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Osmotically Driven Formation of Double Emulsions Stabilized by Amphiphilic Block Copolymers

Jinhye Bae、Thomas P. Russell、Ryan C. Hayward2014-06-16Angewandte Chemie International Edition

Double emulsions are valuable for the formation of multi-compartmental structures. A variety of pathways to prepare double emulsions have been developed, but high-throughput routes to droplets of controlled size and architecture remain scarce. A new single-step process is introduced for preparation of water-in-oil-in-…

Innovative Microfluidic and Catalytic Techniques InnovationBlock Copolymer Self-AssemblyPickering emulsions and particle stabilization

Organic Field Effect Transistors Based on Graphene and Hexagonal Boron Nitride Heterostructures

Seok Ju Kang、Gwan‐Hyoung Lee、Young‐Jun Yu 等 10 位作者2014-06-16Advanced Functional Materials

Enhancing the device performance of single crystal organic field effect transistors (OFETs) requires both optimized engineering of efficient injection of the carriers through the contact and improvement of the dielectric interface for reduction of traps and scattering centers. Since the accumulation and flow of charge…

Organic Electronics and PhotovoltaicsGraphene research and applicationsLuminescence and Fluorescent Materials

Low-Temperature Stress Corrosion Cracking of Austenitic and Duplex Stainless Steels Under Chloride Deposits

Tomáš Prošek、Anne Le Gac、Dominique Thierry 等 12 位作者2014-06-16CORROSION

Corrosion performance of austenitic-ferritic (duplex) stainless steels UNS S32101, S32202, S32304, and S32205 and austenitic stainless steels UNS S30403 and S31603 was studied in the presence of chloride deposits simulating non-rinsing atmospheric conditions. The effect of temperature, relative humidity, concentration…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsMaterial Properties and Failure Mechanisms

Correlation between thermal hysteresis width and broadening of metal–insulator transition in Cr- and Nb-doped VO2films

K. Miyazaki、Keisuke Shibuya、Megumi Suzuki 等 5 位作者2014-06-16Japanese Journal of Applied Physics

Correlation between thermal hysteresis width and broadening of metal–insulator transition in Cr- and Nb-doped VO2 films, Miyazaki, Kenichi, Shibuya, Keisuke, Suzuki, Megumi, Wado, Hiroyuki, Sawa, Akihito

ZnO doping and propertiesTransition Metal Oxide NanomaterialsGa2O3 and related materials

Latex Clearing Protein—an Oxygenase Cleaving Poly( cis -1,4-Isoprene) Rubber at the cis Double Bonds

Sebastian Hiessl、Dietrich Böse、Sylvia Oetermann 等 6 位作者2014-06-16Applied and Environmental Microbiology

Gordonia polyisoprenivorans strain VH2, a potent rubber-degrading actinomycete, harbors two latex clearing proteins (Lcps), which are known to be essential for the microbial degradation of rubber. However, biochemical information on the exact role of this protein in the degradation of polyisoprene was lacking. In this…

Corrosion Behavior and Inhibitionbiodegradable polymer synthesis and propertiesSynthetic Organic Chemistry Methods

Fully Biobased Unsaturated Aliphatic Polyesters from Renewable Resources: Enzymatic Synthesis, Characterization, and Properties

Yi Jiang、Gert O. R. Alberda van Ekenstein、Albert J. J. Woortman 等 4 位作者2014-06-16Macromolecular Chemistry and Physics

Fully biobased saturated and unsaturated aliphatic polyesters and oligoesters are successfully prepared by Candida antarctica lipase B (CALB)‐catalyzed polycondensations of succinate, itaconate, and 1,4‐butanediol. The effects of monomer substrates and polymerization methods on enzymatic polycondensation are investiga…

biodegradable polymer synthesis and propertiesCatalysis for Biomass ConversionCarbon dioxide utilization in catalysis

A Critical Appraisal of the Interpretation of Electrochemical Noise for Corrosion Studies

A.M. Homborg、Tiedo Tinga、E.P.M. van Westing 等 7 位作者2014-06-16CORROSION

In this paper, procedures and parameters that enable identification of, or discrimination between, general and localized corrosion processes through electrochemical noise are critically discussed. Their relevant similarities, differences, and interdependences are indicated. In addition, the relation between different…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsStructural Integrity and Reliability Analysis

Theory and Methodology for Determining Nanoparticle Affinity for Heteroaggregation in Environmental Matrices Using Batch Measurements

Lauren E. Barton、Mathieu Thérézien、Mélanie Auffan 等 5 位作者2014-06-16Environmental Engineering Science

In this study, we present a method for determining the relative affinity of nanoparticles (NPs) for an ensemble of other particles in a complex, heterogeneous suspension. We evaluated this method for NPs heteroaggregating with suspended solids present in activated sludge. A relationship was derived between the heterog…

Nanoparticles: synthesis and applicationsHeavy metals in environmentHealthcare and Environmental Waste Management

Enhanced bipolar fatigue resistance in CaZrO3-modified (K,Na)NbO3 lead-free piezoceramics

Fang‐Zhou Yao、Eric A. Patterson、Ke Wang 等 6 位作者2014-06-16Applied Physics Letters

The bipolar fatigue behavior of (K,Na)NbO3 (KNN)-based lead-free piezoceramics was investigated. A comparative analysis demonstrated that CaZrO3-modified KNN ceramics exhibited highly enhanced bipolar fatigue resistance due to the reduced lattice distortion (c/a ratio) and coexistence of orthorhombic and tetragonal ph…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Oxygen defect assisted paramagnetic to ferromagnetic conversion in Fe doped TiO 2 nanoparticles

Biswajit Choudhury、Ranjana Verma、Amarjyoti Choudhury2014-06-16RSC Advances

Here we report the magnetic properties of Fe doped TiO2 nanoparticles annealed in air and vacuum. Fe doped TiO2 nanoparticles display paramagnetism during air annealing and ferromagnetism when the samples are annealed under vacuum. Ferromagnetism in vacuum annealed pure TiO2 nanoparticles is because of the presence of…

ZnO doping and propertiesCatalytic Processes in Materials ScienceCopper-based nanomaterials and applications

Fabrication of stable photovoltachromic cells using a solvent-free hybrid polymer electrolyte

Ming-Che Yang、Hsun-Wei Cho、Jih‐Jen Wu2014-06-16Nanoscale

In this work, photovoltachromic cells (PVCCs) are fabricated using a solvent-free polyethylene glycol (PEG)-titanium hybrid polymer electrolyte. With appropriate addition of 1,2-dimethyl-3-propylimidazolium iodide in the electrolyte, the range of tunable colored-state transmittance of the PVCC is enlarged due to an im…

TiO2 Photocatalysis and Solar CellsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

Gas Turbine Plant With Overexpansion Turbine and Heat Regeneration in the Ship Propulsion Complex

V.T. MATVIIENKO、Oleksandr Andriets、V. Ocheretianyi2014-06-16OpenAlex

Gas turbine engines (GTE) are widely applied in the ship propulsion complexes. Although GTE have many technical advantages, but for the wider application in shipbuilding it is necessary to carry out one of the most important requirements that nowadays is actual for all power-engineering objects — to increase efficienc…

Material Properties and ApplicationsAdvanced Power Generation TechnologiesTechnical Engine Diagnostics and Monitoring

Three-Dimensional Thin Film for Lithium-Ion Batteries and Supercapacitors

Yang Yang、Zhiwei Peng、Gunuk Wang 等 9 位作者2014-06-16ACS Nano

Three-dimensional heterogeneously nanostructured thin-film electrodes were fabricated by using Ta2O5 nanotubes as a framework to support carbon-onion-coated Fe2O3 nanoparticles along the surface of the nanotubes. Carbon onion layers function as microelectrodes to separate the two different metal oxides and form a nano…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Effect of Surface Wettability Properties on the Electrical Properties of Printed Carbon Nanotube Thin-Film Transistors on SiO2/Si Substrates

Zhen Liu、Jianwen Zhao、Wenya Xu 等 6 位作者2014-06-16ACS Applied Materials & Interfaces

The precise placement and efficient deposition of semiconducting single-walled carbon nanotubes (sc-SWCNTs) on substrates are challenges for achieving printed high-performance SWCNT thin-film transistors (TFTs) with independent gates. It was found that the wettability of the substrate played a key role in the electric…

Carbon Nanotubes in CompositesThin-Film Transistor TechnologiesNanowire Synthesis and Applications

Theoretical Determination of Electronic Spectra and Intersystem Spin–Orbit Coupling: The Case of Isoindole-BODIPY Dyes

Marta E. Alberto、Bruna Clara De Simone、Gloria Mazzone 等 5 位作者2014-06-16Journal of Chemical Theory and Computation

Density functional theory and its time-dependent extension (DFT, TDDFT) has been herein employed to elucidate the structural and electronic properties for a series of isoindole-boron dipyrromethene (isoindole-BODIPY) derivatives. The role played by both the nature and the positions of the substituents on intersystem s…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesLuminescence and Fluorescent Materials

Aqueous dispersions of layered double hydroxide/polyacrylamide nanocomposites: preparation and rheology

Ziqiao Hu、Guangming Chen2014-06-16Journal of Materials Chemistry A

Water was used to replace the toxic organic solvent of formamide in preparation of the aqueous dispersions of layered double hydroxide/polyacrylamide (LDH/PAM) nanocomposites, which exhibited greatly enhanced rheological properties when compared to those of the neat PAM. First, the nanocomposite dispersions were prepa…

Polymer Nanocomposites and PropertiesLayered Double Hydroxides Synthesis and ApplicationsSynthesis and properties of polymers

Aluminum, Indium, and Mixed Yttrium–Lithium Complexes Supported by a Chiral Binap-Based Fluorinated Dialkoxide: Structural Features and Heteroselective ROP of Lactide

Nicolas Maudoux、Thierry Roisnel、Jean‐François Carpentier 等 4 位作者2014-06-16Organometallics

The new chiral Binap-based fluorinated dialcohol proteo-ligand {ONNO}H 2 has been prepared under its enantiomerically pure and racemic forms following reaction of ( R )- or ( rac )-1,1′-binaphthyl-2,2′-diamine with 5,5,5-trifluoro-4-hydroxy-4-(trifluoromethyl)pentan-2-one. The racemic proteo-ligand reacts with the tri…

biodegradable polymer synthesis and propertiesPolyoxometalates: Synthesis and ApplicationsCarbon dioxide utilization in catalysis

Polymer and azo-dye composite: a photo-alignment layer for liquid crystals

Qi Guo、Abhishek Kumar Srivastava、Vladimir G. Chigrinov 等 4 位作者2014-06-16Liquid Crystals

In this article, we disclose a method to fabricate polymer-stabilised azo-dye photo alignment layers for liquid crystal. The idea includes the introduction of polymer network in the alignment layer, in optimal concentration, followed by two-step irradiation. The stabilised photo-alignment layer has been explored for d…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotonic Crystals and Applications

Size-Dependent Property and Cell Labeling of Semiconducting Polymer Dots

Kai Sun、Haobin Chen、Lei Wang 等 10 位作者2014-06-16ACS Applied Materials & Interfaces

Semiconducting polymer dots (Pdots) represent a new class of fluorescent nanoparticles for biological applications. In this study, we investigated their size-dependent fluorescence and cellular labeling properties. We demonstrate that the polymer conformation in solution phase largely affects the polymer folding and p…

Advanced biosensing and bioanalysis techniquesLuminescence and Fluorescent MaterialsCarbon and Quantum Dots Applications

Redox-Responsive Nanocarrier Based on Heparin End-Capped Mesoporous Silica Nanoparticles for Targeted Tumor Therapy in Vitro and in Vivo

Liangliang Dai、Jinghua Li、Beilu Zhang 等 6 位作者2014-06-16Langmuir

This study reports a smart controlled drug release system based on mesoporous silica nanoparticles (MSNs) for targeted drug delivery. The system was fabricated by employing heparin as an end-capping agent to seal the mesopores of MSNs via disulfide bonds as intermediate linkers for intracellular glutathione triggered…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsDendrimers and Hyperbranched Polymers