence of the spin Hall magnetoresistance (SMR) in yttrium iron garnet/platinum hybrid structures via magnetization orientation dependent magnetoresistance measurements. Our experiments show a decrease of the SMR magnitude with decreasing temperature. Using the sensitivity of the SMR to th…

Magnetic properties of thin filmsQuantum and electron transport phenomenaChemical and Physical Properties of Materials

Does Campylobacter jejuni Form Biofilms in Food-Related Environments?

Amy Huei Teen Teh、Sui Mae Lee、Gary A. Dykes2014-06-16Applied and Environmental Microbiology

Campylobacter jejuni is one of the most frequent causes of bacterial gastrointestinal food-borne infection worldwide. This species is part of the normal flora of the gastrointestinal tracts of animals used for food production, including poultry, which is regarded as the primary source of human Campylobacter infections…

Corrosion Behavior and InhibitionSalmonella and Campylobacter epidemiologyBacterial biofilms and quorum sensing

Tar Conversion and Vapor Upgrading via in Situ Catalysis Using Silica-Based Nickel Nanoparticles Embedded in Rice Husk Char for Biomass Pyrolysis/Gasification

Yafei Shen、Kunio Yoshikawa2014-06-16Industrial & Engineering Chemistry Research

This paper proposes two simple approaches for in situ generation of nickel nanoparticles in the carbon matrix of rice husk char (RHC) via incipient wetness impregnation and pyrolysis. The nickel oxides (i.e., NiO) in the RHC matrix can be preliminarily in situ reduced into metallic nickel (Ni 0 ) by carbothermal reduc…

Thermochemical Biomass Conversion ProcessesSupercapacitor Materials and FabricationLignin and Wood Chemistry

Extremely High Yield Conversion from Low‐Cost Sand to High‐Capacity Si Electrodes for Li‐Ion Batteries

Jung‐Keun Yoo、Jongsoon Kim、Min‐Jae Choi 等 8 位作者2014-06-16Advanced Energy Materials

Although magnesiothermic reduction has attracted immense attention as a facile route for the fabrication of mass‐scale Si nanostructures for high‐capacity lithium‐ion battery applications, its low conversion yield (<50%) and the discovery of a sustainable and low‐cost precursor remain challenging. Here, an unprecedent…

Advancements in Battery MaterialsGraphene research and applicationsSemiconductor materials and devices

The structural landscape of heteroaryl-2-imidazoles: competing halogen- and hydrogen-bond interactions

Christer B. Aakeröy、Tharanga K. Wijethunga、Mohammad Abul Haj 等 5 位作者2014-06-16CrystEngComm

In order to examine the competition between hydrogen bonds and halogen bonds when confronted with a probe molecule containing multiple potential acceptor sites and one hydrogen-bond donor, five heteroaryl-2-imidazoles were synthesized and subsequently co-crystallized with fifteen different halogen-bond donors. 30 of t…

Crystal structures of chemical compoundsCrystallography and molecular interactionsCrystallization and Solubility Studies

Thiophene Fused Azacoronenes: Regioselective Synthesis, Self-Organization, Charge Transport and Its Incorporation in Conjugated Polymers

Bo He、Andrew B. Pun、Liana M. Klivansky 等 9 位作者2014-06-16Chemistry of Materials

A regioselective synthesis of an azacoronene fused with two peripheral thiophene groups has been realized through a concise synthetic route. The resulting thienoazacoronene (TAC) derivatives show high degree of self-organization in solution, in single crystals, in the bulk, and in spuncast thin films. Spuncast thin fi…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Native extracellular matrix: a new scaffolding platform for repair of damaged muscle

Laura Teodori、Alessandra Costa、R. Marzio 等 8 位作者2014-06-16Frontiers in Physiology

Effective clinical treatments for volumetric muscle loss resulting from traumatic injury or resection of a large amount of muscle mass are not available to date. Tissue engineering may represent an alternative treatment approach. Decellularization of tissues and whole organs is a recently introduced platform technolog…

Electrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Assessing the quantum mechanical level of theory for prediction of UV/Visible absorption spectra of some aminoazobenzene dyes

Asif Mahmood、Salah Ud‐Din Khan、Fazal Rehman2014-06-16Journal of Saudi Chemical Society

This quantum mechanical study was performed to assess the accuracy of level of theory for the prediction of UV/Visible spectra of aminoazobenzene dyes. Four solvation models (PCM, I-PCM, SCI-PCM and IEF-PCM) and four functionals (CAM-B3LYP, LC-BLYP, BHandHLYP and PBE0) were tested. Double and triple zeta basis sets wi…

Computational Drug Discovery MethodsPhotochromic and Fluorescence ChemistryFree Radicals and Antioxidants

Benzocyclobutene barrier layer for suppressing conductance in nonlinear optical devices during electric field poling

Wenwei Jin、Peter V. Johnston、Delwin L. Elder 等 10 位作者2014-06-16Applied Physics Letters

We measured the electro-optic (EO) coefficients (r33) of thin-film devices made from several monolithic, high number density organic EO chromophores with and without additional charge barrier layers. We found that a cross-linkable benzocyclobutene layer was very effective in suppressing unwanted, leakage current, keep…

Photonic and Optical DevicesMolecular Junctions and NanostructuresNonlinear Optical Materials Research

Ferroelectricity in wurtzite structure simple chalcogenide

Hiroki Moriwake、Ayako Konishi、T. Ogawa 等 9 位作者2014-06-16Applied Physics Letters

The possibility of the new class ferroelectric materials of wurtzite structure simple chalcogenide was discussed using modern first-principles calculation technique. Ferroelectricity in the wurtzite structure (P63mc) can be understood by structure distortion from centrosymmetric P63/mmc by relative displacement of cat…

Acoustic Wave Resonator TechnologiesPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Giant Thermoelectric Effect in Graphene-Based Topological Insulators with Heavy Adatoms and Nanopores

Po-Hao Chang、Mohammad Saeed Bahramy、Naoto Nagaosa 等 4 位作者2014-06-16Nano Letters

Designing thermoelectric materials with high figure of merit ZT = S(2)GT/Ktot requires fulfilling three often irreconcilable conditions, that is, the high electrical conductance G, small thermal conductance Ktot, and high Seebeck coefficient S. Nanostructuring is one of the promising ways to achieve this goal as it ca…

Advanced Thermoelectric Materials and DevicesTopological Materials and PhenomenaThermal properties of materials

Using Information from Historical High-Throughput Screens to Predict Active Compounds

Sereina Riniker、Yuan Wang、Jeremy L. Jenkins 等 4 位作者2014-06-16Journal of Chemical Information and Modeling

Modern high-throughput screening (HTS) is a well-established approach for hit finding in drug discovery that is routinely employed in the pharmaceutical industry to screen more than a million compounds within a few weeks. However, as the industry shifts to more disease-relevant but more complex phenotypic screens, the…

Computational Drug Discovery MethodsMachine Learning in Materials ScienceCell Image Analysis Techniques

Accurate and reproducible detection of proteins in water using an extended-gate type organic transistor biosensor

Tsukuru Minamiki、Tsuyoshi Minami、Ryoji Kurita 等 8 位作者2014-06-16Applied Physics Letters

In this Letter, we describe an accurate antibody detection method using a fabricated extended-gate type organic field-effect-transistor (OFET), which can be operated at below 3 V. The protein-sensing portion of the designed device is the gate electrode functionalized with streptavidin. Streptavidin possesses high mole…

Conducting polymers and applicationsMolecular Junctions and NanostructuresAnalytical Chemistry and Sensors

A practical study of the aerodynamic impact of wind turbine blade leading edge erosion

Nicholas Gaudern2014-06-16Journal of Physics Conference Series

During operation wind turbine blades are exposed to a wide variety of atmospheric and environmental conditions; inspection reports for blades that have been operating for several years show varying degrees of leading edge erosion. It is important to be able to estimate the impact of different stages of erosion on wind…

Surface Modification and SuperhydrophobicityWind Energy Research and DevelopmentIcing and De-icing Technologies