Materials Literature
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Nitrile hydratases (NHases) possess a mononuclear iron or cobalt cofactor whose coordination environment includes rare post-translationally oxidized cysteine sulfenic and sulfinic acid ligands. This cofactor is located in the α-subunit at the interfacial active site of the heterodimeric enzyme. Unlike canonical NHases…
Lithium iron borate (LiFeBO3) has a high theoretical specific capacity (220 mAh/g), which is competitive with leading cathode candidates for next-generation lithium-ion batteries. However, a major factor making it difficult to fully access this capacity is a competing oxidative process that leads to degradation of the…
Cardiovascular disease remains the leading cause of death worldwide(1). Cardiac tissue engineering holds much promise to deliver groundbreaking medical discoveries with the aims of developing functional tissues for cardiac regeneration as well as in vitro screening assays. However, the ability to create high-fidelity…
A series of bipyridyl (bpy) Pt(II) complexes with π-bonded catecholate (cat) [(bpy)Pt(LM)][BF4]n (2-5) (LM = Cp*Rh(cat), n = 2; Cp*Ir(cat), n = 2; Cp*Ru(cat), n = 1; and (C6H6)Ru(cat), n = 2) were prepared and fully characterized. The molecular structures of the four compounds were determined and showed that the solid…
Five different mutants of [Leu-5] Enkephalin YGGFL peptide have been investigated for fibril formation propensities. The early oligomer structures have been probed with a combination of ion-mobility mass spectrometry and computational modeling. The two peptides YVIFL and YVVFL form oligomers and amyloid-like fibrils.…
Polymeric bulk heterojunction (BHJ) organic solar cells represent one of the most promising technologies for renewable energy with a low fabrication cost. Control over BHJ morphology is one of the key factors in obtaining high-efficiency devices. This review focuses on formulation strategies for optimizing the BHJ mor…
We study the formation of Cu 2 ZnSnS 4 (CZTS) films from various liquid-phase precursors. Our experimental data point to the significant role that reactivities of precursor components play in the quality of the final material. Although reactive molecular precursors favor formation of CZTS under milder conditions, the…
Due to the combination of metal ions and organic linkers and the presence of different types of cages and channels, metal-organic frameworks often possess a large structural and chemical heterogeneity, complicating their adsorption behavior, especially for polar-apolar adsorbate mixtures. By allocating isotherms to in…
The potential activities for two series of iron complex precatalysts on ethylene reactivity are evaluated by the density functional theory (DFT)–charge equilibration (DFT–QEq) method on the basis of the molecular mechanics (MM–QEq) method. All three spin states on the central iron atom are calculated through the two c…
In this study, copper oxide nanoparticles with hierarchical morphologies (CuO) have been synthesized via a hydrothermal route. The morphology and microstructure of the as prepared samples were characterized by XRD, SEM, TEM, and SAED. CuO exhibited excellent performance for the removal of Pb(II) from aqueous solution.…
The wide variety of lightning stroke characteristics and the modifying effects of power system components result in a diversity of intrusive lightning voltage waveshapes that stress transformers. These are not the traditional standard lightning impulses with a waveshape of 1.2/50 μs. Therefore the applicability of the…
The physicochemical properties of three transformer mineral oils of different levels of degradation, resulting from exposure to moisture and electrical discharges, are investigated. The first oil is new and untreated whereas the second is taken from a transformer after one year of normal operation; and the third oil i…
Magnetic iron oxide nanoparticles (MNPs) have been widely explored for use in biomedical applications. In the present study, iron oxide nanoparticles were connected to methoxy poly(ethylene glycol) (mPEG) via a new method. The mPEG was acrylated at first and Michael reaction was carried out between acrylated mPEG and…
International audience
Tannins are non toxic, cheap and abundant polyphenolic oligomers extracted from tree barks. They can be easily used for preparing thermoset resins that are natural at the 70–95% level, depending on the cases. From these resins, highly porous monoliths can be obtained by different techniques such as classical physical…
Spontaneous transformation of the thermally stable [HS](-)-bound {Fe(NO)2}(9) dinitrosyl iron complex (DNIC) [(HS)2Fe(NO)2](-) (1) into [(NO)2Fe(μ-S)]2(2-) (Roussin's red salt (RRS)) along with release of H2S, probed by NBD-SCN (NBD = nitrobenzofurazan), was observed when DNIC 1 was dissolved in water at ambient tempe…
TTL caching models have recently regained significant research interest, largely due to their ability to fit popular caching policies such as LRU. In this extended abstract we briefly describe our recent work on two exact methods to analyze TTL cache networks. The first method generalizes existing results for line net…
The development of novel assays for protease sensing plays an important role in clinical diagnostics and therapeutics. Herein, we report a supramolecular platform for label-free protease detection, based on protein/dye self-assembly and enzyme-triggered disassembly. In a typical case, coassembly of protamine sulfate a…
We investigate photoluminescence of Eu-related emission in a GaN host consisting of thin layers grown by organometallic vapor-phase epitaxy. By comparing it with a reference sample of Eu-doped Y₂O₃, we find that the fraction of Eu(3+) ions that can emit light upon optical excitation is of the order of 1%. We also meas…
A novel porous succinylated bioadsorbent was prepared by the partial enzymatic hydrolysis of bamboo (Phyllostachys heterocycla) and its subsequent modification with succinic anhydride. Pb(II) removal from solutions that also contained sodium chloride and an amino acid was investigated using the bioadsorbent. Enzymatic…