Materials Literature
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Mineralization of calcium carbonate in aqueous solutions starting from its initiation was studied by time-resolved small-angle neutron scattering (SANS). SANS revealed that homogeneous crystallization of CaCO 3 involves an initial formation of thin plate-shaped nuclei which subsequently reassemble to 3-dimensional par…
HemCon bandage is an engineered chitosan acetate preparation designed as a hemostatic dressing, and is under investigation as a topical antimicrobial dressing. We studied its effects on healing of excisional wounds that were or were not infected with Staphylococcus aureus, in normal mice or mice previously pretreated…
Rare earth cerium oxide (ceria) nanoparticles are stabilized using end-functional phosphonated-PEG oligomers. The complexation process and structure of the resulting hybrid core-shell singlet nanocolloids are described, characterized, and modeled using light and neutron scattering data. The adsorption mechanism is non…
We have synthesized and structurally characterized the unprecedented peroxo-zirconium(IV) containing [Zr6(O2)6(OH)6(gamma-SiW10O36)3]18- (1). Polyanion 1 comprises a cyclic 6-peroxo-6-zirconium core stabilized by three decatungstosilicate units. We have also prepared the isostructural hafnium(IV) analogue [Hf6(O2)6(OH…
Plants produce a range of biopolymers for purposes such as maintenance of structural integrity, carbon storage, and defense against pathogens and desiccation. Several of these natural polymers are used by humans as food and materials, and increasingly as an energy carrier. In this review, we focus on plant biopolymers…
A frequency upconversion process in Pr3+ doped TeO2–ZnO glasses containing silver nanoparticles is studied under excitation with a nanosecond laser operating at 590 nm, in resonance with the H34→D12 transition. The excited Pr3+ ions exchange energy in the presence of the nanoparticles, originating efficient conversion…
Populations of the planktonic diatom Aulacoseira skvortzowi i in Lake Baikal developed below 4°C, with mortality increasing rapidly at temperatures above 6.5°C. Resting spores were produced before the temperature rise associated with summer stratification. The main cue for sporulation was a decline in phosphate concen…
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Abstract The present study gives an overview of the fundamental material properties of perovskite-type hydrides. Formation ability of the perovskite-type hydrides has been reasonably explained on the basis of the geometric restrictions on the composed ions using the Goldschmidt tolerance factor. Characteristic crystal…
Electronic Structure, Electrical and Dielectric Properties of BaSnO3 below 300 K, Singh, Prabhakar, Brandenburg, Benjamin J., Sebastian, C. Peter, Singh, Prakash, Singh, Sindhu, Kumar, Devendra, Parkash, Om
We discuss the equilibrium condition for a liquid that partially wets a solid on the level of intermolecular forces. By using a mean field continuum description, we generalize the capillary pressure from variation of the free energy and show at what length scale the equilibrium contact angle is selected. After recover…
Nanocrystalline ZrO(2) samples with narrow size distributions and mean particle sizes below 10 nm have been synthesized in a continuous flow reactor in near and supercritical water as well as supercritical isopropyl alcohol using a wide range of temperatures, pressures, concentrations and precursors. The samples were…
The properties of unsaturated polyester reinforced with banana and pandanus woven fabric were studied. Both of the composite systems were fabricated by vacuum bagging technique. Flexural, impact, and water absorption properties were investigated as a function of total fiber volume fraction. It is observed that the fle…
Upconverting phosphors (UCPs) are very attractive reporters for fluorescence resonance energy transfer (FRET)-based bioanalytical assays. The large anti-Stokes shift and capability to convert near-infrared to visible light via sequential absorption of multiple photons enable complete elimination of autofluorescence, w…
For Al, TiAl3, TiAl, Ti3Al, and Ti a morphological threshold from porous to tubular self-ordered anodic oxide structures as well as the length scale of self-ordering are demonstrated to strongly depend on the substrate composition and anodization voltage of self-organization. The results are consistent with a simple v…
Abstract Colloidal particles with well‐defined sizes can self‐assemble into ordered, crystalline structures under non‐equilibrium conditions. This phenomenon originates from the various forces acting upon them. In this article, we provide an overview on the forces at work in a colloidal system, in particular, the role…
Indium doped zinc oxide (IZO) thin films are grown onto Corning glass substrates using the spray pyrolysis technique. The effect of doping concentration on the structural, electrical and optical properties of IZO thin films is studied. X-ray diffraction studies show a change in preferential orientation from the (0 0 2…
editorial
Blocked isocyanates were successfully encapsulated into polystyrene and hydroxyl and amine functionalized polymeric nanospheres via emulsion polymerization. The nanocapsules were characterized via Fourier transform infrared spectroscopy, differential scanning calorimetry and transmission electronic microscopy. The blo…
We developed a novel and convenient method for the synthesis of a potentially safe non-viral gene delivery vehicle based on the cationic block copolymer of spermine and aspartic acid (ASSP) and coupled it with polyethylene glycol (PEG). The copolymer ASSP was prepared by direct polycondensation in the ionic liquid, bu…