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First-principles prediction for the stability of LiK(BH4)2

Le Tuan、Cuong Nguyen、Tran Doan Huan2014-06-10physica status solidi (b)

Abstractauthoren Lithium/potassium borohydride LiK(BH) was recently synthesized and reported to be in a Pnma phase at ambient conditions. Subsequent theoretical studies show that this phase is metastable at finite temperatures up to 400 K. Studying the Pnma phase of LiK(BH) by first-principles calculations, we show th…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsSuperconductivity in MgB2 and Alloys

Core/Shell electrospun fibers as biodegradable scaffolds for sustained drug delivery in Wound Healing applications

Alexandros Repanas、Holger Zernetsch、Birgit Glasmacher2014-06-10Pneumologie

Aim: During the process of wound healing it is really important to keep the area safe from bacteria infections and treat possible inflammation incidents. Model antiseptic and anti-inflammatory agents can be encapsulated into a drug delivery carrier for combined treatment. Electrospinning (E-Spin) has been acknowledged…

Electrospun Nanofibers in Biomedical ApplicationsWound Healing and TreatmentsSilk-based biomaterials and applications

Negative‐Tone Block Copolymer Lithography by In Situ Surface Chemical Modification

Bong Hoon Kim、Kyeong‐Jae Byeon、Ju Young Kim 等 10 位作者2014-06-10Small

Negative-tone block copolymer (BCP) lithography based on in situ surface chemical modification is introduced as a highly efficient, versatile self-assembled nanopatterning. BCP blends films consisting of end-functionalized low molecular weight poly(styrene-ran-methyl methacrylate) and polystyrene-block-Poly(methyl met…

Block Copolymer Self-AssemblyNanopore and Nanochannel Transport StudiesAnodic Oxide Films and Nanostructures

A groundwork for crystal-field Hamiltonian parametrization

Maciej Mulak、Jacek Mulak2014-06-10physica status solidi (b)

Abstractauthoren The method of estimation of the square modules for the -pole components of the crystal-field Hamiltonian , prior to its conventional parametrization, is presented. The method is founded on the additivity of the squares of the multipolar second moments of the CF splittings to the square of the global s…

Advanced Chemical Physics StudiesCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Rahmenbedingungen für die Klassifizierung graphenbasierter Materialien

Peter Wick、Anna E. Louw‐Gaume、Melanie Kucki 等 16 位作者2014-06-10Angewandte Chemie

Ein Graph für Graphene: Die Erwartungen bezüglich der Anwendungsmöglichkeiten von Graphen sind enorm. Ein klares System zur Bezeichnung von Graphenderivaten fördert eine präzise Fachsprache für die Familie der graphenbasierten Materialien. Im Rahmen des GRAPHEN-Flagship-Projekts der EU wurden drei physikalisch-chemisc…

Graphene research and applicationsbiodegradable polymer synthesis and propertiesGraphene and Nanomaterials Applications

Reversal modes in small rings: Signature on the susceptibility

S. Castillo-Sepúlveda、Nicolás M. Vargas、R. A. Escobar 等 6 位作者2014-06-10Journal of Applied Physics

The magnetization reversal mechanisms of small rings have been investigated as a function of the geometry. Stepped and non stepped hysteresis loops were obtained and four different reversal mechanisms were identified. In spite the important information that is possible to get from the hysteresis loops, in some cases i…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsAnodic Oxide Films and Nanostructures

Synthesis and cationic photopolymerization of fluorine‐containing vinyl ether monomers for the hydrophobic films

Wei Li、Ping Feng、Yingquan Zou 等 4 位作者2014-06-10Journal of Applied Polymer Science

ABSTRACT Fluorine‐containing vinyl ether monomer is a combination of UV‐curing technology and low surface energy materials. In this article, a type of fluorine‐containing vinyl ether monomer was synthesized by the reaction of fluorinated alcohols, hexafluorobenzene, 2‐vinyloxy ethanol, and sodium hydride. These monome…

Synthesis and properties of polymersSilicone and Siloxane ChemistryPhotopolymerization techniques and applications

EDTA and pH‐sensitive crosslinking polymerization of acrylic acid, 2‐acrylamidoglycolic acid, and 2‐acrylamide‐2‐methyl‐1‐propanesulfonic acid

Byung‐Soo Kim、Daesun Hong、W. V. Chang2014-06-10Journal of Applied Polymer Science

ABSTRACT Network formation was monitored by shear storage modulus (G′) during free radical crosslinking polymerization to investigate the effects of pH and ethylenediaminetetraacetic acid (EDTA; a complex agent). Three types of acrylic monomers, acrylic acid (AAc), 2‐acrylamidoglycolic acid (AmGc), and 2‐acrylamido‐2‐…

Hydrogels: synthesis, properties, applicationsAdvanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

Experimental Study of Transformer Residual Flux and the Method of Restraining Inrush Current

Yoshihide Hase、Tomoyuki Kamesawa、Shinji Inoue 等 4 位作者2014-06-10Electrical Engineering in Japan

SUMMARY Whenever a power transformer in a no‐load condition is manually tripped, a residual flux appears in the transformer core, which causes an inrush current when the transformer is later re‐energized. However, the true nature of residual fluxes has not yet been experimentally elucidated. The authors interpreted th…

Power Systems Fault DetectionMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

Postpartum posterior reversible encephalopathy syndrome (PRES) in a twin pregnancy complicated by preeclampsia-eclampsia: case report

Dimitrios Papoutsis、N. El-Attabi、Andrew Sizer2014-06-10Clinical and Experimental Obstetrics & Gynecology

This is the second case in literature of posterior reversible encephalopathy syndrome (PRES) in a twin pregnancy complicated by preeclampsia-eclampsia. A 27-year-old primigravida with dichorionic diamniotic twin pregnancy was admitted at 36 weeks of gestation for induction of labour due to preeclampsia. On the second…

Lanthanide and Transition Metal ComplexesNeurological Complications and SyndromesMoyamoya disease diagnosis and treatment

Reaction Mechanism and Catalytic Fingerprint of Allantoin Racemase

Christophe Bovigny、Matteo T. Degiacomi、Thomas Lemmin 等 5 位作者2014-06-10The Journal of Physical Chemistry B

The stereospecific oxidative decomposition of urate into allantoin is the core of purine catabolism in many organisms. The spontaneous decomposition of upstream intermediates and the nonenzymatic racemization of allantoin lead to an accumulation of ( R )-allantoin, because the enzymes converting allantoin into allanto…

Metabolism and Genetic DisordersEnzyme Structure and FunctionPorphyrin Metabolism and Disorders

Superconductivity on a Crossover Phenomenon of Spin–Ladder System SrCa13Cu24O41 Single Crystals

Akihiko Hisada、Kazuyuki Matsubayashi、Yoshiya Uwatoko 等 11 位作者2014-06-10Journal of the Physical Society of Japan

Electrical resistivity and alternating current susceptibility measurements were performed for the spin–ladder compound SrCa13Cu24O41 under hydrostatic pressure up to 8 GPa. The superconducting transition was observed below TC = 14.7 K at pressures above 2 GPa. By using high-quality single crystals, the bulk supercondu…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Microstructure and material soundness in liquid and rheocast AM50 and effect of section thickness

M. Östklint、Magnus Wessén、Anders E. W. Jarfors2014-06-10International Journal of Cast Metals Research

Commercial grade AM50 magnesium alloy was diecast to varying wall thickness using both the RheoMetal process and conventional liquid casting. The resulting microstructure and pore structure were analysed. The rheocast material had larger pores than the conventionally cast material, scattered over the central 50% of th…

Magnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Determination ofSalmonella typhimuriumby a Fluorescence Resonance Energy Transfer Biosensor Using Upconversion Nanoparticles as Labels

Xiaoyuan Ma、Shuang Li、Yu Xia 等 4 位作者2014-06-10Analytical Letters

A Salmonella typhimurium (S. typhimurium) biosensor based on a fluorescence resonance energy transfer between upconversion and gold nanoparticles is reported. NaYF4:Yb,Er nanoparticles were synthesized and modified with a S. typhimurium target DNA complementary sequence to form the sensor. Gold nanoparticles were modi…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesBiosensors and Analytical Detection

Advances in techniques and technologies for bone implants

Natasha H. Munro、Kathryn M. McGrath2014-06-10Bioinspired Biomimetic and Nanobiomaterials

Materials which can augment and repair the function of damaged bone are required. Metals, ceramics and plastics have been widely used as artificial bone implants, although their material properties are not optimally matched to those of the native bone tissue. New materials, and methods of production, are being extensi…

Bone Tissue Engineering MaterialsAdditive Manufacturing and 3D Printing TechnologiesTitanium Alloys Microstructure and Properties

- Biomaterials for Scaffolds: Synthetic Polymers

Lindsay S. Wray、David L. Kaplan2014-06-10OpenAlex

Biomaterials for Scaffolds: Natural Polymers - 1

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Growth of polycrystalline Heusler alloys for spintronic devices

James Sagar、Chris Nga Tung Yu、Leonardo Lari 等 4 位作者2014-06-10Journal of Physics D Applied Physics

We have prepared polycrystalline Co2FeSi thin films on a number of seed layers to optimize their structural and magnetic properties. Using a Cr/Ag combined seed layer, films have been produced with extremely low interfacial roughness (<1 nm) and controllable coercivities in the range 12–27 Oe. Such a structure would b…

Magnetic properties of thin filmsMXene and MAX Phase MaterialsHeusler alloys: electronic and magnetic properties

Effects of rare earth samarium oxide on the properties of polypropylene‐graft‐cardanol grafted by reactive extrusion

Xinggong Mao、Yi Deng、Jinhuo Lin 等 4 位作者2014-06-10Journal of Applied Polymer Science

ABSTRACT Rare earth elements can improve the performance of polymers because of their special 4f orbitals. The nucleation and stabilization of radical groups of rare earth particles can affect the structure of polypropylene (PP) and its properties. In this study, samarium oxide (Sm2O3) particles were used as a cocatal…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Synthesis and Characterization of a Zinc(II) Complex with Mixed 4‐Hydroxypyridine‐2,6‐dicarboxylic Acid and 1,3‐Bis(4‐pyridyl)propane Tectons

Yu‐Fang Wang、Junqing Chen、Jun‐Lei Geng2014-06-10Zeitschrift für anorganische und allgemeine Chemie

Abstract The metal‐organic framework {[Zn2(CAM)(μ2‐OH)(bpp)]·2H2O}n (1) [H3CAM = 4‐hydroxypyridine‐2,6‐dicarboxylic acid, bpp = 1,3‐bis(4‐pyridyl)propane], was hydrothermally synthesized and characterized by elemental analyses, infrared spectroscopy, and single‐crystal X‐ray diffraction. Compound 1 presents a three di…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes